První xxxxxxxx Xxxxxx
xx xxx 26. července 1979,
xxxxxx xx xxxxxxx xxxxxxxxxx metody Xxxxxxxxxxxx xxx zkoušení xxxxxxxxx xxxxx xxxxxxxx x xxxxxx xxxxxxxx
(79/796/XXX)
XXXXXX XXXXXXXXXX XXXXXXXXXXXX,
x ohledem xx Xxxxxxx x xxxxxxxx Xxxxxxxxxx xxxxxxxxxxxxx xxxxxxxxxxxx,
x xxxxxxx xx směrnici Xxxx 73/437/XXX xx xxx 11. xxxxxxxx 1973 o xxxxxxxxxx xxxxxxxx předpisů xxxxxxxxx xxxxx xxxxxxxxxx se xxxxxxxxx xxxxx xxxxxxxx x lidské spotřebě [1], x zejména xx xxxxxx 11 xxxxxxx xxxxxxxx,
xxxxxxxx x xxxx, že xxxxxx 11 xxxxxxx směrnice xxxxxxx, xx xxxxxxx xxxxxxxxx xxxxx xx xxxxxxx analytickými xxxxxxxx Xxxxxxxxxxxx;
xxxxxxxx x tomu, xx xx vhodné xxxxxxxx xxxxxxxxx xxxx xxxxx, xxxxxxx studium xxx xxxx ukončeno;
vzhledem x xxxx, xx x xxxxxxx xxxxxxxx 73/437/XXX xx stanovena xxxxxx xxx xxxxxxxxx xxxxx x xxxxx xxxx xxxxxx xxxxx x xxxxx xxxxx xxxxxx, xxxxxx xxxxxxxxx xxxxxx xxxxxxxxxxxxxxxx x xxxxx xxxxx xxxxxx, xxxxxxxx xxxxx, tekutého xxxxxxxxxx cukru a xxxxxx x invertního xxxxx x xxxxxx xxxxxxxxx xxxxx x xxxxxxx xxxxx extra xxxxxx x tekutého xxxxx;
xxxxxxxx k xxxx, xx by xx xxxxx xxxxxx bylo xxxxxx až do xxxxxxxxxxx xxxxxxx metod Xxxxxxxxxxxx xxx stanovení xxxxxxxxxxxx xxxxx xxxxxxxx xxxxxxxx xxxxxx možnost xxxxxxxx i xxxxxx xxxxxx podle Xxxxx x Eynona (metody 7 a 8 x xxxxxxx XX x. XXX.3 x XXX.4) xxxxx xxxxxx xxxxx Xxxxx x Xxxxxxxx (metoda 6 x xxxxxxx XX x. XXX.3 x XXX.4);
xxxxxxxx x tomu, xx xxxxxxxxxx metody xxxxxxxx x xxxx xxxxxxxx xxxx x xxxxxxx se xxxxxxxxxxx Xxxxxxx xxxxxx xxx xxxxxxxxx,
XXXXXXX XXXX SMĚRNICI:
Článek 1
1. Členské xxxxx stanoví, xx xxxxxxx xxxxxxxx k xxxxxxx xxxxxxxx xxxxxxxxx x xxxxxxx X xxxx být prováděny xxxxx xxxxx popsaných x příloze XX xxxx směrnice.
2. Aniž xx xxxxxx xxxxx xxxxxxxxxxx, xxxxxxx se xxxxxx xxxxx Luffa x Xxxxxxxx (příloha XX, metoda 6) xx xxxxxxxxx xxxxxxxxxxxx xxxxx obsažených
- x xxxxxxx cukru,
- v xxxxxxx xxxxx xxxxx,
- x xxxxxxx xxxxxxxxx xxxxx,
- v tekutém xxxxx xxxxxxxxx xxxxx,
- x xxxxxx x xxxxxxxxxx xxxxx,
- ve xxxxxxxxx xxxxxx,
- v xxxxxxx xxxxxxxxx xxxxxx,
- x dextrose xxxxxxxxxxx,
- x xxxxxxxx xxxxxxx.
Xxxxxxx xxxxx xxxx xxxxx xx xxxx xxxxx xxxxxxxx ke stanovení xxxxxxxxxxxx xxxxx x xxxxxx nebo více xxxxxxx xxxxx uvedených x xxxxxxxxxx xxxxxxx xxxxxx xxxxx Lanea x Xxxxxx (příloha XX, xxxxxx 7 xxxx 8).
3. Pokud xxxxxxx xxxx xxxxxxx xxxxxxx xxxxx xxxxxxxx x odst. 2 xxxxxx pododstavci, xxxxxxxxxx x xxx uvědomí Xxxxxx x ostatní xxxxxxx xxxxx.
Xxxxxx 2
Xxxxxxx xxxxx xxxxxx x xxxxxxxx xxxxxx x xxxxxxx xxxxxxxx nezbytné xxx xxxxxxxx xxxxxxx x xxxxx xxxxxxxx do 18 měsíců xx xxxxxxxx xxxx xxxxxxxx. Xxxxxxxxxx o xxxx xxxxxxx Komisi.
Xxxxxx 3
Tato xxxxxxxx xx určena xxxxxxxx xxxxxx.
X Xxxxxxx dne 26. xxxxxxxx 1979.
Za Xxxxxx
Xxxxxxx Xxxxxxxx
xxxx Xxxxxx
[1] Xx. věst. X 356, 27.12.1973, x. 71.
PŘÍLOHA X
XXXXXX XXXXXXX XXXXXXXXXXXX XXXXX XXXXXXXXXXXX XXX XXXXXXX CUKRY XXXXXX K LIDSKÉ XXXXXXXX
PŘÍLOHA XX
XXXXXXXXXX XXXXXX X OVĚŘENÍ XXXXXXX XXXXXXXXX CUKRŮ URČENÝCH X XXXXXX XXXXXXXX
XXXX
1. Xxxxxxxx vzorků x xxxxxxx
Xxxxxx doručený do xxxxxxxxxx xx xxxxxxxx xxxxxxxx.
Xxx analýzu xx xx vzorku xxxxxx xxxxxxxx nejméně 200 x x okamžitě xxxxxxx xx čisté, xxxxx, xxxxxxxxx xxxxxxx xxxxxxxx xxxxxxxxxxxxx xxxxxxxx.
2. Xxxxxxx xxxxxxx, xxxxxxxxx x pomůcky
Při xxxxxx xxxxxxxxx x pomůcek xxxx xxxxxxx xxxxxx xxxxx x xxxxxxx xxxxxxxxxxx xxxxxxxx x xxxxxxxxx, nebo xxxx xxxxxxxxx, které xxxx xxxxxxxxx xxxxxxxxx xxxxxxxxxx.
Xxxxx xx xxxxxxxxx xxxx, xxxxxx xx destilovaná xxxx xxxx xxxxxxxxxxxxxxxx xxxx s xxxxxxx xxxxxxxxxxxx xxxxxxxx.
Xxxxxxx xxxxxxx xxxx být analytické xxxxxxx, xxxxx xxxx xxxxxxxxx xxxxx.
Xxxxx xx xxxxxxxxxx xx roztok xxxxxxx xxx dalšího xxxxxxxxx, xxxxx xx x xxxxx roztok.
3. Xxxxxxxxx xxxxxxxx
X úředním xxxxxxxxx x xxxxxxx xx xxxxx výsledek xxxxxxx xxxx xxxxxxxx xxxxxxx ze xxxx xxxxxxxxx x xxxxxxxxxxx xxxxxxxxxxxxxxx.
Xxxxx xxxx xxxxxxx xxxxx, xxxx xxxxxxxx xxxxxxxxx x procentech xxxxxxxxxxxx xxxxxxxxx xxxxxxxxxxxxx xxxxxx xxx, xxx xxx do xxxxxxxxxx xxxxxxx.
Xxxxx xxxxxxxx xxxxxx x takto vyjádřeném xxxxxxxx xx určen xxxxxxxxx xxxxxx.
XXXXXX 1
XXXXXXXXX XXXXXX XXXXXXXXX XXXXXXX
1. Xxxxxxx x oblast xxxxxxx
Xxxxxx slouží ke xxxxxxxxx xxxxxx xxxxxxxxx xxxxxxx
- x xxxxx xxxxxxxxx,
- x xxxxx xxxx x cukru xxxxx,
- v xxxxx xxxxx xxxxx.
2. Xxxxxxxx
"Xxxxxx xxxxxxxxx sušením": xxxxxxx xxxxxx xxxxxxxxx sušením xxxxxxxxx xxxxxxxx metodou.
3. Xxxxxxxx metody
Ztráta xxxxxxxxx xxxxxxx xx stanoví xxxxxxx při xxxxxxx 103 ± 2 °X.
4. Přístroje a xxxxxxx
4.1 Xxxxxxxxxx xxxx xxxxxx x xxxxxxxxx 0,1 xx.
4.2 Xxxxxxx x vhodnou xxxxxxxxx, xxxxxx termostatem, umožňující xxxxxxxx xxxxxxx 103 ± 2 °C.
4.3 Xxxxxx váženka s xxxxxxx dnem, odolná xxxx xxxxxxxx xxxxxx x xxxxxxxxxx xxxxxxxxx, x xxxxxxxx xxxxxxx 100 mm x x hloubkou xxxxxxx 30 mm.
4.4 Xxxxxxxxx x xxxxxxx aktivovaným xxxxxxxxxxx nebo s xxxxxxxxxxx sušidlem s xxxxxxxxxxx xxxxxx xxxxxxxx.
5. Xxxxxx
Xxxxxxxx:
Xxxxxxx xxxxxxx v xxxxxx 5.3 xx 5.7 musí xxx xxxxxxxxx okamžitě po xxxxxxxx xxxxxx se xxxxxxx.
5.1 Miska (4.3) xx xxxxxx xx xxxxxxxxxx hmotnosti v xxxxxxx (4.2) xxx xxxxxxx 103 ± 2 °C.
5.2 Xxxxx xx xxxxx v xxxxxxxxxx (4.4) vychladnout xxxxxxx xx xxxx 30 až 35 xxxxx x xxxx xx zváží x xxxxxxxxx xx 0,1 xx.
5.3 Xx xxxxx xx xxxxxx xxxxxxxxx 20 xx 30 x xxxxxx x xxxxxxxxx xx 0,1 xx.
5.4 Xxxxx se xxxxx do xxxxxxx (4.2) o xxxxxxx 103 ± 2 °X, xxx xx xxxxxxx 3 hodiny.
5.5 Xxxxx xx xxxxx xxxxxxxxxxx x exsikátoru (4.4) x xxxxx xx x přesností xx 0,1 xx.
5.6 Xxxxx xx xxxxx xxxxx xx 30 xxxxx xx sušárny x xxxxxxx 103 ± 2 °X.
Xxxxx xx xxxxxxxxxxx x xxxxxxxxxx (4.4) x xxxxx xx s xxxxxxxxx xx 0,1 xx. Pokud je xxxxxx xxxx xxxxx xxxxxxxx xxxxx než 1 mg, xxxxxx xx opakuje. Xxxxx-xx xx xxxxxxx hmotnosti, xxxxxxx xx k xxxxxxx nejnižší xxxxxxxxxxx xxxxxxx.
5.7 Xxxxxxx xxx xxxxxx xxxxx být xxxxx než čtyři xxxxxx.
6. Xxxxxxxxx xxxxxxxx
6.1 Xxxxxx x postup xxxxxxx
Xxxxxx xxxxxxxxx xxxxxxx x xxxxxxxxxx xxxxxxxxxxxx xxxxxx xx xxxx xxxxx vzorcem:
kde:
m0 je xxxxxxxxx hmotnost xxxxxxxxxx xxxxxx (g),
m1 xx xxxxxxxx xxxxxxxxxx xxxxxx xx xxxxxxxx (x).
6.2 Xxxxxxxxxxxxxx
Xxxxxx mezi xxxxxxxx xxxx xxxxxxxxx xxxxxxxxxxx xxxxxxx xxxx xxxxxx xx xxxxx z xxxxx xxxxxx xxxxxx xxxxxxxxxxx xx totožných xxxxxxxx nesmí být xxxxx než 0,02 x xx 100 x vzorku.
METODA 2
XXXXXXXXX XXXXXX
Xxxxxx xxxxxx ve xxxxxxx xxxxxxx
1. Xxxxxxx x xxxxxx xxxxxxx
Xxxxxx xxxxxx xx xxxxxxxxx xxxxxx sušiny
- ve xxxxxxxxx xxxxxx,
- x xxxxxxx xxxxxxxxx xxxxxx,
- x xxxxxxxx xxxxxxxxxxx,
- x xxxxxxxx xxxxxxx.
2. Xxxxxxxx
"Xxxxx xxxxxx": xxxxx xxxxxx xxxxxxxxx popsanou xxxxxxx.
3. Podstata xxxxxx
Xxxxxx xx xxxxxxx při xxxxxxx 70 ± 1 °C xx xxxxxxx sušárně xxx xxxxx xxxxxxx 3,3 xXx (34 mbar). Xxxxxxxx xxxxxx xxxxxxxxxx xxxxxx nebo xxxxxxxx xxxxxxxxxx sirupu se xxxx xxxxxxx xxxxxx xxxxxxxxx s vodou x x xxxxxxxxxx.
4. Xxxxxxx xxxxxxx
4.1 Xxxxxxxxx: xxxxxxxx se v Xüxxxxxxxx xxxxxxx xxxxxxxxxx xxxxxxxxxx xxxxxxxx kyselinou xxxxxxxxxxxxxxx (1 xx xxxxxxxxxxxxx kyseliny x xxxxxxx 1,19 x/xx xx xxxx xxxx xxx 20 °X), xxxxx xxxxxxx xxxxxxxxxx xxxxxxxx xxxxxxx reakci. Xxxxxxxxx xx xxxxxx xx xxx xxxxxxx xxxxx xxx dlouho, xxxxx hodnota xX xxxxxxxx xxxxxxxxxx xxx 4; xxx se xxxxxxxxx xxxxxx x xxxxxxx při 103 ± 2 °C x uloží xx xx vzduchotěsného nádoby.
5. Xxxxxxxxx x pomůcky
5.1 Xxxxxxx sušárna, utěsněná, xxxxxx xxxxxxxxxxx, vybavená xxxxxxxxxx a vakuovým xxxxxxxxxx. Xxxx xxx xxxxxxxxxxxx xxx, xxx xxx zajištěn xxxxxx xxxxxxx xxxxx xx xxxxxxx xxxxxxxxx xx xxxxxxxx.
5.2 Xxxxxxxxx k xxxxxxxxx xxxxxxx xxxxxxxxxx xx xx xxxxxxxx xxxxxx xxxxxxxx xxxxxxx xxxxxxxxxxx silikagelem xxxx xxxxxxxxxxx xxxxxxxxxxx, x xxxxxxxxxxx xxxxxx xxxxxxxx. Xxxx kolona xxxxxxxxxx xxxxxxxxxxxxxx xxxxxxxx xxxxxxx xx xxxxxxx xxxxxxxxx x xxxxxxx plynů xxxxxxxxxx xx xxxxx xxxxxxx xx xxxxxxx.
5.3 Xxxxxx xxxxxxxxxx xxxxxxxx x sušárně xxxx 3,3 xXx (34 xxxx) nebo xxxxx.
5.4 Xxxxxx váženka x xxxxxxx dnem xxxxxx xxxx xxxxxxxx vzorků x podmínkám xxxxxxx x xxxxxxxx xxxxxxx 100 xx x x xxxxxxxx xxxxxxx 300 mm.
5.5 Xxxxxxxx xxxxxxx x xxxxxx xxxxx, xxx xxxxxxx xxxxx xxxxxxxxx xx xxxxxxx.
5.6 Xxxxxxxxx x xxxxxxx xxxxxxxxxxx xxxxxxxxxxx xxxx s xxxxxxxxxxx xxxxxxxxxxx x indikátorem xxxxxx vlhkosti.
5.7 Xxxxxxxxxx xxxx vážící x xxxxxxxxx xx 0,1 xx.
6. Xxxxxx
6.1 Xx xxxxxxx (5.4) xx xxxxxxxxx xxxxxxxx (5.5) xx xxxxxxx xxxxxxxxx 30 g křemeliny (4.1), vše vloží xx xx xxxxxxx (5.1) x xxxxxxxx 70 ± 1 °X x tlak xx sníží nejméně xx 3,3 xXx (34 mbar).
Suší se xxx xxxx nejméně 5 hodin, přičemž xx xxxx aparaturu xxx xxxxxxxxx xxxxxxx xx sušárny xxxxxx xxxxxx xxxxx xxxxxxx. Xxxxx xx xxxxxxxxxxx xxxx x xxxxx xxxxxxx xx upraví.
6.2 Xxxxxxxxxx dosažení atmosférického xxxxx x sušárně xx dosáhne xxxxxxxx xxxxxxxx přívodu suchého xxxxxxx. Xxxxx i xx xxxxxxxxx xxxxxxxx xx xxxxxxxx přemístí xx xxxxxxxxxx (5.6), xxx se xxxxx xxxxxxxxxxx, x xxx xx zváží.
6.3 Xx xxxxxxx x obsahu 100 xx xx x xxxxxxxxx xx 1 xx xxxxxx xxxxxxxxx 10 x xxxxxxxxxxxxx xxxxxx.
6.4 Xxxxxxxx xxxxxx xx zředí 10 ml teplé xxxx a roztok xx xxxxxx skleněné xxxxxxx (5.5) kvantitativně xxxxxxx xx xxxxxxx.
6.5 Xxxxx xx zkušebním xxxxxxx x xxxxxxxxx xxxxxxxx se xxxxx xx xxxxxxx a xxxx xx xxxxx xxxxxxx na 3,3 xXx (34 mbar). Xxxx xx xxx 70 ± 1 °X, xxxxxxx se xxxxxxxx nechá xxxxxxxxx xxxxxx xxxxx suchého xxxxxxx.
Xxxxxx xx xxxxxxx xx dobu 20 xxxxx; x xxxxxxxxxx xxxxxx vlhkosti má xxxxx ke konci xxxxxxx xxx. Je xxxxxxxx udržovat xxxxxx x xxxxx při xxxxxxxxxx xxxxx x xxxxxx xxxxxx xxxxxxx xx xxxxxxx xxxxx xxxxxx xxx, xxx xx xxxxx noci xxxx udržoval přibližně xx xxxxxxx 3,3 xXx (34 mbar) xxxx xxxxx.
6.6 Atmosférického xxxxx x xxxxxxx xx opět xxxxxxx xxxxxxxx xxxxxxxx přívodu xxxxxxx vzduchu. Xxxxxxx x x xxxxxxx xx xxxxxxxx xxxxxxxx xx xxxxxxxxxx, xxx xx xxxxx xxxxxxxxxxx, x xxxx se xxxxx s xxxxxxxxx xx 1 xx.
6.7 Xxxxxxx (6.5) xx xxxxxxx xx další 4 xxxxxx. X xxxxxxx xx xxxxxx xxxxxxxxxxxx xxxx a xxxxx xx xxxxx xxxxx do exsikátoru. Xxxxx xx xxxxxxxxxxx x xxxxxxx xx xxxxxx, xxx xxx xxxx xxxxxxxx xxxxxxxxxx xxxxxxxxx. Xx konstantní xxxxxxxx xx xxxxxxxx xxxxxx xxxxxxxx, kdy xxxxxx xxxx xxxxx xxxxxxxx téže xxxxx xxxx větší xxx 2 xx. X xxxxxxx případě se xxxxxxx xxxxxxx 6.7.
6.8 Xxx xxxxxxxxx xxxxxx xx xxxxxxxx xxxxxxx xxxxxxxx nebo v xxxxxxxxxxx dextrosy xxxx xxxxxxx xxxxxxxxx x xxxx xxxxxxxxx.
7. Xxxxxxxxx xxxxxxxx
7.1 Vzorec x xxxxxx xxxxxxx
Xxxxx xxxxxx xxxxxxxxx x xxxxxxxxxx xxxxxxxxxxxx xxxxxx xx xxxxxxxx podle tohoto xxxxxx:
xxx:
x0 = xx xxxxxxxxx hmotnost zkušebního xxxxxx (g),
m1 = xx hmotnost xxxxxxx x křemelinou, skleněnou xxxxxxxx x zbytkem xxxxxxxxxx xxxxxx po xxxxxx (x),
x2 = xx xxxxxxxx xxxxxxx x xxxxxxxxxx x xxxxxxxxx xxxxxxxx (x).
7.2 Xxxxxxxxxxxxxx
Xxxxxx xxxx výsledky xxxx xxxxxxxxx provedených xxxxxxx nebo xxxxxx xx sebou x xxxxx xxxxxx xxxxxx xxxxxxxxxxx xx totožných xxxxxxxx xxxxx xxx xxxxx xxx 0,12 x xx 100 x xxxxxx.
XXXXXX 3
XXXXXXXXX XXXXXXX XXXXXX
(Xxxxxxxxxxxxxxxx xxxxxx)
1. Xxxxxxx x xxxxxx xxxxxxx
Xxxxxx xxxxxxx xxxxx xxxxxx
- v xxxxxxx xxxxx,
- x xxxxxxx xxxxx xxxxx,
- v xxxxxxx xxxxxxxxx xxxxx,
- x xxxxxxx xxxxx xxxxxxxxx xxxxx,
- x xxxxxx x xxxxxxxxxx xxxxx,
- x xxxxxx x xxxxxx invertního xxxxx.
2. Xxxxxxxx
"Xxxxx xxxxxx": xxxxx xxxxxx stanovený xxxxxxxx xxxxxxx.
3. Xxxxxxxx xxxxxx
Xxxxxxx xx index xxxx xxxxxxxxxx xxxxxx xxx 20 °X x podle xxxxxxx xxxxxxxxxxx xxxxxxxxxxx jako xxxxxx xxxxxx xxxx xx převede na xxxxx xxxxxx.
4. Přístroje x pomůcky
4.1 Xxxxxxxxxxxx x xxxxxxxxx xxxxxx xx čtyři desetinná xxxxx, xxxxxxxx xxxxxxxxxx x xxxxxxxx xxxxxx xxxxxxxxx xxxxxxxxxx x xxxxx lázní, která xx udržována xxxxxxxxxxx xx xxxxxxx 20 ± 0,5 °C.
4.2 Xxxxxxxx zdroj xxxxxxxxxxx xx xxxxxxxx výbojky.
5. Xxxxxx
5.1 Xxxxx jsou xx xxxxxx xxxxxxxx xxxxxxxx, xxxxxxxx xx xxxxxxxx xxxxxx x xxxxxx 1:1 (x/x).
5.2 Xxxxxxxxxxxxxx (4.1) xx xxxxx index xxxx xxxxxx xxx 20 °X.
6. Xxxxxxxxx výsledků x jejich xxxxxxx
6.1 Xxxxx sušiny se xxxxxxx z xxxxxx xxxx pro xxxxxxx xxxxxxxxx xxx 20 °X xxxxx xxxxxxx xxxxxxx x jako xxxxxxx xx přítomnost xxxxxxxxxx xxxxx x xxxxxxxxxxxx vzorku xx x xxxxxxxx x xxxxxxx xxxxxx xx xxxxx 1 % xxxxxxxxxx xxxxx hodnota 0,022.
6.2 Xxxxx byl xxxxxx zředěn xxxxx x xxxxxx 1:1 (x/x), xxxx xx xxxxx xxxxxxxxx sušiny xxxxxxxxx xxxxx.
6.3 Xxxxxxxxxxxxxx
Xxxxxx xxxx výsledky xxxx xxxxxxxxx provedených xxxxxxx xxxx rychle za xxxxx z xxxxx xxxxxx xxxxxx xxxxxxxxxxx xx totožných xxxxxxxx xxxxx xxx větší xxx 0,2 g xxxxxx xx 100 x xxxxxx.
XXXXXXXXXX XXXXXXX
Xxxxxx xxxx (n) roztoků xxxxxxxxx při 20 °X [1]
|
x (20 °X) |
Xxxxxxxxx (%) |
|
1,3330 |
0,009 |
|
1,3331 |
0,078 |
|
1,3332 |
0,149 |
|
1,3333 |
0,218 |
|
1,3334 |
0,288 |
|
1,3335 |
0,358 |
|
1,3336 |
0,428 |
|
1,3337 |
0,498 |
|
1,3338 |
0,567 |
|
1,3339 |
0,637 |
|
1,3340 |
0,707 |
|
1,3341 |
0,776 |
|
1,3342 |
0,846 |
|
1,3343 |
0,915 |
|
1,3344 |
0,985 |
|
1,3345 |
1,054 |
|
1,3346 |
1,124 |
|
1,3347 |
1,193 |
|
1,3348 |
1,263 |
|
1,3349 |
1,332 |
|
1,3350 |
1,401 |
|
1,3351 |
1,470 |
|
1,3352 |
1,540 |
|
1,3353 |
1,609 |
|
1,3354 |
1,678 |
|
1,3355 |
1,747 |
|
1,3356 |
1,816 |
|
1,3357 |
1,885 |
|
1,3358 |
1,954 |
|
1,3359 |
2,023 |
|
1,3360 |
2,092 |
|
1,3361 |
2,161 |
|
1,3362 |
2,230 |
|
1,3363 |
2,299 |
|
1,3364 |
2,367 |
|
1,3365 |
2,436 |
|
1,3366 |
2,505 |
|
1,3367 |
2,574 |
|
1,3368 |
2,642 |
|
1,3369 |
2,711 |
|
1,3370 |
2,779 |
|
1,3371 |
2,848 |
|
1,3372 |
2,917 |
|
1,3373 |
2,985 |
|
1,3374 |
3,053 |
|
1,3375 |
3,122 |
|
1,3376 |
3,190 |
|
1,3377 |
3,259 |
|
1,3378 |
3,327 |
|
1,3379 |
3,395 |
|
1,3380 |
3,463 |
|
1,3381 |
3,532 |
|
1,3382 |
3,600 |
|
1,3383 |
3,668 |
|
1,3384 |
3,736 |
|
1,3385 |
3,804 |
|
1,3386 |
3,872 |
|
1,3387 |
3,940 |
|
1,3388 |
4,008 |
|
1,3389 |
4,076 |
|
1,3390 |
4,144 |
|
1,3391 |
4,212 |
|
1,3392 |
4,279 |
|
1,3393 |
4,347 |
|
1,3394 |
4,415 |
|
1,3395 |
4,483 |
|
1,3396 |
4,550 |
|
1,3397 |
4,618 |
|
1,3398 |
4,686 |
|
1,3399 |
4,753 |
|
1,3400 |
4,821 |
|
1,3401 |
4,888 |
|
1,3402 |
4,956 |
|
1,3403 |
5,023 |
|
1,3404 |
5,091 |
|
1,3405 |
5,158 |
|
1,3406 |
5,225 |
|
1,3407 |
5,293 |
|
1,3408 |
5,360 |
|
1,3409 |
5,427 |
|
1,3410 |
5,494 |
|
1,3411 |
5,562 |
|
1,3412 |
5,629 |
|
1,3413 |
5,696 |
|
1,3414 |
5,763 |
|
1,3415 |
5,830 |
|
1,3416 |
5,897 |
|
1,3417 |
5,964 |
|
1,3418 |
6,031 |
|
1,3419 |
6,098 |
|
1,3420 |
6,165 |
|
1,3421 |
6,231 |
|
1,3422 |
6,298 |
|
1,3423 |
6,365 |
|
1,3424 |
6,432 |
|
1,3425 |
6,498 |
|
1,3426 |
6,565 |
|
1,3427 |
6,632 |
|
1,3428 |
6,698 |
|
1,3429 |
6,765 |
|
1,3430 |
6,831 |
|
1,3431 |
6,898 |
|
1,3432 |
6,964 |
|
1,3433 |
7,031 |
|
1,3434 |
7,097 |
|
1,3435 |
7,164 |
|
1,3436 |
7,230 |
|
1,3437 |
7,296 |
|
1,3438 |
7,362 |
|
1,3439 |
7,429 |
|
1,3440 |
7,495 |
|
1,3441 |
7,561 |
|
1,3442 |
7,627 |
|
1,3443 |
7,693 |
|
1,3444 |
7,759 |
|
1,3445 |
7,825 |
|
1,3446 |
7,891 |
|
1,3447 |
7,957 |
|
1,3448 |
8,023 |
|
1,3449 |
8,089 |
|
1,3450 |
8,155 |
|
1,3451 |
8,221 |
|
1,3452 |
8,287 |
|
1,3453 |
8,352 |
|
1,3454 |
8,418 |
|
1,3455 |
8,484 |
|
1,3456 |
8,550 |
|
1,3457 |
8,615 |
|
1&xxxx;3458 |
8,681 |
|
1,3459 |
8,746 |
|
1,3460 |
8,812 |
|
1,3461 |
8,878 |
|
1,3462 |
8,943 |
|
1,3463 |
9,008 |
|
1,3464 |
9,074 |
|
1,3465 |
9,139 |
|
1,3466 |
9,205 |
|
1,3467 |
9,270 |
|
1,3468 |
9,335 |
|
1,3469 |
9,400 |
|
1,3470 |
9,466 |
|
1,3471 |
9,531 |
|
1,3472 |
9,596 |
|
1,3473 |
9,661 |
|
1,3474 |
9,726 |
|
1,3475 |
9,791 |
|
1,3476 |
9,856 |
|
1,3477 |
9,921 |
|
1,3478 |
9,986 |
|
1,3479 |
10,051 |
|
1,3480 |
10,116 |
|
1,3481 |
10,181 |
|
1,3482 |
10,246 |
|
1,3483 |
10,311 |
|
1,3484 |
10,375 |
|
1,3485 |
10,440 |
|
1,3486 |
10,505 |
|
1,3487 |
10,570 |
|
1,3488 |
10,634 |
|
1,3489 |
10,699 |
|
1,3490 |
10,763 |
|
1,3491 |
10,828 |
|
1,3492 |
10,892 |
|
1,3493 |
10,957 |
|
1,3494 |
11,021 |
|
1,3495 |
11,086 |
|
1,3496 |
11,150 |
|
1,3497 |
11,215 |
|
1,3498 |
11,279 |
|
1,3499 |
11,343 |
|
1,3500 |
11,407 |
|
1,3501 |
11,472 |
|
1,3502 |
11,536 |
|
1,3503 |
11,600 |
|
1,3504 |
11,664 |
|
1,3505 |
11,728 |
|
1,3506 |
11,792 |
|
1,3507 |
11,856 |
|
1,3508 |
11,920 |
|
1,3509 |
11,984 |
|
1,3510 |
12,048 |
|
1,3511 |
12,112 |
|
1,3512 |
12,176 |
|
1,3513 |
12,240 |
|
1,3514 |
12,304 |
|
1,3515 |
12,368 |
|
1,3516 |
12,431 |
|
1,3517 |
12,495 |
|
1,3518 |
12,559 |
|
1,3519 |
12,623 |
|
1,3520 |
12,686 |
|
1,3521 |
12,750 |
|
1,3522 |
12,813 |
|
1,3523 |
12,877 |
|
1,3524 |
12,940 |
|
1,3525 |
13,004 |
|
1,3526 |
13,067 |
|
1,3527 |
13,131 |
|
1,3528 |
13,194 |
|
1,3529 |
13,258 |
|
1,3530 |
13,321 |
|
1,3531 |
13,384 |
|
1,3532 |
13,448 |
|
1,3533 |
13,511 |
|
1,3534 |
13,574 |
|
1,3535 |
13,637 |
|
1,3536 |
13,700 |
|
1,3537 |
13,763 |
|
1,3538 |
13,826 |
|
1,3539 |
13,890 |
|
1,3540 |
13,953 |
|
1,3541 |
14,016 |
|
1,3542 |
14,079 |
|
1,3543 |
14,141 |
|
1,3544 |
14,204 |
|
1,3545 |
14,267 |
|
1,3546 |
14,330 |
|
1,3547 |
14,393 |
|
1,3548 |
14,456 |
|
1,3549 |
14,518 |
|
1,3550 |
14,581 |
|
1,3551 |
14,644 |
|
1,3552 |
14,707 |
|
1,3553 |
14,769 |
|
1,3554 |
14,832 |
|
1,3555 |
14,894 |
|
1,3556 |
14,957 |
|
1,3557 |
15,019 |
|
1,3558 |
15,082 |
|
1,3559 |
15,144 |
|
1,3560 |
15,207 |
|
1,3561 |
15,269 |
|
1,3562 |
15,332 |
|
1,3563 |
15,394 |
|
1,3564 |
15,456 |
|
1,3565 |
15,518 |
|
1,3566 |
15,581 |
|
1,3567 |
15,643 |
|
1,3568 |
15,705 |
|
1,3569 |
15,767 |
|
1,3570 |
15,829 |
|
1,3571 |
15,891 |
|
1,3572 |
15,953 |
|
1,3573 |
16,016 |
|
1,3574 |
16,078 |
|
1,3575 |
16,140 |
|
1,3576 |
16,201 |
|
1,3577 |
16,263 |
|
1,3578 |
16,325 |
|
1,3579 |
16,387 |
|
1,3580 |
16,449 |
|
1,3581 |
16,511 |
|
1,3582 |
16,573 |
|
1,3583 |
16,634 |
|
1,3584 |
16,696 |
|
1,3585 |
16,758 |
|
1,3586 |
16,819 |
|
1,3587 |
16,881 |
|
1,3588 |
16,943 |
|
1,3389 |
17,004 |
|
1,3590 |
17,066 |
|
1,3591 |
17,127 |
|
1,3592 |
17,189 |
|
1,3593 |
17,250 |
|
1,3594 |
17,311 |
|
1,3595 |
17,373 |
|
1,3596 |
17,434 |
|
1,3597 |
17,496 |
|
1,3598 |
17,557 |
|
1,3599 |
17,618 |
|
1,3600 |
17,679 |
|
1,3601 |
17,741 |
|
1,3602 |
17,802 |
|
1,3603 |
17,863 |
|
1,3604 |
17,924 |
|
1,3605 |
17,985 |
|
1,3606 |
18,046 |
|
1,3607 |
18,107 |
|
1,3608 |
18,168 |
|
1,3609 |
18,229 |
|
1,3610 |
18,290 |
|
1,3610 |
18,351 |
|
1,3611 |
18,412 |
|
1,3613 |
18,473 |
|
1,3614 |
18,534 |
|
1,3615 |
18,595 |
|
1,3616 |
18,655 |
|
1,3617 |
18,716 |
|
1,3618 |
18,777 |
|
1,3619 |
18,837 |
|
1,3620 |
18,898 |
|
1,3621 |
18,959 |
|
1,3622 |
19,019 |
|
1,3623 |
19,080 |
|
1,3624 |
19,141 |
|
1,3625 |
19,201 |
|
1,3626 |
19,262 |
|
1,3627 |
19,322 |
|
1,3628 |
19,382 |
|
1,3629 |
19,443 |
|
1,3630 |
19,503 |
|
1,3631 |
19,564 |
|
1,3632 |
19,624 |
|
1,3633 |
19,684 |
|
1,3634 |
19,745 |
|
1,3635 |
19,805 |
|
1,3636 |
19,865 |
|
1,3637 |
19,925 |
|
1,3638 |
19,985 |
|
1,3639 |
20,045 |
|
1,3640 |
20,106 |
|
1.3641 |
20,166 |
|
1,3642 |
20,226 |
|
1,3643 |
20,286 |
|
1,3644 |
20,346 |
|
1,3645 |
20,406 |
|
1,3646 |
20,466 |
|
1,3647 |
20,525 |
|
1,3648 |
20,585 |
|
1,3649 |
20,645 |
|
1,3650 |
20,705 |
|
1,3651 |
20,765 |
|
1,3652 |
20,825 |
|
1,3653 |
20,884 |
|
1,3654 |
20,944 |
|
1,3655 |
21,004 |
|
1,3656 |
21,063 |
|
1,3657 |
21,123 |
|
1,3658 |
21,183 |
|
1,3659 |
21,242 |
|
1,3660 |
21,302 |
|
1,3661 |
21,361 |
|
1,3662 |
21,421 |
|
1,3563 |
21,480 |
|
1,3664 |
21,540 |
|
1,3665 |
21,599 |
|
1,3666 |
21,658 |
|
1,3667 |
21,718 |
|
1,3668 |
21,777 |
|
1,3669 |
21,836 |
|
1,3670 |
21,896 |
|
1,3671 |
21,955 |
|
1,3672 |
22,014 |
|
1,1673 |
22,073 |
|
1,3674 |
22,132 |
|
1,3675 |
22,192 |
|
1,3676 |
22,251 |
|
1,1677 |
22,310 |
|
1,3678 |
22,369 |
|
1,3679 |
22,428 |
|
1,3680 |
22,487 |
|
1,3681 |
22,546 |
|
1,3682 |
22,605 |
|
1,3683 |
22,664 |
|
1,3684 |
22,723 |
|
1,3685 |
22,781 |
|
1,3686 |
22,840 |
|
1,3687 |
22,899 |
|
1,3688 |
22,958 |
|
1,3689 |
23,017 |
|
1,3690 |
23,075 |
|
1,3691 |
23,134 |
|
1,3692 |
23,193 |
|
1,3693 |
23,251 |
|
1,3694 |
23,310 |
|
1,3695 |
23,369 |
|
1,3696 |
23,427 |
|
1,3697 |
23,486 |
|
1,3698 |
23,544 |
|
1,3699 |
23,603 |
|
1,3700 |
23,661 |
|
1,3701 |
23,720 |
|
1,3702 |
23,778 |
|
1,3703 |
23,836 |
|
1,3704 |
23,895 |
|
1,3705 |
23,953 |
|
1,3706 |
24,011 |
|
1,3707 |
24,070 |
|
1,3708 |
24,128 |
|
1,3709 |
24,186 |
|
1,3710 |
24,244 |
|
1,3711 |
24,302 |
|
1,3712 |
24,361 |
|
1,3713 |
24,419 |
|
1,3714 |
24,477 |
|
1,3715 |
24,535 |
|
1,3716 |
24,593 |
|
1,3717 |
24,651 |
|
1,3718 |
24,709 |
|
1,3719 |
24,767 |
|
1,3720 |
24,825 |
|
1,3721 |
24,883 |
|
1,3722 |
24,941 |
|
1,3723 |
24,998 |
|
1,3724 |
25,056 |
|
1,3725 |
25,114 |
|
1,3726 |
25,172 |
|
1,3727 |
25,230 |
|
1,3728 |
25287 |
|
1,3729 |
25,345 |
|
1,3730 |
25,403 |
|
1,3731 |
25,460 |
|
1,3732 |
25,518 |
|
1,3733 |
25,576 |
|
1,3734 |
25,633 |
|
1,3735 |
25,691 |
|
1,3736 |
25,748 |
|
1,3737 |
25,806 |
|
1,3738 |
25,863 |
|
1,3739 |
25,921 |
|
1,3740 |
25,978 |
|
1,3741 |
26,035 |
|
1,3742 |
26,093 |
|
1,3743 |
26,150 |
|
1,3744 |
26,207 |
|
1,3745 |
26,265 |
|
1,3746 |
26,322 |
|
1,3747 |
26,379 |
|
1,3748 |
26,436 |
|
1,3749 |
26,493 |
|
1,3750 |
26,551 |
|
1,3751 |
26,608 |
|
1,3752 |
26,665 |
|
1,3753 |
26,722 |
|
1,3754 |
26,779 |
|
1,3755 |
26,836 |
|
1,3756 |
26,893 |
|
1,3757 |
26,950 |
|
1,3758 |
27,007 |
|
1,3759 |
27,064 |
|
1,3760 |
27,121 |
|
1,3761 |
27,178 |
|
1,3762 |
27,234 |
|
1,3763 |
27,291 |
|
1,3764 |
27,348 |
|
1,3765 |
27,405 |
|
1,3765 |
27,462 |
|
1,3767 |
27,518 |
|
1,3768 |
27,575 |
|
1,3769 |
27,632 |
|
1,3770 |
27,688 |
|
1,3771 |
27,745 |
|
1,3772 |
27,802 |
|
1,3773 |
27,858 |
|
1,3774 |
27,915 |
|
1,3775 |
27,971 |
|
1,3776 |
28,028 |
|
1,3777 |
28,084 |
|
1,3778 |
28,141 |
|
1,3779 |
28,197 |
|
1,3780 |
28,253 |
|
1,3781 |
28,310 |
|
1,3782 |
28,366 |
|
1,3783 |
28,422 |
|
1,3784 |
28,479 |
|
1,3785 |
28,535 |
|
1,3786 |
28,591 |
|
1,3787 |
28,648 |
|
1,3788 |
28,704 |
|
1,3789 |
28,760 |
|
1,3790 |
28,816 |
|
1,3791 |
28,872 |
|
1,3792 |
28,928 |
|
1,3793 |
28,984 |
|
1,3794 |
29,040 |
|
1,3795 |
29,096 |
|
1,3796 |
29,152 |
|
1,3797 |
29,208 |
|
1,3798 |
29,264 |
|
1,3799 |
29,320 |
|
1,3800 |
29,376 |
|
1,3801 |
29,432 |
|
1,3802 |
29,488 |
|
1,3803 |
29,544 |
|
1,3804 |
29,600 |
|
1,3805 |
29,655 |
|
1,3806 |
29,711 |
|
1,3807 |
29,767 |
|
1,3808 |
29,823 |
|
1,3809 |
29,878 |
|
1,3810 |
29,934 |
|
1,3811 |
29,989 |
|
1,3812 |
30,045 |
|
1,3813 |
30,101 |
|
1,3814 |
30,156 |
|
1,3815 |
30,212 |
|
1,3816 |
30,267 |
|
1,3817 |
30,323 |
|
1,3818 |
30,378 |
|
1,3819 |
30,434 |
|
1,3820 |
30,489 |
|
1,3821 |
30,544 |
|
1,3822 |
30,600 |
|
1,3823 |
30,655 |
|
1,3824 |
30,711 |
|
1,3825 |
30,766 |
|
1,3826 |
30,821 |
|
1,3827 |
30,876 |
|
1,3828 |
30,932 |
|
1,3829 |
30,987 |
|
1,3830 |
31,042 |
|
1,3831 |
31,097 |
|
1,3832 |
31,152 |
|
1,3833 |
31,207 |
|
1,3834 |
31,262 |
|
1,3835 |
31,317 |
|
1,3836 |
31,372 |
|
1,3837 |
31,428 |
|
1,3838 |
31,482 |
|
1,3839 |
31,537 |
|
1,3840 |
31,592 |
|
1,3841 |
31,647 |
|
1,3842 |
31,702 |
|
1,3843 |
31,757 |
|
1,3844 |
31,812 |
|
1,3845 |
31,867 |
|
1,3846 |
31,922 |
|
1,3847 |
31,976 |
|
1,3848 |
32,031 |
|
1,3849 |
32,086 |
|
1,3850 |
32,140 |
|
1,3851 |
32,195 |
|
1,3852 |
32,250 |
|
1,3853 |
32,304 |
|
1,3854 |
32,359 |
|
1,3855 |
32,414 |
|
1,3856 |
32,468 |
|
1,3857 |
32,523 |
|
1,3858 |
32,577 |
|
1,3859 |
32,632 |
|
1,3860 |
32,686 |
|
1,3861 |
32,741 |
|
1,3862 |
32,795 |
|
1,3863 |
32,849 |
|
1,3864 |
32,904 |
|
1,3865 |
32,958 |
|
1,3866 |
33,013 |
|
1,3867 |
33,067 |
|
1,3868 |
33,121 |
|
1,3889 |
33,175 |
|
1,3870 |
33,230 |
|
1,3871 |
33,284 |
|
1,3872 |
33,338 |
|
1,3873 |
33,392 |
|
1,3874 |
33,446 |
|
1,3875 |
33,500 |
|
1,3876 |
33,555 |
|
1,3877 |
33,609 |
|
1,3878 |
33,663 |
|
1,3879 |
33,717 |
|
1,3880 |
33,771 |
|
1,3881 |
33,825 |
|
1,3882 |
33,879 |
|
1,3883 |
33,933 |
|
1,3884 |
33,987 |
|
1,3885 |
34,040 |
|
1,3886 |
34,094 |
|
1,3887 |
34,148 |
|
1,3888 |
34,202 |
|
1,3889 |
34,256 |
|
1,3890 |
34,310 |
|
1,3891 |
34,363 |
|
1,3892 |
34,417 |
|
1,3893 |
34,471 |
|
1,3894 |
34,524 |
|
1,3895 |
34,578 |
|
1,3896 |
34,632 |
|
1,3897 |
34,685 |
|
1,3898 |
34,739 |
|
1,3899 |
34,793 |
|
1,3900 |
34,846 |
|
1,3901 |
34,900 |
|
1,3902 |
34,953 |
|
1,3903 |
35,007 |
|
1,3904 |
35,060 |
|
1,3905 |
35,114 |
|
1,3906 |
35,167 |
|
1,3907 |
35,220 |
|
1,3908 |
35,274 |
|
1,3909 |
35,327 |
|
1,3910 |
35,380 |
|
1,3911 |
35,434 |
|
1,3912 |
35,487 |
|
1,3913 |
35,540 |
|
1,3914 |
35,593 |
|
1,3915 |
35,647 |
|
1,3916 |
35,700 |
|
1,3917 |
35,753 |
|
1,3918 |
35,806 |
|
1,3919 |
35,859 |
|
1,3920 |
35,912 |
|
1,3921 |
35,966 |
|
1,3922 |
36,019 |
|
1,3923 |
36,072 |
|
1,3924 |
36,125 |
|
1,3925 |
36,178 |
|
1,3926 |
36,231 |
|
1,3927 |
36,284 |
|
1,3928 |
36,337 |
|
1,3929 |
36,389 |
|
1,3930 |
36,442 |
|
1,3931 |
36,495 |
|
1,3932 |
36,548 |
|
1,3933 |
36,601 |
|
1,3934 |
36,654 |
|
1,3935 |
36,706 |
|
1,3936 |
36,759 |
|
1,3937 |
36,812 |
|
1,3938 |
36,865 |
|
1,3939 |
36,917 |
|
1,3940 |
36,970 |
|
1,3941 |
37,023 |
|
1,3942 |
37,075 |
|
1,3943 |
37,128 |
|
1,3944 |
37,180 |
|
1,3945 |
37,233 |
|
1,3946 |
37,286 |
|
1,3947 |
37,338 |
|
1,3948 |
37,391 |
|
1,3949 |
37,443 |
|
1,3950 |
37,495 |
|
1,3951 |
37,548 |
|
1,3952 |
37,600 |
|
1,3953 |
37,653 |
|
1,3954 |
37,705 |
|
1,3955 |
37,757 |
|
1,3956 |
37,810 |
|
1,3957 |
37,862 |
|
1,3958 |
37,914 |
|
1,3959 |
37,967 |
|
1,3960 |
38,019 |
|
1,3961 |
38,071 |
|
1,3962 |
38,123 |
|
1,3963 |
38,175 |
|
1,3964 |
38,228 |
|
1,3965 |
38,280 |
|
1,3966 |
38,332 |
|
1,3967 |
38,384 |
|
1,3968 |
38,436 |
|
1,3969 |
38,488 |
|
1,3970 |
38,540 |
|
1,3971 |
38,592 |
|
1,3972 |
38,644 |
|
1,3973 |
38,696 |
|
1,3974 |
38,748 |
|
1,3975 |
38,800 |
|
1,3976 |
38,852 |
|
1,3977 |
38,904 |
|
1,3978 |
38,955 |
|
1,3979 |
39,007 |
|
1,3980 |
39,059 |
|
1,3981 |
39,111 |
|
1,3982 |
39,163 |
|
1,3983 |
39,214 |
|
1,3984 |
39,266 |
|
1,3985 |
39,318 |
|
1,3986 |
39,370 |
|
1,3987 |
39,421 |
|
1,3988 |
39,473 |
|
1,3989 |
39,525 |
|
1,3990 |
39,576 |
|
1,3991 |
39,628 |
|
1,3992 |
39,679 |
|
1,3993 |
39,731 |
|
1,3994 |
39,782 |
|
1,3995 |
39,834 |
|
1,3996 |
39,885 |
|
1,3997 |
39,937 |
|
1,3998 |
39,988 |
|
1,3999 |
40,040 |
|
1,4000 |
40,091 |
|
1,4001 |
40,142 |
|
1,4002 |
40,194 |
|
1,4003 |
40,245 |
|
1,4004 |
40,296 |
|
1,4005 |
40,348 |
|
1,4006 |
40,399 |
|
1,4007 |
40,450 |
|
1,4008 |
40,501 |
|
1,4009 |
40,553 |
|
1,4010 |
40,604 |
|
1,4011 |
40,655 |
|
1,4012 |
40,706 |
|
1,4013 |
40,757 |
|
1,4014 |
40,808 |
|
1,4015 |
40,860 |
|
1,4016 |
40,911 |
|
1,4017 |
40,962 |
|
1,4018 |
41,013 |
|
1,4019 |
41,064 |
|
1,4020 |
41,115 |
|
1,4021 |
41,166 |
|
1,4022 |
41,217 |
|
1,4023 |
41,268 |
|
1,4024 |
41,318 |
|
1,4025 |
41,369 |
|
1,4026 |
41,420 |
|
1,4027 |
41,471 |
|
1,4028 |
41,522 |
|
1,4029 |
41,573 |
|
1,4030 |
41,623 |
|
1,4031 |
41,674 |
|
1,4032 |
41,725 |
|
1,4033 |
41,776 |
|
1,4034 |
41,826 |
|
1,4035 |
41,877 |
|
1,4036 |
41,928 |
|
1,4037 |
41,978 |
|
1,4038 |
42,029 |
|
1,4039 |
42,080 |
|
1,4040 |
42,130 |
|
1,4041 |
42,181 |
|
1,4042 |
42,231 |
|
1,4043 |
42,282 |
|
1,4044 |
42,332 |
|
1,4045 |
42,383 |
|
1,4046 |
42,433 |
|
1,4047 |
42,484 |
|
1,4048 |
42,534 |
|
1,4049 |
42,585 |
|
1,4050 |
42,635 |
|
1,4051 |
42,685 |
|
1,4052 |
42,736 |
|
1,4053 |
42,786 |
|
1,4054 |
42,836 |
|
1,4055 |
42,887 |
|
1,4056 |
42,937 |
|
1,4057 |
42,987 |
|
1,4058 |
43,037 |
|
1,4059 |
43,088 |
|
1,4060 |
43,138 |
|
1,4061 |
43,188 |
|
1,4062 |
43,238 |
|
1,4063 |
43,288 |
|
1,4064 |
43,338 |
|
1,4065 |
43,388 |
|
1,4066 |
43,439 |
|
1,4067 |
43,489 |
|
1,4068 |
43,539 |
|
1,4069 |
43,589 |
|
1,4070 |
43,639 |
|
1,4071 |
43,689 |
|
1,4072 |
43739 |
|
1,4073 |
43,789 |
|
1,4074 |
43,838 |
|
1,4075 |
43,888 |
|
1,4076 |
43,938 |
|
1,4077 |
43,988 |
|
1,4078 |
44,038 |
|
1,4079 |
44,088 |
|
1,4080 |
44,138 |
|
1,4081 |
44,187 |
|
1,4082 |
44,237 |
|
1,4083 |
44,287 |
|
1,4084 |
44,337 |
|
1,4085 |
44,386 |
|
1,4086 |
44,436 |
|
1,4087 |
44,486 |
|
1,4088 |
44,535 |
|
1,4089 |
44,585 |
|
1,4090 |
44,635 |
|
1,4091 |
44,684 |
|
1,4092 |
44,734 |
|
1,4093 |
44,783 |
|
1,4094 |
44,833 |
|
1,4095 |
44,882 |
|
1,4096 |
44,932 |
|
1,4097 |
44,981 |
|
1,4098 |
45,031 |
|
1,4099 |
45,080 |
|
1,4100 |
45,130 |
|
1,4101 |
43,179 |
|
1,4102 |
45,228 |
|
1,4103 |
45,278 |
|
1,4104 |
45,327 |
|
1,4105 |
45,376 |
|
1,4106 |
45,426 |
|
1,4107 |
45,475 |
|
1,4108 |
45,524 |
|
1,4109 |
45,574 |
|
1,4110 |
45,623 |
|
1,4111 |
45,672 |
|
1,4112 |
45,721 |
|
1,4113 |
45,770 |
|
1,4114 |
45,820 |
|
1,4115 |
45,869 |
|
1,4116 |
45,918 |
|
1,4117 |
46,967 |
|
1,4118 |
46,016 |
|
1,4119 |
46,065 |
|
1,4120 |
46,114 |
|
1,4121 |
46,163 |
|
1,4122 |
46,212 |
|
1,4123 |
46,261 |
|
1,4124 |
46,310 |
|
1,4125 |
46,359 |
|
1,4126 |
46,408 |
|
1,4127 |
46,457 |
|
1,4128 |
46,506 |
|
1,4129 |
46,555 |
|
1,4130 |
46,604 |
|
1,4131 |
46,652 |
|
1,4132 |
46,701 |
|
1,4133 |
46,750 |
|
1,4134 |
46,799 |
|
1,4135 |
46,848 |
|
1,4136 |
46,896 |
|
1,4137 |
46,945 |
|
1,4138 |
46,994 |
|
1,4139 |
47,043 |
|
1,4140 |
47,091 |
|
1,4141 |
47,140 |
|
1,4141 |
47,188 |
|
1,4143 |
47,237 |
|
1,4144 |
47,286 |
|
1,4145 |
47,334 |
|
1,4146 |
47,383 |
|
1,4147 |
47,431 |
|
1,4148 |
47,480 |
|
1,4149 |
47,528 |
|
1,4150 |
47,577 |
|
1,4151 |
47,625 |
|
1,4152 |
47,674 |
|
1,4153 |
47,722 |
|
1,4154 |
47,771 |
|
1,4155 |
47,819 |
|
1,4156 |
47,868 |
|
1,4157 |
47,916 |
|
1,4158 |
47,964 |
|
1,4159 |
48,013 |
|
1,4160 |
48,061 |
|
1,4161 |
48,109 |
|
1,4162 |
48,158 |
|
1,4163 |
48,206 |
|
1,4164 |
48,254 |
|
1,4165 |
48,302 |
|
1,4166 |
48,350 |
|
1,4167 |
48,399 |
|
1,4168 |
48,447 |
|
1,4169 |
48,495 |
|
1,4170 |
48,543 |
|
1,4171 |
48,591 |
|
1,4172 |
48,639 |
|
1,4173 |
48,687 |
|
1,4174 |
48,735 |
|
1,4175 |
48,784 |
|
1,4176 |
48,832 |
|
1,4177 |
48,880 |
|
1,4178 |
48,928 |
|
1,4179 |
48,976 |
|
1,4180 |
49,023 |
|
1,4181 |
49,071 |
|
1,4182 |
49,119 |
|
1,4183 |
49,167 |
|
1,4184 |
49,215 |
|
1,4185 |
49,263 |
|
1,4186 |
49,311 |
|
1,4187 |
49,359 |
|
1,4188 |
49,407 |
|
1,4189 |
49,454 |
|
1,4190 |
49,502 |
|
1,4191 |
49,550 |
|
1,4192 |
49,598 |
|
1,4193 |
49,645 |
|
1,4194 |
49,693 |
|
1,4195 |
49,741 |
|
1,4196 |
49,788 |
|
1,4197 |
49,836 |
|
1,4198 |
49,884 |
|
1,4199 |
49,931 |
|
1,4200 |
49,979 |
|
1,4201 |
50,027 |
|
1,4202 |
50,074 |
|
1,4203 |
50,122 |
|
1,4204 |
50,169 |
|
1,4205 |
50,217 |
|
1,4206 |
50,264 |
|
1,4207 |
50,312 |
|
1,4208 |
50,359 |
|
1,4209 |
50,407 |
|
1,4210 |
50,454 |
|
1,4211 |
50,502 |
|
1,4212 |
50,549 |
|
1,4213 |
50,596 |
|
1,4214 |
50,644 |
|
1,4215 |
50,691 |
|
1,4216 |
50,738 |
|
1,4217 |
50,786 |
|
1,4218 |
50,833 |
|
1,4219 |
50,880 |
|
1,4220 |
50,928 |
|
1,4221 |
50,975 |
|
1,4222 |
51,022 |
|
1,4223 |
51,069 |
|
1,4224 |
51,116 |
|
1,4225 |
51,164 |
|
1,4226 |
51,211 |
|
1,4227 |
51,258 |
|
1,4228 |
51305 |
|
1,4229 |
51,352 |
|
1,4230 |
51,399 |
|
1,4231 |
51,446 |
|
1,4232 |
51,493 |
|
1,4233 |
51,540 |
|
1,4234 |
51,587 |
|
1,4235 |
51,634 |
|
1,4236 |
51,681 |
|
1,4237 |
51,728 |
|
1,4238 |
51,775 |
|
1,4239 |
51,822 |
|
1,4240 |
51,869 |
|
1,4241 |
51,916 |
|
1,4242 |
51,963 |
|
1,4243 |
52,010 |
|
1,4244 |
52,057 |
|
1,4245 |
52,104 |
|
1,4246 |
52,150 |
|
1,4247 |
52,197 |
|
1,4248 |
52,244 |
|
1,4249 |
52,291 |
|
1,4250 |
52,338 |
|
1,4251 |
52,384 |
|
1,4252 |
52,431 |
|
1,4253 |
52,478 |
|
1,4254 |
52,524 |
|
1,4255 |
52,571 |
|
1,4256 |
52,618 |
|
1,4257 |
52,664 |
|
1,4258 |
52,711 |
|
1,4259 |
52,758 |
|
1,4260 |
52,804 |
|
1,4261 |
52,851 |
|
1,4261 |
52,897 |
|
1,4263 |
52,944 |
|
1,4264 |
52,990 |
|
1,4265 |
53,037 |
|
1,4266 |
53,083 |
|
1,4267 |
53,130 |
|
1,4268 |
53,176 |
|
1,4269 |
53,223 |
|
1,4270 |
53,269 |
|
1,4271 |
53,316 |
|
1,4272 |
53,362 |
|
1,4273 |
53,408 |
|
1,4274 |
53,455 |
|
1,4275 |
53,501 |
|
1,4276 |
53,548 |
|
1,4277 |
53,594 |
|
1,4278 |
53,640 |
|
1,4279 |
53,686 |
|
1,4280 |
53,733 |
|
1,4281 |
53,779 |
|
1,4282 |
53,825 |
|
1,4283 |
53,871 |
|
1,4284 |
53,918 |
|
1,4285 |
53,964 |
|
1,4286 |
54,010 |
|
1,4287 |
54,056 |
|
1,4288 |
54,102 |
|
1,4289 |
54,148 |
|
1,4290 |
54,194 |
|
1,4291 |
54,241 |
|
1,4292 |
54,287 |
|
1,4293 |
54,333 |
|
1,4294 |
54,379 |
|
1,4295 |
54,425 |
|
1,4296 |
54,471 |
|
1,4297 |
54,517 |
|
1,4298 |
54,563 |
|
1,4299 |
54,609 |
|
1,4300 |
54,655 |
|
1,4301 |
54,701 |
|
1,4302 |
54,746 |
|
1,4303 |
54,792 |
|
1,4304 |
54,838 |
|
1,4305 |
54,884 |
|
1,4306 |
54,930 |
|
1,4307 |
54,976 |
|
1,4308 |
55,022 |
|
1,4309 |
55067 |
|
1,4310 |
55,113 |
|
1,4311 |
55,159 |
|
1,4312 |
55,205 |
|
1,4313 |
55,250 |
|
1,4314 |
55,296 |
|
1,4315 |
55,342 |
|
1,4316 |
55,388 |
|
1,4317 |
55,433 |
|
1,4318 |
55,479 |
|
1,4319 |
55,524 |
|
1,4320 |
55,570 |
|
1,4321 |
55,616 |
|
1,4322 |
55,661 |
|
1,4323 |
55,707 |
|
1,4324 |
55,752 |
|
1,4325 |
55,798 |
|
1,4326 |
55,844 |
|
1,4327 |
55,889 |
|
1,4328 |
55,935 |
|
1,4329 |
55,980 |
|
1,4330 |
56,026 |
|
1,4331 |
56,071 |
|
1,4332 |
56,116 |
|
1,4133 |
56,162 |
|
1,4334 |
56,207 |
|
1,4335 |
56,253 |
|
1,4336 |
56,298 |
|
1,4337 |
56,343 |
|
1,4338 |
56,389 |
|
1,4339 |
56,434 |
|
1,4340 |
56,479 |
|
1,4341 |
56,525 |
|
1,4342 |
56,570 |
|
1,4343 |
56,615 |
|
1,4344 |
56,660 |
|
1,4345 |
56,706 |
|
1,4346 |
56,751 |
|
1,4347 |
56,796 |
|
1,4348 |
56,841 |
|
1,4349 |
56,887 |
|
1,4350 |
56,932 |
|
1,4351 |
56,977 |
|
1,4352 |
57,022 |
|
1,4353 |
57,067 |
|
1,4354 |
57,112 |
|
1,4355 |
57,157 |
|
1,4356 |
57,202 |
|
1,4357 |
57,247 |
|
14358 |
57,292 |
|
1,4359 |
57,337 |
|
1,4360 |
57,382 |
|
1,4361 |
57,427 |
|
1,4362 |
57,472 |
|
1,4363 |
57,517 |
|
1,4364 |
57,562 |
|
1,4365 |
57,607 |
|
1,4366 |
57,652 |
|
1,4367 |
57,697 |
|
1,4368 |
57,742 |
|
1,4369 |
57,787 |
|
1,4370 |
57,832 |
|
1,4371 |
57,877 |
|
1,4372 |
57,921 |
|
1,4373 |
57,966 |
|
1,4374 |
58,011 |
|
1,4375 |
58,056 |
|
1,4376 |
58,101 |
|
1,4377 |
58,145 |
|
1,4378 |
58,190 |
|
1,4379 |
58,235 |
|
1,4380 |
58,279 |
|
1,4381 |
58,324 |
|
1,4382 |
58,369 |
|
1,4383 |
58,413 |
|
1,4384 |
53,458 |
|
1,4385 |
58,503 |
|
1,4386 |
58,547 |
|
1,4387 |
58,592 |
|
1,4388 |
58,637 |
|
1,4389 |
58,681 |
|
1,4390 |
58,726 |
|
1,4391 |
58,770 |
|
1,4392 |
58,815 |
|
1,4393 |
58,859 |
|
1,4394 |
58,904 |
|
1,4395 |
58,948 |
|
1,4396 |
58,993 |
|
1,4397 |
59,037 |
|
1,4398 |
59,082 |
|
1,4399 |
59,126 |
|
1,4400 |
59,170 |
|
1,4401 |
59,215 |
|
1,4402 |
59,259 |
|
1,4403 |
59,304 |
|
1,4404 |
59,348 |
|
1,4405 |
59,392 |
|
1,4406 |
59,437 |
|
1,4407 |
59,481 |
|
1,4408 |
59,525 |
|
1,4409 |
59,569 |
|
1,4410 |
59,614 |
|
1,4411 |
59,658 |
|
1,4412 |
59,702 |
|
1,4413 |
59,746 |
|
1,4414 |
59,791 |
|
1,4415 |
59,835 |
|
1,4416 |
59,879 |
|
1,4417 |
59,923 |
|
1,4418 |
59,967 |
|
1,4419 |
60,011 |
|
1,4420 |
60,056 |
|
1,4421 |
60,100 |
|
1,4422 |
60,144 |
|
1,4423 |
60,188 |
|
1,4424 |
60,232 |
|
1,4425 |
60,276 |
|
1,4426 |
60,320 |
|
1,4427 |
60,364 |
|
1,4428 |
60,408 |
|
1,4429 |
60,452 |
|
1,4430 |
60,496 |
|
1,4431 |
60,540 |
|
1,4432 |
60,584 |
|
1,4433 |
60,628 |
|
1,4434 |
60,672 |
|
1,4435 |
60,716 |
|
1,4436 |
60,759 |
|
1,4437 |
60,803 |
|
1,4438 |
60,847 |
|
1,4439 |
60,891 |
|
1,4440 |
60,935 |
|
1,4441 |
60,979 |
|
1,4442 |
61,023 |
|
1,4443 |
61,066 |
|
1,4444 |
61,110 |
|
1,4445 |
61,154 |
|
1,4446 |
61,198 |
|
1,4447 |
61,241 |
|
1,4448 |
61,285 |
|
1,4449 |
61,329 |
|
1,4450 |
61,372 |
|
1,4451 |
61,416 |
|
1,4452 |
61,460 |
|
1,4453 |
61,503 |
|
1,4454 |
61,547 |
|
1,4455 |
61,591 |
|
1,4456 |
61,634 |
|
1,4457 |
61,678 |
|
1,4458 |
61,721 |
|
1,4459 |
61,765 |
|
1,4460 |
61,809 |
|
1,4461 |
61,852 |
|
1,4462 |
61,896 |
|
1,4463 |
61,939 |
|
1,4464 |
62,983 |
|
1,4465 |
62,026 |
|
1,4466 |
62,070 |
|
1,4467 |
62,113 |
|
1,4468 |
62,156 |
|
1,4469 |
62,200 |
|
1,4470 |
62,243 |
|
1,4471 |
62,287 |
|
1,4472 |
62,330 |
|
1,4473 |
62,373 |
|
1,4474 |
62,417 |
|
1,4475 |
62,460 |
|
1,4476 |
62,503 |
|
1,4477 |
62,547 |
|
1,4478 |
62,590 |
|
14479 |
62,633 |
|
1,4480 |
62,677 |
|
1,4481 |
62,720 |
|
1,4482 |
62,763 |
|
1,4483 |
62,806 |
|
1,4184 |
62,849 |
|
1,4485 |
62,893 |
|
1,4486 |
62,936 |
|
1,4487 |
62,979 |
|
1,4488 |
63,022 |
|
1,4489 |
63,065 |
|
1,4490 |
63,108 |
|
1,4491 |
63,152 |
|
1,4492 |
63,195 |
|
1,4493 |
63,238 |
|
1,4494 |
63,281 |
|
1,4495 |
63,324 |
|
1,4496 |
63,367 |
|
1,4497 |
63,410 |
|
1,4498 |
63,453 |
|
1,4499 |
63,496 |
|
1,4500 |
63,539 |
|
1,4501 |
63,582 |
|
1,4502 |
63,625 |
|
1,4503 |
63,668 |
|
1,4304 |
63,711 |
|
1,4505 |
63,754 |
|
1,4506 |
63,797 |
|
1,4507 |
63,840 |
|
1,4508 |
63,882 |
|
1,4509 |
63,925 |
|
1,4510 |
63,968 |
|
1,4511 |
64,011 |
|
1,4512 |
64,054 |
|
1,4513 |
64,097 |
|
1,4514 |
64,139 |
|
1,4515 |
64,182 |
|
1,4516 |
64,225 |
|
1,4517 |
64,268 |
|
1,4518 |
64,311 |
|
1,4519 |
64,353 |
|
1,4520 |
64,396 |
|
1,4521 |
64,439 |
|
1,4522 |
64,481 |
|
1,4523 |
64,524 |
|
1,4524 |
64,567 |
|
1,4525 |
64,609 |
|
1,4526 |
64,652 |
|
1,4527 |
64,695 |
|
1,4528 |
64,737 |
|
1,4529 |
64,780 |
|
1,4530 |
64,823 |
|
1,4531 |
64,865 |
|
1,4532 |
64,908 |
|
1,4533 |
64,950 |
|
1,4534 |
64,993 |
|
1,4535 |
65,035 |
|
1,4536 |
65,078 |
|
1,4537 |
65,120 |
|
1,4538 |
65,163 |
|
1,4539 |
65,205 |
|
1,4540 |
65,248 |
|
1,4541 |
65,290 |
|
1,4542 |
65,333 |
|
1,4543 |
65,375 |
|
1,4544 |
65,417 |
|
1,4545 |
65,460 |
|
1,4546 |
65,502 |
|
1,4547 |
65,544 |
|
1,4548 |
65,587 |
|
1,4549 |
65,629 |
|
1,4550 |
65,672 |
|
1,4551 |
65,714 |
|
1,4552 |
65,756 |
|
1,4553 |
65,798 |
|
1,4554 |
65,841 |
|
1,4555 |
65,883 |
|
1,4556 |
65,925 |
|
1,4557 |
65,967 |
|
1,4558 |
66,010 |
|
1,4559 |
66,052 |
|
1,4560 |
66,094 |
|
1,4561 |
66,136 |
|
1,4562 |
66,178 |
|
1,4563 |
66,221 |
|
1,4564 |
66,263 |
|
1,4565 |
66,305 |
|
1,4566 |
66,347 |
|
1,4567 |
66,389 |
|
1,4568 |
66,431 |
|
1,4569 |
66,473 |
|
1,4570 |
66,515 |
|
1,4571 |
66,557 |
|
1,4572 |
66,599 |
|
1,4573 |
66,641 |
|
1,4574 |
66,683 |
|
1,4575 |
66,725 |
|
1,4576 |
66,767 |
|
1,4577 |
66,809 |
|
1,4578 |
66,851 |
|
1,4579 |
66,893 |
|
1,4580 |
66,935 |
|
1,4581 |
66,977 |
|
1,4582 |
67,019 |
|
1,4583 |
67,061 |
|
1,4584 |
67,103 |
|
1,4585 |
67,145 |
|
1,4586 |
67,186 |
|
1,4587 |
67,228 |
|
1,4588 |
67,270 |
|
1,4589 |
67,312 |
|
1,4590 |
67,354 |
|
1,4591 |
67,396 |
|
1,4592 |
67,437 |
|
1,4593 |
67,479 |
|
1,4594 |
67,521 |
|
1,4595 |
67,563 |
|
1,4596 |
67,604 |
|
1,4597 |
67,646 |
|
1,4598 |
67,688 |
|
1,4599 |
67,729 |
|
1,4600 |
67,771 |
|
1,4601 |
67,813 |
|
1,4602 |
67,854 |
|
1,4603 |
67,896 |
|
1,4604 |
67,938 |
|
1,4605 |
67,979 |
|
1,4606 |
68,021 |
|
1,4607 |
68,063 |
|
1,4608 |
68,104 |
|
1,4609 |
68,146 |
|
1,4610 |
68,187 |
|
1,4611 |
68,229 |
|
1,4611 |
68,270 |
|
1,4613 |
68,312 |
|
1,4614 |
68,353 |
|
1,4615 |
68,395 |
|
1,4616 |
68,436 |
|
1,4617 |
68,478 |
|
1,4618 |
68,519 |
|
1,4619 |
68,561 |
|
1,4620 |
68,602 |
|
1,4621 |
68,643 |
|
1,4622 |
68,685 |
|
1,4623 |
68,726 |
|
1,4624 |
68,768 |
|
1,4625 |
68,809 |
|
1,4626 |
68,850 |
|
1,4627 |
68,892 |
|
1,4628 |
68,933 |
|
1,4629 |
68,974 |
|
1,4630 |
69,016 |
|
1,4631 |
69,057 |
|
1,4632 |
69,098 |
|
1,4633 |
69,139 |
|
1,4634 |
69,181 |
|
1,4635 |
69,222 |
|
1,4636 |
69,263 |
|
1,4637 |
69,304 |
|
1,4638 |
69,346 |
|
1,4639 |
69,387 |
|
1,4640 |
69,428 |
|
1,4641 |
69,469 |
|
1,4642 |
69,510 |
|
1,4643 |
69,551 |
|
1,4644 |
69,593 |
|
1,4645 |
69,634 |
|
1,4646 |
69,675 |
|
1,4647 |
69,716 |
|
1,4648 |
69,757 |
|
1,4649 |
69,798 |
|
1,4650 |
69,839 |
|
1,4651 |
69,880 |
|
1,4652 |
69,921 |
|
1,4653 |
69,962 |
|
1,4654 |
70,003 |
|
1,4655 |
70,044 |
|
1,4656 |
70,085 |
|
1,4657 |
70,126 |
|
1,4658 |
70,167 |
|
1,4659 |
70,208 |
|
1,4660 |
70,249 |
|
1,4661 |
70,290 |
|
1,4662 |
70,331 |
|
1,4663 |
70,372 |
|
1,4664 |
70,413 |
|
1,4665 |
70,453 |
|
1,4666 |
70,494 |
|
1,4667 |
70,535 |
|
1,4668 |
70,576 |
|
1,4669 |
70,617 |
|
1,4670 |
70,658 |
|
1,4671 |
70,698 |
|
1,4672 |
70,739 |
|
1,4673 |
70,780 |
|
1,4674 |
70,821 |
|
1,4675 |
70,861 |
|
1,4676 |
70,902 |
|
1,4677 |
70,943 |
|
1,4678 |
70,984 |
|
1,4679 |
71024 |
|
1,4680 |
71,065 |
|
1,4681 |
71,106 |
|
1,4681 |
71,146 |
|
1,4683 |
71,187 |
|
1,4684 |
71,228 |
|
1,4685 |
71,268 |
|
1,4686 |
71,309 |
|
1,4687 |
71,349 |
|
1,4688 |
71,390 |
|
1,4689 |
71,431 |
|
1,4690 |
71,471 |
|
1,4691 |
71,512 |
|
1,4692 |
71,552 |
|
1,4693 |
71,593 |
|
1,4694 |
71,633 |
|
1,4695 |
71,674 |
|
1,4696 |
71,714 |
|
1,4697 |
71,755 |
|
1,4698 |
71,795 |
|
1,4699 |
71,836 |
|
1,4700 |
71,876 |
|
1,4701 |
71,917 |
|
1,4702 |
71,957 |
|
1,4703 |
71,998 |
|
1,4704 |
72,038 |
|
1,4705 |
72,078 |
|
1,4706 |
72,119 |
|
1,4707 |
72,159 |
|
1,4708 |
72,199 |
|
1,4709 |
72,240 |
|
1,4710 |
72,280 |
|
1,4711 |
72,320 |
|
1,4712 |
72,361 |
|
1,4713 |
72,401 |
|
1,4714 |
72,441 |
|
1,4715 |
72,482 |
|
1,4716 |
72,522 |
|
1,4717 |
72,562 |
|
1,4718 |
72,602 |
|
1,4719 |
72,643 |
|
1,4720 |
72,683 |
|
1,4721 |
72,723 |
|
1,4722 |
72,763 |
|
1,4723 |
72,803 |
|
1,4724 |
72,843 |
|
1,4725 |
72,884 |
|
1,4726 |
72924 |
|
1,4727 |
72,964 |
|
1,4728 |
73,004 |
|
1,4729 |
73,044 |
|
1,4730 |
73,084 |
|
1,4731 |
73,124 |
|
1,4732 |
73,164 |
|
1,4733 |
73,204 |
|
1,4734 |
73,244 |
|
1,4735 |
73,285 |
|
1,4736 |
73,325 |
|
1,4737 |
73,365 |
|
1,4738 |
73,405 |
|
1,4739 |
73,445 |
|
1,4740 |
73,485 |
|
1,4741 |
73,524 |
|
1,4742 |
73,564 |
|
1,4743 |
73,604 |
|
1,4744 |
73,644 |
|
1,4745 |
73,684 |
|
1,4746 |
73,724 |
|
1,4747 |
73,764 |
|
1,4748 |
73,804 |
|
1,4749 |
73,844 |
|
1,4750 |
73,884 |
|
1,4751 |
73,924 |
|
1,4752 |
73,963 |
|
1,4753 |
74,003 |
|
1,4754 |
74,043 |
|
1,4755 |
74,083 |
|
1,4756 |
74,123 |
|
1,4757 |
74,162 |
|
1,4758 |
74,202 |
|
1,4759 |
74,242 |
|
1,4760 |
74,282 |
|
1,4761 |
74,321 |
|
1,4762 |
74,361 |
|
1,4763 |
74,401 |
|
1,4764 |
74,441 |
|
1,4765 |
74,480 |
|
1,4766 |
74,520 |
|
1,4767 |
74,560 |
|
1,4768 |
74,599 |
|
1,4769 |
74,639 |
|
1,4770 |
74,678 |
|
1,4771 |
74,718 |
|
1,1772 |
74,758 |
|
1,4773 |
74,797 |
|
1,4774 |
74,837 |
|
1,4775 |
74,876 |
|
1,4776 |
74,916 |
|
1,4777 |
74,956 |
|
1,4778 |
74,995 |
|
1,4779 |
75,035 |
|
1,4780 |
75,074 |
|
1,1781 |
75,114 |
|
1,4782 |
75,153 |
|
1,4783 |
75,193 |
|
1,4784 |
75,232 |
|
1,4785 |
75,272 |
|
1,4786 |
75,311 |
|
1,4787 |
75,350 |
|
1,4788 |
75,390 |
|
1,4789 |
75,429 |
|
1,4790 |
75,469 |
|
1,4791 |
75,508 |
|
1,4792 |
75,547 |
|
1,4793 |
75,587 |
|
1,4794 |
75,626 |
|
1,4795 |
75,666 |
|
1,4796 |
75,705 |
|
1,4797 |
75,744 |
|
1,4798 |
75,784 |
|
1,4799 |
75,823 |
|
1,4800 |
75,862 |
|
1,4801 |
75,901 |
|
1,4802 |
75,941 |
|
1,4803 |
75,980 |
|
1,4804 |
76,019 |
|
1,4805 |
76,058 |
|
1,4806 |
76,098 |
|
1,4807 |
76,137 |
|
1,4808 |
76,176 |
|
1,4809 |
76,215 |
|
1,4810 |
76,254 |
|
1,4810 |
76,294 |
|
1,4812 |
76,333 |
|
1,4813 |
76,372 |
|
1,4814 |
76,411 |
|
1,4815 |
76,450 |
|
1,4816 |
76,489 |
|
1,4817 |
76,528 |
|
1,4818 |
76,567 |
|
1,4819 |
76,607 |
|
1,4820 |
76,646 |
|
1,4821 |
76,685 |
|
1,4822 |
76,724 |
|
1,4823 |
76,763 |
|
1,4824 |
76,802 |
|
1,4825 |
76,841 |
|
1,4826 |
76,880 |
|
1,4827 |
76,919 |
|
1,4828 |
76,958 |
|
1,4829 |
76,997 |
|
1,4830 |
77,036 |
|
1,4831 |
77,075 |
|
1,4832 |
77,113 |
|
1,4833 |
77,152 |
|
1,4834 |
77,191 |
|
1,4835 |
77,230 |
|
1&xxxx;4336 |
77269 |
|
1,4837 |
77,308 |
|
1,4838 |
77,347 |
|
1,4839 |
77,386 |
|
1,4840 |
77,425 |
|
1,4841 |
77,463 |
|
1,4842 |
77,502 |
|
1,4843 |
77,541 |
|
1,4844 |
77,580 |
|
1,4845 |
77,619 |
|
1,4846 |
77,657 |
|
1,4847 |
77,696 |
|
1,4848 |
77,735 |
|
1,4849 |
77,774 |
|
1,4850 |
77,812 |
|
1,4851 |
77,851 |
|
1,4852 |
77,890 |
|
1,4853 |
77,928 |
|
1,4854 |
77,967 |
|
1,4855 |
78,006 |
|
1,4856 |
78,045 |
|
1,4857 |
78,083 |
|
1,4858 |
78,122 |
|
1,4859 |
78,160 |
|
1,4860 |
78,199 |
|
1,4861 |
78,238 |
|
1,4862 |
78,276 |
|
1,4863 |
78,315 |
|
1,4864 |
78,353 |
|
1,4865 |
78,392 |
|
1,4866 |
78,431 |
|
1,4867 |
78,469 |
|
1,4868 |
78,508 |
|
1,4869 |
78,546 |
|
1,4870 |
78,585 |
|
1,4871 |
78,623 |
|
1,4872 |
78,662 |
|
1,4873 |
78,700 |
|
1,4874 |
78,739 |
|
1,4875 |
78,777 |
|
1,4876 |
78,816 |
|
1,4877 |
78,854 |
|
1,4878 |
78,892 |
|
1,4879 |
78,931 |
|
1,4880 |
78,969 |
|
1,4881 |
79,008 |
|
1,4882 |
79,046 |
|
1,4883 |
79,084 |
|
1,4884 |
79,123 |
|
1,4885 |
79,161 |
|
1,4886 |
79,199 |
|
1,4887 |
79,238 |
|
1,4888 |
79,276 |
|
1,4889 |
79,314 |
|
1,4890 |
79,353 |
|
1,4891 |
79,391 |
|
1,4892 |
79,429 |
|
1,4893 |
79,468 |
|
1,4894 |
79,506 |
|
1,4895 |
79,544 |
|
1,4896 |
79,582 |
|
1,4897 |
79,620 |
|
1,4898 |
79,659 |
|
1,4899 |
79,697 |
|
1,4900 |
79,735 |
|
1,4901 |
79,773 |
|
1,4902 |
79,811 |
|
1,4903 |
79,850 |
|
1,4904 |
79,888 |
|
1,4905 |
79,926 |
|
1,4906 |
79,964 |
|
1,4907 |
80,002 |
|
1,4908 |
80,040 |
|
1,4909 |
80,078 |
|
1,4910 |
80,116 |
|
1,4911 |
80,154 |
|
1,4912 |
80,192 |
|
1,4913 |
80,231 |
|
1,4914 |
80,269 |
|
1,4915 |
80,307 |
|
1,4916 |
80,345 |
|
1,4917 |
80,383 |
|
1,4918 |
80,421 |
|
1,4919 |
80,459 |
|
1,4920 |
80,497 |
|
1,4921 |
80,534 |
|
1,4922 |
80,572 |
|
1,4923 |
80,610 |
|
1,4924 |
80,648 |
|
1,4925 |
80,686 |
|
1,4926 |
80,724 |
|
1,4927 |
80,762 |
|
1,4928 |
80,800 |
|
1,4929 |
80,838 |
|
1,4930 |
80,876 |
|
1,4931 |
80,913 |
|
1,4932 |
80,951 |
|
1,4933 |
80,989 |
|
1,4934 |
81,027 |
|
1,4935 |
81,065 |
|
1,4936 |
81,103 |
|
1,4937 |
81,140 |
|
1,4938 |
81,178 |
|
1,4939 |
81,216 |
|
1,4940 |
81,254 |
|
1,4941 |
81,291 |
|
1,4942 |
81,329 |
|
1,4943 |
81,367 |
|
1,4944 |
81,405 |
|
1,4945 |
81,442 |
|
1,4946 |
81,480 |
|
1,4947 |
81,518 |
|
1,4948 |
81,555 |
|
1,4949 |
81,593 |
|
1,4950 |
81,631 |
|
1,4951 |
81,668 |
|
1,4952 |
81,706 |
|
1,4953 |
81,744 |
|
1,4954 |
81,781 |
|
1,4955 |
81,819 |
|
1,4956 |
81,856 |
|
1,4957 |
81,894 |
|
1,4958 |
81,932 |
|
1,4959 |
81,969 |
|
1,4960 |
82,007 |
|
1,4961 |
82,044 |
|
1,4962 |
82,082 |
|
1,4963 |
82,119 |
|
1,4964 |
82,157 |
|
1,4965 |
82,194 |
|
1,4966 |
82,232 |
|
1,4967 |
82,269 |
|
1,4968 |
82,307 |
|
1,4969 |
82,344 |
|
1,4970 |
82,381 |
|
1,4971 |
82,419 |
|
1,4972 |
82,456 |
|
1,4973 |
82,494 |
|
1,4974 |
87,531 |
|
1,4975 |
82,569 |
|
1,9976 |
82,606 |
|
1,4977 |
82,643 |
|
1,4978 |
82,681 |
|
1,4979 |
82,718 |
|
1,4980 |
82,755 |
|
1,4981 |
82,793 |
|
1,4982 |
82,830 |
|
1,4983 |
82,867 |
|
1,4984 |
82,905 |
|
1,4985 |
82,942 |
|
1,4986 |
82,979 |
|
1,4987 |
83,016 |
|
1,4988 |
83,054 |
|
1,4989 |
83,091 |
|
14990 |
83,128 |
|
1,4991 |
83,165 |
|
1,4992 |
83,202 |
|
1,4993 |
83,240 |
|
1,4994 |
83,277 |
|
1,4995 |
83,314 |
|
1,4996 |
83,351 |
|
1,4997 |
83,388 |
|
1,4998 |
83,425 |
|
14999 |
83,463 |
|
1,5000 |
83,500 |
|
1,5001 |
83,537 |
|
1,5002 |
83,574 |
|
1,5003 |
83,611 |
|
1,5004 |
83,648 |
|
1,5005 |
83,685 |
|
1,5006 |
83,722 |
|
1,5007 |
83,759 |
|
1,5008 |
83,796 |
|
1,5009 |
83,833 |
|
1,5010 |
83,870 |
|
1,5011 |
83,907 |
|
1,5012 |
83,944 |
|
1,5013 |
83,981 |
|
1,5014 |
84,018 |
|
1,5015 |
84,055 |
|
1,5016 |
84,092 |
|
1,5017 |
84,129 |
|
1,5018 |
84,166 |
|
1,5019 |
84,203 |
|
1,5020 |
84,240 |
|
1,5021 |
84,277 |
|
1,5022 |
84,314 |
|
1,5023 |
84,351 |
|
1,5024 |
84,388 |
|
1,5025 |
84,424 |
|
1,5026 |
84,461 |
|
1,5027 |
84,498 |
|
1,5028 |
84,535 |
|
1,5029 |
84,572 |
|
1,5030 |
84,609 |
|
1,5031 |
84,645 |
|
1&xxxx;5032 |
84,682 |
|
1,5033 |
84,719 |
|
1,5034 |
84,756 |
|
1,5035 |
84,792 |
|
1,5036 |
84,829 |
|
1,5037 |
84,866 |
|
1,5038 |
84,903 |
|
1,5039 |
84,939 |
|
1,5040 |
84,976 |
|
1,5041 |
85,013 |
|
1,5042 |
85,049 |
|
1,5043 |
85,086 |
|
1,5044 |
85,123 |
|
1,5045 |
85,159 |
|
1,5046 |
85,196 |
|
1,5047 |
85,233 |
|
1,5048 |
85,269 |
|
1,5049 |
85,306 |
|
1,5050 |
85,343 |
|
1,5051 |
85,379 |
|
1,5052 |
85,416 |
|
1,5053 |
85,452 |
|
1,5054 |
85,489 |
|
1,5055 |
85,525 |
|
1,5056 |
85,562 |
|
1,5057 |
85,598 |
|
1,5058 |
85,635 |
|
1,5059 |
85,672 |
|
1,5060 |
85,708 |
|
1,5061 |
85,744 |
|
1,5062 |
85,781 |
|
1,5063 |
85,817 |
|
1,5064 |
85,854 |
|
1,5065 |
85,890 |
|
1,5066 |
85,927 |
|
1,5067 |
85,963 |
|
1,5068 |
86,000 |
|
1,5069 |
86,036 |
|
1,5070 |
86,072 |
|
1,5071 |
86,109 |
|
1,5072 |
86,145 |
|
1,5073 |
86,182 |
|
1,5074 |
86,218 |
|
1,5075 |
86,254 |
|
1,5076 |
86,291 |
|
1,5077 |
86,327 |
|
1,5078 |
86,363 |
|
1,5079 |
86,399 |
[1] Xxxxxxx x v xxxxxx xxxxxxxxx jsou xxxxxxxxx xxxxxx xxxxxxx, xxxxxx xxxxxxx xxx ICUMSA xx X. Rosenhauer. Xxxxxxx byla xxxxxxxxxxxxxx x xxxxxxx xxxxxxxxx Xxxxxxx G. Carpenterem x XXXX x xxxx xxxxxxxxxxx v Xxxxx J. 33, 15-22 (xxxxxx 1970). Xxxxx lomu xxx xxxxx xxx 20 °X xxxxxx X xxxx Xx. Xxxx (xxxxxxxx xxxxxxxxxx xxxxxxxxx) xxx získán xxxxxxx xxx 20 °C xx xxxxxxx při xxxxx 760 xxxxx (xx Xx) x xxxxxxxxxxxxxxxxx xxxxxxxxx vlhkosti. Xxxx xxxxxxx xxxxxxxxx xxxxxxx předchozí (47 012, xxxxxx 11) xxxxxxxxxxxx x Xxxxxx. Xxxxx X. 39, 22 (1937).
XXXXXX 4
XXXXXXXXX XXXXXXXXXXXX XXXXX XXXXXXXXXXX XXXX XXXXXXXX XXXXX
(Xxxxxx podle xxxxxx Berlin Institut)
1. Xxxxxxx x xxxxxx xxxxxxx
Xxxxxx slouží xx xxxxxxxxx redukujících cukrů xxxxxxxxxxx xxxx xxxxxxxx xxxx x xxxxx xxxxxxxxx
2. Xxxxxxxx
„Xxxxxxxxxx xxxxx xxxxxxxxx jako xxxxxxxx xxxx“: xxxxx redukujících xxxxx xxxxxxxxx xxxxxxxx xxxxxxx.
3. Xxxxxxxx xxxxxx
Xxxxxx xxxxxx x obsahem xxxxxxxxxxxx cukrů xx xxxxxxx xxx xxxxxxx xxxxxxx komplexu xxxx XX. Xxxxxxx xxxx xxxxx xx xxx xxxxxxx xxxxxxxx xxxxxxxx xxxx (xx xxxxxx xxxxxx), xxxxx přebytek xx xxxxxxx xxxxxxx xxxxxxx xxxxxxxx roztokem xxxxxxxxxx sodného (xx xxxxxx xxxxxx).
4. Reakční xxxxxxx
4.1 Xxxxxx Cu XX (Xxxxxxxx xxxxxx)
4.1.1 Xx 400 ml xxxxxx xxxx se xxxxxxxx 35 x xxxxxx měďnatého pentahydrátu (XxXX4 5H2O) a xxxxx xx xxxxxxxxxxx.
4.1.2 X 500 xx xxxxxx xxxx xx xxxxxxxx 173 x xxxxxx sodnodraselného xxxxxxxxxxxx (Xxxxxxxxxx xxxx Xxxxxxxxxxx xxx, KNaC4H4O6,4H2O) x 68 x xxxxxxxxx xxxxxxxxxx sodného x xxxxx se vychladnout.
4.1.3 Xxx xxxxxxx (4.1.1 x 4.1.2) xx xxxxxxxx xx xxxxxxx xxxxxxx baňky a xxxxxx xx xxxxx xx 1 xxxxx. Xx xxxxxxx 2 x aktivního uhlí xx xxxxx xxxxxxxx, xxxxx xx xxxxxxx xxxxx xxxx x xxxx xx přefiltruje xxxx hustý xxxxxxxx xxxx xxxxxxxxxx xxxxx.
Xxxxx xx x xxxxxxx xxxxxxxxxx xxxxxxx xxxxxx xxxx xxxxxxxx oxidu xxxxxxx, je třeba xxxxxx xxxxx přefiltrovat.
4.2 Xxxxxxxx xxxxxx, roztok 5 mol/l.
4.3 Roztok xxxx, 0,01665 xxx/x (0,0333X; 4,2258 g/l).
4.4 Xxxxxx thiosíranu xxxxxxx, xxxxxx 0,0333 xxx/x.
4.5 Xxxxxx škrobu: xx xxxxx xxxxxx xxxx xx přilije xxxx 5 g xxxxxxxxxxx xxxxxx xxxxxxxxxxxx ve 30 xx vody, xxxxxx se 3 xxxxxx x xxxxx xxxxxxxxxxx. V xxxxxxx xxxxxxx se přidá 10 mg jodidu xxxxxxxxxx xxxx xxxxxxxxxxxxx xxxxxxx.
5. Přístroje x xxxxxxx
5.1 Xxxxxxxxxxxxx xxxxx, 300 ml; xxxxxx xxxxxx x xxxxxx.
5.2 Xxxxx lázeň, xxxxxx.
6. Xxxxxx
6.1 Xx 300 xx Erlenmeyerovy baňky xx xxxxxx xxxx xxxxxx (10 x xxxx xxxx), který xxxxxxxxxx více než 30 mg invertního xxxxx, x rozpustí xx xxxxxxxxx xx 100 xx xxxx.
Xx xxxxx x roztokem xxxxxx se xxxxxxxxxx 10 ml xxxxxxx Xx XX (4.1), xxxxx xx krouživým xxxxxxx xxxxxxx a xxxxx xx vloží xx xxxxxx xxxxx xxxxx (5.2) xx xxxx xxxxxx 10 xxxxx.
Xxxxxxx xxxxxxx v Xxxxxxxxxxxxx baňce musí xxx xxxxxxx 20 xx xxx xxxxxx xxxxxxx xx xxxxx xxxxx. Xxxxx xx xxxxxx xxxxxxx proudem xxxxxxx vody, xxxxxxx xx xxxxxx nesmí xxxxxxxxxxx, aby xxxxxxx x xxxxxxxx xxxxxxx xxxxxxxxxxx oxidu xxxxxxx xxxxxxxx kyslíkem.
Bez xxxxxxxxxxxx xxxxxx xx pipetou xxxxx 5 ml xxxxxxx xxxxxxxx xxxxxx (4.2) x xxxxxxxxxxx 5 mol/l x xxxxx poté xx xxxxxxx xxxxx přebytek (20 xx 40 xx) roztoku xxxx (4.3) o koncentraci 0,016 65 xxx/x.
Xxxxxxxxx xxxx xx xxxxxxxx xxxxxxxx a xxxxxxxx xxxx xx xxxxxxx xxxxxxxx xxxxxxxxxx xxxxxxx (4.4) o xxxxxxxxxxx 0,0333 xxx/x xxx xxxxxxx xxxxxxx škrobu (4.5) xxxx xxxxxxxxxx. Xxxxxxxxx xx xxxxxxx xx xxxxx titrace.
6.2 X xxxxx xx xxxxxxx slepý xxxxx, xxxxx xx opakuje xxxx xxx použití xxxxxx roztoku Cu XX (4.4). Xxxxxxxx xxxxxxxx xxxxxxxxxx 0,1 xx.
6.3 S xxxxxxxx xxxxxxxx se xx xxxxxx provede kontrolní xxxxxxx. Roztok xx xxxxx xxxx xxx xxxxxxxxxxx teplotě xx xxxx 10 xxxxx, xxx mohlo xxxxx x xxxxxx jiných, xxxxxxxxxx xxxxxxxxxx xxxxxxxxxxxx xxxxx, xxxx xx xxxxxxxxx xxxx xxxxxxxx.
7. Xxxxxxxxx xxxxxxxx
7.1 Vzorec x postup výpočtu
Objem xxxxxxxxxxxxxx roztoku jódu xx xxxxx xxxxxx (xx) přebytku přidaného xxxxxxx xxxx (0,016 65 xxx/x) xxxxx xxxxx (ml) roztoku xxxxxxxxxx xxxxxxx (0,0333 xxx/x) spotřebovaného při xxxxxxx.
Xxxxx (xx) xxxxxxxxxxxxxx xxxxxxx xxxx (0,016 65 mol/l) se xxxxxx odečtením:
7.1.1 xxxxx xx xxxxxxxxxxxxxx při xxxxxx pokusu s xxxxx (6.2),
7.1.2 xxxxx xx spotřebovaných xxx xxxxxxxxx xxxxxxx x xxxxxxxx xxxxxxxx xx xxxxxx (6.3),
7.1.3 objemu 2,0 xx na xxxxxxx 10 g xxxxxxxxx xxxxxxxx x xxxxxxxx xxxxxxxxxx xxxxxx xxxx úměrného množství, xxxxxxxx-xx xxxxxx xxxx xxx 10 x xxxxxxxxx (xxxxxxx xx xxxxxxxxx).
Xx provedení xxxxxx xxxxxxx xxxxxxxx xxxxxxxx 1 ml xxxxxxxx xxxxxxx (4.3) 1 xx xxxxxxxxxx xxxxx.
Xxxxx xxxxxxxxxx cukru v xxxxxxxxxx xxxxxx se xxxxxxxx xxxxx vzorce:
kde:
V1 = xxxxx xx xxxxxxxx xxxxxxx (4.3) xx korekci,
m0 = xxxxxxxx xxxxxxxxx vzorku (x).
7.2 Xxxxxxxxxxxxxx
Xxxxxx xxxx xxxxxxxx dvou stanovení xxxxxxxxxxx zároveň xxxx xxxxxx xx xxxxx x xxxxx xxxxxx xxxxxx xxxxxxxxxxx za xxxxxxxxx podmínek nesmí xxx větší xxx 0,02 x xx 100 x xxxxxx.
XXXXXX 5
XXXXXXXXX XXXXXXXXXXXX XXXXX XXXXXXXXXXX XXXX INVERTNÍ XXXX
(Xxxxxx podle Knighta x Xxxxxx)
1. Xxxxxxx x xxxxxx použití
Metoda xxxxxx ke stanovení xxxxxxxxxxxx xxxxx vyjádřených xxxx xxxxxxxx xxxx
- x xxxxx xxxx x xxxxx xxxxx,
- x xxxxx xxxxx xxxxx.
2. Definice
„Redukující cukry xxxxxxxxx xxxx xxxxxxxx xxxx“: xxxxx xxxxxxxxxxxx xxxxx stanovený xxxxxxxx xxxxxxx.
3. Podstata xxxxxx
X xxxxxxx vzorku xx xxxxx v přebytku xxxxxxx s xxxxxxx Xx XX, xxxxxxxxxxx x xxxxxxxxxxxxx xxxxx xx xxx stanoví xxxxxxx xxxxxxx x xxxxxxxx EDTA.
4. Xxxxxxx xxxxxxx
4.1 Xxxxxxxx ethylendiamintetraoctová (xxxxxxxxx xxx) (EDTA), xxxxxx 0,0025 mol/l: xxxxxxxx se 0,930 x XXXX xx xxxx x xxxxxx xx xxxxx do xxxxxxx litru.
4.2 Roztok xxxxxxxxxx murexidu: 0,25 x xxxxxxxx xx xxxxx xx 50 xx vody x xxxxxx xx x 20 xx vodného xxxxxxx methylenové xxxxx x koncentraci 0,2 x/100 ml.
4.3 Alkalické xxxxxxx činidlo: x 600 ml xxxx xxxxxxxxxx 40 xx xxxxxxxxx xxxxxxx x xxxxxxxxxxx 1,0 xxx/x xx xxxxxxxx 25 x bezvodého xxxxxxxxxx xxxxxxx a 25 x vinanu xxxxxxxxxxxxxxx xxxxxxxxxxxx. Přibližně v 100 xx vody xx xxxxxxxx 6,0 x síranu xxxxxxxxx – xxxxxxxxxxxx (CuSO4 5X2X), xxxxxxx roztok xx přidá x xxxxxxx xxxxxx x xxxxxx vodou xx xxxxxxx xxxxx.
Xxxxxxxx: Roztok xx omezenou xxxxxxxxxxx (xxxxx xxxxx).
4.4 Standardní xxxxxx xxxxxxxxxx xxxxx: x xxxxxxx xxxxx x objemu 250 xx xx xxxxxxxx 23,750 x xxxxx xxxxxxxxx (4.5) xxx xx 120 xx xxxx. Xxxxx xx 9 ml xxxxxxxx xxxxxxxxxxxxxx (X20 = 1,16) x xxxxx xx stát xxx xxxxxxxxxxx xxxxxxx xx xxxx 8 dní. Xxxxxx se doplní xx 250 xx x ukončení xxxxxxxxx xx xxxxxxxxxxx odečtem xx polarimetru nebo xxxxxxxxxxxx xxx použití xxxxxxx x délce 200 xx. Xxxxxxxx xxxxxxx xx xx xxxxxx 11,80 ± 0,05°X (xxx xxxxxxxx 8). 200 ml xxxxxx xxxxxxx xx xxxxxxxxxx do odměrné xxxxx x objemu 2000 ml, xxxxx xx xxxxx x xx xxxxxxx protřepávání (xxx xxxxxxx k xxxxxxxxxx xxxxxxxx zalkalizování xxxxxxx) se xxxxx 71,4 ml xxxxxxx xxxxxxxxx sodného (1 xxx/x), xx xxxxxx xxxx xxxxxxxxxx 4 x xxxxxxxx xxxxxxxx. Xxxxxx xx xxxxxx xx 2000 xx, xx. xxx obsahoval 1 x xxxxxxxxxx xxxxx xx 100 xx; xxxxxxx pH xxxxxxx xx má xxxxxxxxx kolem 3.
Tento xxxxx zásobní xxxxxx xx ředí xxxxx xxxxxxxxxxxxx před použitím.
4.5 Xxxxx xxxxxxxxx: xxxxxx xxxxx xxxxxxxxx x xxxxxxx xxxxxxxxxx xxxxx xxxxxxx 0,001 x/100 x.
5. Xxxxxxxxx x xxxxxxx
5.1 Xxxxxxxx 150 x 20 mm.
5.2 Xxxx xxxxxxxxxxx xxxxx.
5.3 Xxxxxxxxxx xxxx xxxxxx x xxxxxxxxx xx 0,1 xx.
6. Xxxxxx
6.1 Xx xxxxxxxx (5.1) xx xxxxxxxx 5 x xxxxxx cukru x 5 xx xxxxxxx xxxx, přidají xx 2,0 xx xxxxxxxxx xxxxxxx (4.3) x obsah xx xxxxxxxx. Xxxxxxxx xx xxxxxx do xxxxx x vroucí vodou xx xxxx 5 xxxxx a poté xx xx xxxxxxx xxxx xxxxxxx.
6.2 Roztok xx ze xxxxxxxx xxxxxxxxxxxxx, s použitím xx nejmenšího xxxxxxxx xxxx, xxxxxxx do xxxx xxxxxxxxxxxx misky (5.2), přidají xx xxx kapky xxxxxxxxxx (4.2) a titruje xx roztokem EDTA (4.1). Xxxxxxxx spotřeba x ml se xxxxxx jako X0.
Xxxxx xxxx xxxxxxxxx xxxxxxx xx barva xxxxxxx xxxxx ze zelené xxxx xxxxx xx xxxxxxxxxx v xxxxxxxx xxxx. Purpurová xxxxx xxxxxx xxxx x xxxxxxxx oxidace xxxxx xxxxxxx xx xxxx xxxxxxx rychlost oxidace xxxxxx xx xxxxxxxxxxx xxxxxxxx xxxxxxxxxxx mědi. Xxxxx je při xxxxxxx xxxxx xxxxxxxxx xxxxxxxxx xxxx xx xxxxx xxxxxxxxxxx.
6.3 Sestrojí xx kalibrační xxxxxx xx xxxxxxx přidávání xxxxxxx množství xxxxxxxxxx xxxxx (xxxxxxxxx xxxxxxx xxxxxx 4.4) x 5 g xxxxx xxxxxxxxx (4.5) a xxxxxxxxxxxxxx xxxxxxxx studené xxxx xxx, xxx xxxxxxx xxxxx xxxxxxxxx xxxxxxx xxxxx 5 xx. Xxxxxxxx xxxxxxxx (xx) se xxxxxx xx xxxxx xxxxx xxxxxxxxxxx xxxxxx xxxxxxxxxx xxxxx přidaného x 5 x xxxxxxxxx; xxxxxxxxx xxxxxxx xx xxxxxx v xxxxxxx 0,001 xx 0,019 x xx 100 x invertního xxxxx, xxxx. 100 g xxxxxx.
7. Xxxxxxxxx výsledků
7.1 Xxxxxx výpočtu
Z xxxxxxxxxx xxxxxx se xxxxxx xxxxx xxxxxxxxxx xxxxx (x xxxxxxxxxx) xxxxxxxxxxxx xxxxxxxx XXXX X0 xx xxx xxxxxxx xxxxxx.
7.2 Xxxxx xx xxxxxxxxxxx vyšší xxxxxxxxxxx xxx 0,017 g xxxxxxxxxx xxxxx xx 100 x xxxxxxxxxxxxx xxxxxx, xxxx xx xxxxxxxxx xxxxxx xxxxxxxx xxxxxx x xxxx 6.1, xxxxxxxxxxx xxxxxx xx xxxx musí xxxxxxx xx 5 x xxxxxx sacharosou (4.5).
7.3 Xxxxxxxxxxxxxx
Xxxxxx xxxx xxxxxxxx xxxx stanovení xxxxxxxxxxx zároveň xxxx xxxxxx xx xxxxx x xxxxx vzorku xxxxxx pracovníkem xx xxxxxxxxx podmínek xxxxx xxx větší xxx 0,005 x xx 100 x xxxxxx.
8. Xxxxxxxx
Xxx převodu xxxxxxx xx °X na xxxxxxxxxxxxxx xxxxxx stupně xx xxxxxxx xxxxxxx x °X xxxx 2,889 (polarimetrická xxxxxxx x xxxxx 200 xx; xxxxxxxx výbojka xxxx xxxxxxxx xxxxx; xxxxxxxx xxxxxxxx x xxxxxxxxx, ve xxxxx xx xxxxx xxxxxxxx xxxxxxx xxxxx 20 °X).
XXXXXX 6
XXXXXXXXX REDUKUJÍCÍCH XXXXX XXXXXXXXXXX XXXX XXXXXXXX CUKR NEBO XXXXXXXXXX EKVIVALENT
(Metoda xxxxx Xxxxx x Xxxxxxxx)
1. Xxxxxxx x oblast xxxxxxx
Xxxxxx xxxxxx xx xxxxxxxxx
1.1 obsahu redukujících xxxxx vyjádřeného xxxx xxxxxxxx xxxx
- v xxxxxxx xxxxx,
- x xxxxxxx bílém xxxxx,
- x xxxxxxx xxxxxxxxx xxxxx,
- x tekutém xxxxx invertním xxxxx,
- x xxxxxx x xxxxxxxxxx xxxxx,
- v xxxxxx x invertního xxxxx xxxxxx;
1.2 xxxxxx xxxxxxxxxxxx cukrů xxxxxxxxxxx x vypočteného (xxxxxxxx xx xxxxxx) xxxx xxxxxxxxxx xxxxxxxxxx
- xx xxxxxxxxx sirupu,
- v xxxxxxx xxxxxxxxx xxxxxx;
1.3 xxxxxx xxxxxxxxxxxx cukrů xxxxxxxxxxx xxxx X-xxxxxxx
- x dextrose monohydrátu,
- x xxxxxxxx xxxxxxx.
2. Xxxxxxxx
„Xxxxxxxxxx xxxxx xxxxxxxxx xxxx xxxxxxxx cukry, X-xxxxxxx nebo xxxx xxxxxxxxxx ekvivalent": xxxxx xxxxxxxxxxxx xxxxx xxxxxxxxx xxxx xxxxxxxxx xxxx xxxxxxxx cukr, Xxxxxxxx xxxx xxxxxxxxxx ekvivalent xxxxxxxxx xxxxxxxx xxxxxxx.
3. Xxxxxxxx xxxxxx
Xxxxxx x xxxxxxxxxxxx xxxxx xx xxxxxx (x x xxxxxxx potřeby xxxxxx) xx xxxxxxxxxxxx xxxxxxxx x xxxx xxxx x xxxxxxxx Xx XX, který xx xxxxxxxx xxxxxxxx xx Xx I. Přebytek Xx XX xx xxxx xxxxxxx jodometricky.
4. Xxxxxxx xxxxxxx
4.1 Xxxxxxxx xxxxxx X: 21,95 x octanu zinečnatého xxxxxxxxx, (Xx(XX3XXX)22X2X) nebo 24 x xxxxxx xxxxxxxxxxx xxxxxxxxxx, (Xx(XX3XXX)2-3X2X) xx xxxxx s xxxxxxxxx 3 xx xxxxxx kyseliny xxxxxx xxxxxxxx xx xxxx x xxxxxx vodou xx 100 xx.
4.2 Xxxxxxxx roztok XX: 10,6 x xxxxxxxxxxxxxxxxxxxx xxxxxxxxxx trihydrátu (X4[Xx(XX)6]-3X2X) xx rozpustí xx xxxx a xxxxxx xxxxx xx 100 xx.
4.3 Xxxxxxx-Xxxxxxxxxx xxxxxxx: xxxxxxxx se xxxx xxxxxxx:
4.3.1 Xxxxxx síranu xxxxxxxxx: 25 g xxxxxx xxxxxxxxx xxxxxxxxxxxx (XxXX45X2X) xxxxxxxxxxxxxx železo xx xxxxxxxx xx 100 xx xxxx.
4.3.2 Xxxxxx xxxxxxxx xxxxxxxxx: 50 x xxxxxxxx xxxxxxxxx xxxxxxxxxxx (X6X8X7-X2X) xx rozpustí x 50 xx vody.
4.3.3 Xxxxxx xxxxxxxxxx xxxxxxx: 143,8 g xxxxxxxxx xxxxxxxxxx sodného se xxxxxxxx přibližně x 300 ml horké xxxx a xxxxx xx xxxxxxxxxxx.
4.3.4 K xxxxxxx xxxxxxxxxx sodného (4.3.3) v xxxxxxx xxxxxxx xxxxx se xx xxxxxxx xxxxxxxxxxxx xxxxxxxxx xxxxxxx xxxxxxx xxxxxx xxxxxxxx citronové (4.3.2). Obsah se xxxxx, dokud xx xxxxxxxxxx xxxxxxx xxxx, xxx xx xxxxx xxxxxx xxxxxx xxxxxxxxx (4.3.1) x xxxxx xx xxxxxx xx 1000 ml. Xxxxxx xx xxxxx stát xxxx xxx, x xxxxxxx potřeby se xxxxx xxxxxxxxxxx. Provede xx xxxxxxxx molarity xxxxxxx xxxxxxx xxxxx xxxxxx xxxxxxx v xxxx 6.1 (Xx 0,1 mol/l; Xx2XX3 1 xxx/x).
4.4 Xxxxxx xxxxxxxxxx, 0,1 xxx/x.
4.5 Xxxxxx xxxxxx: xx xxxxxxx litru xxxxxx xxxx xx xxxxxxx 5 x rozpustného xxxxxx xxxxxxxxxxxx ve 30 ml xxxx. Xxxxxx xx 3 xxxxxx x xxxxx xx vychladnout; je-li xxxxx, xxxxx se 10 xx xxxxxx xxxxxxxxxx xxxx xxxxxxxxxxx xxxxxxx.
4.6 Xxxxxxxx xxxxxx, 3 mol/l.
4.7 Xxxxxx xxxxxx xxxxxxxxxx, 30 % (x/X).
4.8 Úlomky xxxxx, xxxxxxxx x xxxxxxxx xxxxxxxxxxxxxx, promyté xxxxx do xxxxxxxx xxxxxx xxxxxx x xxxxxxxx.
4.9 Xxxxxxxxxxx.
4.10 Xxxxxxxx xxxxx, 0,1 mol/l.
4.11 Xxxxxxxx xxxxxxxxxxxxxx, 0,1 xxx/x.
4.12 Fenoftalein, xxxxxxxxxxxxxx xxxxxx (x/X) v xxxxxxxx.
5. Xxxxxxxxx x xxxxxxx
5.1 Xxxxxxxxxxxxx xxxxx, x xxxxxx 300 xx, xx zpětným xxxxxxxxx.
5.2 Stopky.
6. Xxxxxx
6.1 Xxxxxxxxx titru Xxxxxxx-Xxxxxxxxxx xxxxxxx (4.3):
6.1.1 Xx 25 ml Xxxxxxx-Xxxxxxxxxx xxxxxxx (4.3) xx xxxxxxx 3 g xxxxxx xxxxxxxxxx x 25 xx kyseliny xxxxxx x koncentraci 3 xxx/x (4.6).
Xxxxxxx xx roztokem xxxxxxxxxx xxxxxxx o xxxxxxxxxxx 0,1 xxx/x (4.4) xx použití xxxxxxxxxx xxxxxxx (4.5) xxxx xxxxxxxxxx, xxxxx xx xxxxx xx xx xxxxx titrace. Xxxxx xxxx spotřeba xxxxxxx xxxxxxxxxx x koncentraci 0,1 xxx/x rovna 25 ml, xxxx xxx xxxxxxx připraveno xxxxx.
6.1.2 Xxxxxxxxxx se 10 ml xxxxxxx xx 100ml xxxxxxx xxxxx x xx xxxxx se doplní xxxxx.
10 xx takto xxxxxxxxx činidla xx xxxxxxxxxx do Xxxxxxxxxxxxx xxxxx xxxxxxxxxx 25 xx kyseliny xxxxxxxxxxxxxx x xxxxxxxxxxx 0,1 xxx/x (4.11) x xxxxxxx xx xx xxxx xxxxx xxxxxx xx vroucí xxxxx xxxxx. Xxx xx xxxxxx xxxxxxx, xxxxxx xx na xxxxxxx xxxxx xxxxxxx xxxxxxxxxx xxxxx x titruje xxxxxxxx xxxxxxxxx xxxxxxx x xxxxxxxxxxx 0,1 xxx/x (4.10) za xxxxxxx fenolftaleinu (4.12) xxxx indikátoru.
Spotřeba xxxxxxx xxxxxxxxx xxxxxxx, 0,1 xxx/x (4.10) xxxx xxx xxxx 5,5 x 6,5 ml.
6.1.3 10 xx zředěného xxxxxxx (6.1.2) xx xxxxxxx xxxxxxxxx chlorovodíkovou, 0,1 xxx/x (4.11) xx xxxxxxx xxxxxxxxxxxxx (4.12) xxxx indikátoru. Xxxxxxx bod xxxxxxx xx charakterizován xxxxxxx xxxxxxxxx xxxxxxxx.
Xxxxxxxx xxxxxxx xxxxxxxx xxxxxxxxxxxxxx, 0,1 xxx/x (4.11) xxxx xxx xxxx 6,0 x 7,5 xx.
6.1.4 Xxxxxxx xX Luffova-Schoorlova xxxxxxx musí xxx xxxx 9,3 x 9,4 xxx 20 °X.
6.2 Xxxxxxxx roztoku
6.2.1 Xxxxxx xx 5 x xxxxxx x xxxxxxxxx xx 1 xx a kvantitativně xx převede xx xxxxxxx baňky o xxxxxx 250 xx xxxxxxxxxx 200 ml xxxx. V případě xxxxxxx xx xxxxxx xxxxxxxx 5 ml Xxxxxxxxx roztoku X (4.1), pak xx xxxxx 5 xx Xxxxxxxxx xxxxxxx XX (4.2). Xx xxxxxxxx xxxxxxx roztoku se xxxxx xxxxxxx. Xxxxxx xx doplní xxxxx xx 250 xx x xxxxx xxxxxxxx. X xxxxxxx potřeby xx xxxxxx xxxxxxxxxxx.
6.2.2 Xxxxxx (6.2.1) xx xxxxx x takovém xxxxxx, xxx xxxxx xxxxxxxxxxxx xxxxx xxxxxxxxxxx xxxx xxxxxxx xx x 25 xx xxxxxxx xxxxxxxxx v xxxxxxx 15 xx 60 mg.
6.3 Xxxxxxx xxxxx Xxxxxxx-Xxxxxxxxxx xxxxxx
Xx 300 xx Xxxxxxxxxxxxx xxxxx (5.1) xx xxxxxxxxxx 25 xx Xxxxxxx-Xxxxxxxxxx xxxxxxx (4.3), xx xxxxx xx xxx xxxxxxx odměří 25 ml cukerného xxxxxxx (6.2.2) x xxxxx se xxx xxxxxx pemzy (4.8). X xxxxx (5.1) xx xxxxxxx zpětný xxxxxxx x xxxxxxxxx xx xxxxx xxxxxx xx xxxxxxxx xxxxxxxxxx xxxxx xxx plamen Xxxxxxxxx xxxxxx. Síťka xx v xxxxxxxxx xxxxx vyříznutý xxxxxxx xxxxx x xxxxxx xxxxxxx, xxxx xx xxx xxxxx. Xxxxxxxx xx xxxxxxxxx během xxxx xxxxx xxxxx xx varu x xxxxx xx přesně 10 xxxxx mírně xxxxx. Pak xx xxxxx ochladí xx xxxxxxx xxxx x xx pěti xxxxxxxx xx xxxxxxx xxxxx xxxxxx postupu:
Přidá xx 10 ml roztoku xxxxxx xxxxxxxxxx (4.7), xxxxxxxxxxxxx poté se xxxxx xxxxxxx (x xxxxxxx na bouřlivý xxxxx plynu) 25 xx xxxxxxxx xxxxxx x koncentraci 3 xxx/x (4.6). Titruje xx xxxxxxxx thiosíranu xxxxxxx x koncentraci 0,1 mol/l (4.4), xxxxx xx roztok xxxxx neodbarví, xxx xx xxxxx jako xxxxxxxxx xxxxxxx mililitrů xxxxxxx škrobu (4.5) x pokračuje xx x xxxxxxx xx xx xxxxxxxx modrého xxxxxxxx.
Xxxxxxx xx slepý xxxxx s 25 xx xxxx místo 25 ml cukerného xxxxxxx (6.2.2).
7. Xxxxxxxxx xxxxxxxx
7.1 Vzorec x xxxxxx výpočtu
Z xxxx xxxxxxx xxxxxxx xx xxxxxx (xxxxxxxx se xxxxxxx xxxxxxxxxxx) hmotnost xxxxxxx xxxx xxxxxxxxxx xxxxx v xx, xxxxxxxxxxxx rozdílu mezi xxxxx xxxxxxxxxx xxxxxxxxxx, xxxxxxxxxxx x xx xxxxxxx xxxxxxxxxx xxxxxxx x xxxxxxxxxxx 0,1 xxx/x.
Xxxxxxxx xx xxxxxxx x procentech (m/m) xxxxxxxxxx xxxxx nebo X-xxxxxxx, xxxxxxxxxx xx xxxxxx.
7.2 Xxxxxxxxxxxxxx
Xxxxxx xxxx xxxxxxxx dvou stanovení xxxxxxxxxxx xxxxxxx xxxx xxxxxx xx xxxxx x xxxxx vzorku xxxxxx xxxxxxxxxxx xx xxxxxxxxx xxxxxxxx xxxxx xxx xxxxx xxx 0,2 xx.
8. Xxxxxxxx
Xxxx xxxxxxxxxx xxxxxxxxx xxxxxxx xx může xxxxxx xxxx xxxxxxxx xxxxxxxxxxxx (4.9), xxx xx xxxxxxx xxxxxx xxxx.
Xxxxxxx xxxxxx xxx Xxxxxxx – Schoorlovo činidlo
|
0,1 xxx/x Xx2X2X3 |
Xxxxxxx, fruktosa, xxxxxxxx xxxx X6X12X6 |
|
|
xx |
xx |
xxxxxx |
|
1 |
2,4 |
|
|
2 |
4,8 |
2,4 |
|
3 |
7,2 |
2,4 |
|
4 |
9,7 |
2,5 |
|
5 |
12,2 |
2,5 |
|
6 |
14,7 |
2,5 |
|
7 |
17,2 |
2,5 |
|
8 |
19,8 |
2,6 |
|
9 |
22,4 |
2,6 |
|
10 |
25,0 |
2,6 |
|
11 |
27,6 |
2,6 |
|
12 |
30,3 |
2,7 |
|
13 |
33,0 |
2,7 |
|
14 |
35,7 |
2,7 |
|
15 |
38,5 |
2,8 |
|
16 |
41,3 |
2,8 |
|
17 |
44,2 |
2,9 |
|
18 |
47,1 |
2,9 |
|
19 |
50,0 |
2,9 |
|
20 |
53,0 |
3,0 |
|
21 |
56,0 |
3,0 |
|
22 |
59,1 |
3,1 |
|
23 |
62,2 |
3,1 |
XXXXXX 7
XXXXXXXXX XXXXXXXXXXXX XXXXX XXXXXXXXXXX XXXX XXXXXXXX XXXX
(Xxxxxx xxxxx Xxxxx x Xxxxxx – xxxxxxxxxx x konstantním xxxxxxx)
1. Xxxxxxx a xxxxxx xxxxxxx
Xxxxxx xxxxxx xx stanovení xxxxxxxxxxxx xxxxx vyjádřených xxxx xxxxxxxx xxxx
- v xxxxxxx xxxxx,
- x xxxxxxx xxxxx xxxxx,
- x xxxxxxx invertním xxxxx,
- v xxxxxxx xxxxx xxxxxxxxx xxxxx,
- x xxxxxx x xxxxxxxxxx xxxxx,
- x xxxxxx x invertního xxxxx xxxxxx.
2. Definice
"Redukující xxxxx xxxxxxxxx xxxx xxxxxxxx cukr": obsah xxxxxxxxxxxx xxxxx xxxxxxxxx xxxxxxxx xxxxxxx.
3. Xxxxxxxx xxxxxx
Xxxxxxxx xxxxxxxxxx xxxxxx xx xxxxxxx xx xxxx xxxx určité xxxxxxxx Fehlingova roztoku x použitím xxxxxxxxxxx xxxxx jako indikátoru.
4. Xxxxxxx xxxxxxx
4.1 Xxxxxxxxx xxxxxx:
4.1.1 Roztok A:
69,3 x síranu xxxxxxxxx xxxxxxxxxxxx (XxXX4·5X2X) xx xxxxxxxx ve vodě x xxxxxx xx xx 1000 xx.
4.1.2 Xxxxxx X:
346,0 x xxxxxx xxxxxxxxxxxxxxx xxxxxxxxxxxx (XXxX4X4X6·4X2X) x 100 x xxxxxxxxx xxxxxxx xx xxxxxxxx xx xxxx a doplní xx 1000 xx. Xxxx xxxxxx se xxxxxx xxxxxxxxx xx xxxxxxxxx, xxxxx se xxxx někdy xxxxxxxx.
Xxxxxxxx:
Xxxx xxx xxxxxxx xx xxxxx xxxxxxxxx x xxxxxxx xxxx xxxxxxxxx xxxxxxxxxx xxxxxxx.
4.2 Roztok xxxxxxxxx xxxxxxx, 1 xxx/x.
4.3 Standardní xxxxxx xxxxxxxxxx xxxxx: 23,750 x xxxxx xxxxxxxxx xx xxxxxxxx xxx xx 120 xx xxxx xx 250mililitrové xxxxxxx baňce, xxxxx xx 9 ml xxxxxxxx chlorovodíkové (xxxxxxx 1,16 x/xx) x xxxxx xx xxxx xxx xxxxxxxxxxx xxxxxxx xx dobu 8 xxx. Roztok se xxxxxx xx 250 xx x xxxxxxxx xxxxxxxxx xx xxxxxxxxxxx xxxxxxxxxxxx xxxx sacharometrem xxxxxx trubice xxxxx 200 xx. Odečtená xxxxxxx xx xx xxxxxx 11,80 ± 0,05 °X (xxx xxxxxxxx 8). 200 xx tohoto roztoku xx xxxxxxxxxx xx 2000xxxxxxxxxxx xxxxxxx baňky, xxxxx se xxxxx x xx stálého xxxxxxxxxxxx (xxx nedošlo x nadměrnému xxxxxxxx xxxxxxxxxxxxx xxxxxxx) se xxxxx 71,4 xx xxxxxxx xxxxxxxxx sodného x xxxxxxxxxxx 1 xxx/x (4.2), ve xxxxxx xxxx xxxxxxxxxx 4 x xxxxxxxx xxxxxxxx. Baňka xx xxxxxx xx 2000 xx, xxx xxxxxxxx xxxxxx xxxxxxxxx 1 x xxxxxxxxxx cukru xx 100 xx. Xxxxxxx xX xxxxxxx xx být xxxxxxxxx xxxxx 3.
Tento xxxxxxxx xxxxxxx xxxxxx xx xx xxx xxxxx xx těsně xxxx xxxxxxxx.
Xxx xxxxxxxx xxxxxxx xxxxxxxxxx xxxxx x xxxxxxxxxxx 0,25 g/100 xx se 250ml xxxxxxx xxxxx xxxxxx xx rysku xxxxxxxx xxxxxxxx x koncentraci 1 x/100 xx xxx 20 °X. Xxxxx xx xxxxxxxxxxxxx xxxxxxx do 1000 xx xxxxxxx xxxxx x xxxxxx se xxx 20 °X xx xxxxx xxxxx.
4.4 Xxxxxx methylenové modři, 1 x/100 ml.
5. Xxxxxxxxx x xxxxxxx
5.1 Xxxxx xxxxx x xxxxx xxxxxx x xxxxxx 500 xx.
5.2 Xxxxxx x objemu 50 xx, xxxxxx xx 0,05 ml, x xxxxxxxxxx xxxxxxxx.
5.3 Xxxxxx x xxxxxxx xx 20, 25 x 50 ml.
5.4 Xxxxxxx xxxxx x xxxxxx 250, 1000 x 2000 ml.
5.5 Xxxxxxxx x xxxxxx, xxxxxx xxx xxxxxxxxx xxxx xx podmínek xxxxxxxxx x xxxx 6.1 x xxxxxxxxxx xxxxxxxx xxxxxxxx xxxxx x konečném bodě, xxxx xx xx xxxxx xxxxx (5.1) xxxxxx xxxxxxxxx ze xxxxxx xxxxx.
5.6 Xxxxxx xxxxxxxxx x xxxxxxxxx xxxxxxx xx 1 xxxxxxx.
6. Xxxxxx
6.1 Stanovení xxxxx Fehlingova xxxxxxx
6.1.1 Xx xxxxx x xxxxx xxxxxxx xx xxxxxxxxxx 50 xx xxxxxxx X (4.1.2), xxxx 50 xx xxxxxxx A (4.1.1) x xxxxx se xxxxxxxx.
6.1.2 Xxxxxx xx xxxxxxxxxx x naplní 0,25 % (0,25 x/100 ml) xxxxxxxxxxx xxxxxxxx xxxxxxxxxx cukru (4.3).
6.1.3 Do 500 xx xxxxx xxxxx (5.1) xx odpipetuje xxxxxxxxx xxxxx 20 xx xxxxxxxx xxxxxxx X x X (6.1.1) a xxxxxxx xx 15 xx xxxx. Z xxxxxx xx xx xxxxx xxxxxx 39 xx xxxxxxx invertního cukru, xxxxx xx xxxxxxx xxxxxxx kamínků x xxxxx se xxxxxx xxxxxxxxx pohybem xxxxxxxx.
6.1.4 Xxxxx xxxxx xx xxxxxxx x varu x nechá xx xxxxx přesně dvě xxxxxx. Xxxxx dalšího xxxxxxx xx baňka xxxxx xxxxxxx xx xxxxxx xxxxx x xxxxx dojít x xxxxxxxxx xxxx.
Xx konci xxxxxxxxxxxxxx xxxx se xxxxxxx xxx xxxx xxxxx kapky roztoku xxxxxxxxxxx xxxxx (4.4). Xxxxx xxxxxxx musí xxx xxxxxxx modrá.
6.1.5 Xxxxxxxxx xx x xxxxxxxxx xxxxxxxxxxxx xxxxxxx xxxxxxxxxx cukru x xxxxxx, xxxxxxxx xx 0,2 xx, pak xx 0,1 xx x xxxxxxx xx xxxxxxx, xx se xxxxxxx xxxxxxxxx xxxx. Xxx xx xxxxxxxxx xxxxxxxxx modrého zbarvení xxxxxxxx methylenové modři. Xxxxx roztoku je xxxxxxxxxxx xxxxxxxxx xxxxxxxxxxx xxxxxxxx xxxxx měďného.
6.1.6 Xxxxxxxxx xxxx xxxxxxx xx xxxx xxx xxxxxxxx xx xxx xxxxx xx začátku xxxx roztoku. Xxxxxxx xxxxxxxx X0 xx xxxx pohybovat x xxxxxxx 39,0 až 41,0 ml. Xx-xx xxxxxxx X0 xxxx xxxxxxx xxxxxx xxxxxxx, xxxxxx xx xxxxxxxxxxx xxxx ve Xxxxxxxxxx xxxxxxx X (4.1.1) x xxxxxxxxx xxxxx xx xxxxxxx.
6.2 Příprava xxxxxxx xxxxxx
Xxxxxxxxxxx xxxxxxx xxxxxxxxxx xxxxxx xx xx xxxxxxxxx x xxxxxxx 250 xx 400 mg xxxxxxxxxx xxxxx xx 100 xx.
6.3 Orientační zkouška
6.3.1 Xx xxxxx xxxxxxx xxxxxxxxxx xxxxxxx xx xxxxxxxx xxxxxxxxxx xxxxxxxx xxxx k 20 xx xxxxxxxx roztoku X x X, xxxxx xxxxxxx, že xxxxxxx objem po xxxxxxx bude xxxxx 75 xx.
Xxxxxxxxx xx xxxxxx xxxxx xxxxxx x bodě 6.1.4, xxxxx xxxxx xxxxxxxxxxxx xxxxxxx invertního xxxxx xx použije roztok xxxxxx, xx. xx xxxxx xx xxxxxxx xxxxxx 25 xx xxxxxxx xxxxxx, přidá xx 15 xx xxxx, xxxxx xx 2 xxxxxx xxxxxxx x roztok xx xxx xxxxxxx xx xx xxxxxxxx xxxxxxxxx xxxx, xxx je xxxxxxx x xxxx 6.1.5.
6.3.2 Xxxxx po xxxxxxxx xxxxxxx xxxxxxxxxxx xxxxx přetrvává xxxxxxxxxxx xxxxxxxx, xx xxxxxxx xxxxxx xxxxxx příliš xxxxxxxxxxxxx. X xxxxx xxxxxxx xx xxxxxxx xxxxxxx a xxxxxxx xx xxxxxxxxx stanovení x xxxxx xxxxxxxxxxx xxxxxxx xxxxxx.
Xx-xx k xxxxxxxx načervenalého xxxxxxxx xxxxxxxxx xxxx než 50 xx xxxxxxx xxxxxx, xxxx xx xxxxxx xxxxxx xxxxxx x xxxxx xxxxxxxxxxx.
Xxxxxxxx xxxx, xxxxx xx xx xxxxxx, xx xxxxxxxx xxxxxxxxx xxxxxx xxxxxxxx Xxxxxxxxxx roztoku (20 ml) x xxxxxx xxxxxxx xxxxxx xx 75 xx.
6.4 Xxxxxxx xxxxxxx xxxxxxx xxxxxx
6.4.1 Do xxxxx xxxxx xx odpipetuje 20 ml směsného Xxxxxxxxxx roztoku x xxxxxxxx vody xxxxxxxxx xxxxx xxxx 6.3.
6.4.2 X xxxxxx xx xxxxxx roztok vzorku x xxxxxxxx stanoveném xxxxx xxxx 6.3, xxxxxxxx x 1 xx. Xxxxx xx xxxxxxx xxxxxxx xxxxxxx, xxxxx baňky xx xxxxxxxxx pohybem xxxxxxxx, xxxxxx x xxxxxxx xxxxx xxxxxxxxxxx xxxxx (6.3). Xxxxxxxxx xxxx xxxxxxx musí xxx xxxxxxxx jednu minutu xx přidání xxxxxxx xxxxxxxxxxx xxxxx. Spotřeba xxx xxxxxxx titraci xx rovná X1.
7. Xxxxxxxxx xxxxxxxx
7.1 Xxxxxx x xxxxxx xxxxxxx
Xxxxx xxxxxxxxxxxx cukrů xx xxxxxx xxxxxxxxx jako xxxxxxxx xxxx se xxxxxxxx xxxxx xxxxxx:
xxx:
X = xxxxxxxxxxx xxxxxxx xxxxxxxxxx xxxxxx (x/100 xx),
X0 = xxxxxxxx xxxxxxxxxxxx xxxxxxx invertního xxxxx (xx) při xxxxxxxxx xxxxx,
X1 = xxxxxxxx xxxxxxx xxxxxxxxxx xxxxxx (ml) při xxxxxx xxxxxxx (6.4.2),
x = xxxxxxxx faktor xxxxxxxxxxxx koncentraci sacharosy xxxxxxxx v xxxxxxx xxxxxxxxxx xxxxxx; hodnoty xxxx xxxxxxx x xxxx xxxxxxx tabulce:
|
Sacharosa (x xx směsi xxxxxxx xx xxxx) |
Xxxxxxxx xxxxxx f |
|
0,0 |
1,000 |
|
0,5 |
0,982 |
|
1,0 |
0,971 |
|
1,5 |
0,962 |
|
2,0 |
0,954 |
|
2,5 |
0,946 |
|
3,0 |
0,939 |
|
3,5 |
0,932 |
|
4,0 |
0,926 |
|
4,5 |
0,920 |
|
5,0 |
0,915 |
|
5,5 |
0,910 |
|
6,0 |
0,904 |
|
6,5 |
0,898 |
|
7,0 |
0,893 |
|
7,5 |
0,888 |
|
8,0 |
0,883 |
|
8,5 |
0,878 |
|
9,0 |
0,874 |
|
9,5 |
0,869 |
|
10,0 |
0,864 |
Korekce pro xxxx xxxxxxxx xxxxxxxxx x roztoku xxxxxxxxxx xxxxxx xx xxxxx xxxxxxxxx x tabulkových xxxxxx xxxxxxxxxxx.
Xxxxxxxx:
Xxxxxxxxx xxxxxxxxxxx xxxxxxxxx se xxxx xxxxxxxx xxxxxxxxx koncentrace xxxxxxxxxxxx xxxxxxx látek x xxxxxxxxxx xxxxx (xxx xxxxx výpočet xx xxxxxxx hodnota x xxxxx 1,0) xx xxxxxxxxxxx xxxxxxxxx xxxxxxxxxxxx xxxxx xxxxxxxxxxx xxxx xxxxxxxxx x xxxxxxxxxxx xx xxxxxxx xxxxxx lomu xxxxx xxxxxx 3 tohoto xxxxxxxx.
7.2 Opakovatelnost
Rozdíl xxxx xxxxxxxx dvou xxxxxxxxx xxxxxxxxxxx zároveň xxxx xxxxxx xx xxxxx x téhož xxxxxx xxxxxx pracovníkem za xxxxxxxxx xxxxxxxx xxxxx xxx xxxxx xxx 1,0 % xxxxxx xxxxxxxxxxxxx xxxxxxx.
8. Xxxxxxxx
Xxx xxxxxxx hodnoty ve °X xx polarimetrické xxxxxx stupně se xxxx xxxxxxx xxxxx x xxxxxxxxxx °X xxxx xxxxxxxx 2,889 (xxxxxxxxxxxxxx trubice x xxxxx 200 xx; xxxxxxxx výbojka xxxx xxxxxxxx xxxxx; xxxxxxxx xxxxxxxx x místnosti, xx které xx xxxxx udržovat xxxxxxx xxxxxxx 20 °X).
XXXXXX 8
XXXXXXXXX DEXTROSOVÉHO EKVIVALENTU
(Metoda xxxxx Xxxxx x Xxxxxx s xxxxxxxxxxx xxxxxx)
1. Xxxxxxx a xxxxxx použití
Tato metoda xxxxxx ke xxxxxxxxx xxxxxxxxxxxx ekvivalentu
- xx xxxxxxxxx xxxxxx,
- x xxxxxxx xxxxxxxxx xxxxxx,
- x dextrose xxxxxxxxxxx,
- x dextrose xxxxxxx.
2. Xxxxxxxx
2.1 "Xxxxxxxx xxxx": xxxxx xxxxxxxxxxxx xxxxx xxxxxxxxx xxxxxxxx xxxxxxx, xxxxxxxxx xxxx xxxxxxx xxxxxxxx (X-xxxxxxx) x xxxxxxxxx v procentech xxxxxxxxx xxxxxx.
2.2 "Dextrosový xxxxxxxxxx": redukční síla xxxxxxxxx v procentech xxxxxxxxx xxxxxx xxxxxx.
3. Xxxxxxxx xxxxxx
Xxxxxxxx xxxxxxxxxx xxxxxx xx xx xxxxxx určených podmínek xxxxxxx xx xxxx xxxx xxxxxx objem xxxxxxxx Xxxxxxxxxx xxxxxxx x xxxxxxxx methylenové xxxxx xxxx indikátoru.
4. Xxxxxxx xxxxxxx
4.1 Xxxxxxxxx xxxxxx:
4.1.1 Roztok A:
Ve xxxx se rozpustí 69,3 x xxxxxx xxxxxxxxx xxxxxxxxxxxx (CuSO4·5H2O) x x odměrné xxxxx o xxxxxx 1000 ml xx xxxxxx po xxxxx.
4.1.2 Xxxxxx B:
Ve xxxx xx xxxxxxxx 346,0 x xxxxxx xxxxx-xxxxxxxxxx xxxxxxxxxxxx (XXxX4X4X6·4X2X) x 100 x xxxxxxxxx xxxxxxx x v xxxxxxx xxxxx o xxxxxx 1000 ml xxxxxx xxxxx po xxxxx. Xxxx xxxxxx xx dekantací xxxxxx xx xxxxxxxxx, která xx může někdy xxxxxxxx.
Xxxxxxxx:
Xxxx xxx xxxxxxx (4.1.1 x 4.1.2) xx třeba xxxxxxxxx x xxxxxxx xxxx xxxxxxxxx zbarvených xxxxxxx.
4.1.3 Xxxxxxxx xxxxxxxx Fehlingova xxxxxxx
Xx xxxxx xxxxxxx xx odpipetuje 50 xx xxxxxxx X (4.1.2) x poté 50 ml xxxxxxx X (4.1.1) x xxxxx xx xxxxxxxxxx.
Xxxxxxxx:
Xxxxxx Xxxxxxxxx xxxxxx se xxxxx uchovávat, xxxxx xx xxxx xxxxx xxx připravovat xxxxxxx x standardizovaný (6.1).
4.2 Xxxxxxx xxxxxxxx (X-xxxxxxx) (X6X12X6)
Xxxxx xxxxxxxx xx xxxxx xxxx xxxxxxxx 4 xxxxxx xxxxx xx xxxxxxx sušárně xxx xxxxxxx 100 ± 1 °C xxxx xxxxx x xxx xxxxx xxx 10 kPa (103 xxxx).
4.3 Xxxxxxxxxx xxxxxx xxxxxxxx, 0,600 x/100 xx
X xxxxxxxxx xx 0,1 xx se xxxxxx 0,6 x xxxxxxx xxxxxxxx (4.2), xxxxxxxx xx ve xxxx, kvantitativně xxxxxxx xx xxxxxxx xxxxx x xxxxxx 100 xx (5.4), xxxxxx xxxxx xx xxxxx x promíchá.
Tento roztok xx xxxxx xxxxxxxxx xxxxxxx na xxxxx xxx, kdy bude xxxxxxxx.
4.4 Xxxxxx methylenové xxxxx, 0,1 g/100 xx xxxx
Xxxxxxxx xx 0,1 x xxxxxxxxxxx xxxxx xx 100 xx xxxx.
5. Přístroje x xxxxxxx
5.1 Xxxxx xxxxx s xxxxx xxxxxx x objemu 250 ml.
5.2 Xxxxxx x xxxxxx 50 xx, x xxxxxxxxxx xxxxxxxx a xxxxxx xx 0,05 xx.
5.3 Xxxxxx xxxxxxxx s xxxxxxx 25 xx x 50 xx.
5.4 Xxxxxxx xxxxx o xxxxxx 100 x 500 xx.
5.5 Zařízení x xxxxxx, xxxxxx xxx udržování xxxx x xxxxxxx x xxxxxxxxxx xxxxxxxxx v xxxx 6.1 x xxxxxxxxxx xxxxxxxx xxxxxxxx xxxxx v xxxxxxxx xxxx xxx xxxxxxxx xxxxxxx xxxxxx xxxxx (5.1) ze xxxxxx xxxxx (viz bod 6.1 poznámka 3).
5.6 Xxxxxx ukazující s xxxxxxxxx xxxxxxx xx 1 xxxxxxx.
6. Xxxxxx
6.1 Xxxxxxxxxxxxx Xxxxxxxxxx xxxxxxx
6.1.1 Xx čisté suché xxxxx xxxxx (5.1) xx xxxxxxxxxx 25 xx Xxxxxxxxxx roztoku (4.1.3).
6.1.2 Xxxxxx (5.2) xx naplní xxxxxxxxxxx xxxxxxxx dextrosy (4.3) x xxxxxxxx se xxxxxxx xx nulovou xxxxx.
6.1.3 Do varné xxxxx (5.1) se x xxxxxx napustí 18 ml standardního xxxxxxx dextrosy (4.3) x xxxxx xx xxxxxxxxx pohybem xxxxxxxx.
6.1.4 Xxxxx baňka xx xxxxxx na xxxxxxxx x xxxxxx (5.5), xxxxxx xxxxxxxxx xxx, xxx xxx nastal xx 120 ± 15 xxxxxx.
X xxxxx xxxxxxx xxxxxxx xxxxx xxx xxxxxxxx x xxxxxx xxxxxxxxxxx xxxxx (xxx poznámka 1).
6.1.5 Xxxxxxx xx roztok xxxxx xxxxx, spustí xx stopky xx xxxx.
6.1.6 Xxxxx xxxxx xx xxxxxx 120 xxxxxx (xxxxx xxxxxx).
Xx xxxxx se přidá 1 xx roztoku xxxxxxxxxxx xxxxx (4.4).
6.1.7 Xx 120 xxxxxxxxx (xxxxx xxxxxx) xx xxxxxxx xxxx xx xxxxx x xxxxxx (6.1.2) xx xxxxx xxxxx (5.1) xxxxxxxx xxxxxxxxxx xxxxxx dextrosy xx 0,5xx dávkách, xxxxx xx xxxxxxxxxxx xxxx xxxxxxxxx (viz xxxxxxxx 2 a 3).
Xxxxxxxxx xx xxxxxxx xxxxx xxxxxxxxx xxxxxxxxxxxx xxxxxxx xxxxxxxx (X xx) xxxxxx xxxxxxxxxxxx 0,5xx xxxxx.
6.1.8 Xxxxx x xxxxxx 6.1.1 x 6.1.2 se xxxxxxxx.
6.1.9 X xxxxxx xx xx xxxxx xxxxx (5.1) napustí (X 0,3) xx xxxxxxxxxxxx xxxxxxx dextrosy.
6.1.10 Xxxxx x xxxxxx 6.1.4, 6.1.5 x 6.1.6 se zopakují.
6.1.11 Xx 120 xxxxxxxxx (xxxxx xxxxxx) xx xxxxxxx varu se xxxxx x xxxxxx xx xxxxx baňky (5.1) přidávat xxxxxxxxxx xxxxxx xxxxxxxx, xxxxxxxx xx 0,2ml dávkách x nakonec xx xxxxxxx, xxxxx se xxxxxxxxxxx xxxx xxxxx xxxxxxxxx.
Xx xxxxx tohoto xxxxxxx musí xxx xxxx xxxx dvěma xx sobě xxxxxxxxxxxxx xxxxxxxx xxxxxxxxxxxx xxxxxxx xxxxxxxx 10 až 15 sekund.
Toto xxxxxxxxx xxxx xxx xxxxxxxxx xxxxx 60 sekund x xxxxxxx xxxx xxxx xxxx nesmí xxxxxxxxx 180 xxxxxx.
X xxxxxx xxxxx xxxx xxx xxxxxxxxx xxxxxxx xxxxx xxxxxxx x xxxxxxx xxxxx, příslušně xxxxxxxxx počáteční dávkou xxxxxxxxxxxx xxxxxxx dextrosy (6.1.9).
6.1.12 Xxxxxxxxx se xxxxxxx spotřeba (X0 xx) xxxxxxxxxxxx roztoku xxx závěrečné xxxxxxx (xxx poznámka 4).
6.1.13 Xxxxxxx X0 xxxx xxx x xxxxxxx 19,0 až 21,0 xx xxxxxxxxxxxx xxxxxxx xxxxxxxx (4.3).
Xxxxx xx xxxxxxx X0 nachází xxxx xxxx xxxxxxx, xxxxxxxxx xx upraví xxxxxxxxxxx Fehlingova roztoku X (4.1.1) x xxxxxxxxxxxxxx xxxxxx xx xxxxxxxx.
6.1.14 Xxxxxxxx x xxxx, že xxxxxxx X0 xx přesně xxxxx, je xxxxx xxx každodenní standardizaci xxxxxxx xxxxx xxxxxxx x xxxxxxxxxx xxxxxxxxx xxxxxxxxxxxx xxxxxxx xxxxxxxx X0 – 0,5.
Xxxxxxxx 1:
Xxxxx xx xxxxxxxxx, xx jakmile nastane xxx, xxxxxxxx páry xx xxxxxx a xxxxxxxxxxx během celé xxxxxxxx xxxxxxxxx a x co xxxxxxxx xxxx xx xxxxxxx xxxxxxxx xxxxxxx xx xxxxxxxx xxxxx x xxxxxxxx xxxxxxxx oxidaci xxxxxx xxxxxx.
Xxxxxxxx 2:
Xxxxxxxxx xxxxxxx xxxxxxxxxxx xxxxx xx xxxxxxx pozorovatelné x xxxxxxx xxxxxxxx xxxxxx titrační baňky x x xxxxxxx xxxxxxx, xx. x xxxxxxx, které x xxxxxxxx xxxxxxxxxx xxxxxxx xxxxxxx xxxx měďnatý. Xxxxxxxxx xx xxxxxxxx xxxxxxxxxxxxx xx nepřímého xxxxxxxxx. Je výhodné xxxxxx stínítko xx xxxxxxxx xxxxxx.
Xxxxxxxx 3:
Byreta xx měla být xxxxx xxxxxxxxx xx xxxxxxx chráněna xxxx xxxxxxx xxxxx.
Xxxxxxxx 4:
Vzhledem x xxxx, xx xxxxx xxxxx vyloučit xxxxxxxxxxx xxxxxx, xxxx xxxxx pracovník xxxxxxxx xxxx vlastní standardizační xxxxxxx x xxx xxxxxxx xxxx použít xxxx xxxxxxx xxxxxxx X0 (7.1).
6.2 Xxxxxxxxxx xxxxxxx xxxxxxxxxxxx xxxxxx
6.2.1 Xxxxx není známa xxxxxxxxx hodnota redukční xxxx (2.1) xxxxxxxxxxxx xxxxxx, je nutno xxxxxxx předběžnou xxxxxxx, xxx xx xxxxxxx xxxx xxxxxxxxx xxxxxxx, x mohla xxx xxx xxxxxxxxx xxxxxxxx xxxxxxxxxx xxxxxx (6.3).
Xxxx xxxxxxx xx xxxxxxx xxxxx:
6.2.2 Xxxxxxxx xx X % (x/X) xxxxxx vzorku, "X" xx xxxxxxxxxx xxxxxxx.
6.2.3 Xxxxxxxxx xx xxxx x xxxx 6.1.2 x xxxxxxxx xxxxxxx xxxxxx (6.2.2) namísto xxxxxxxxxxxx xxxxxxx xxxxxxxx.
6.2.4 Xxxxxxxxx xx jako x bodě 6.1.1.
6.2.5 Xxxxxxxxx xx xxxx x xxxx 6.1.3 x xxxxxxxx 10 xx xxxxxxx xxxxxx xxxxxxx 18,0 xx xxxxxxxxxxxx xxxxxxx xxxxxxxx.
6.2.6 Xxxxxxxxx xx xxxx x xxxx 6.1.4.
6.2.7 Xxxxx xxxxx se xxxxxxx k varu. Xxxxx xx 1 xx xxxxxxx xxxxxxxxxxx xxxxx (4.4).
6.2.8 Jakmile xxxxxxx xxx, xxxxxx xx stopky (5.6) xx nuly a xxxxx xxxxxxxxx roztoku xxxxxx z byrety xx baňky xx 1,0 xx xxxxxxx x odstupem xxx 10 xxxxxx, a xx až xx xxxxxxxxx methylenové modři.
Zaznamená xx xxxxxxx xxxxxxxx xxxxxxxxxxxx xxxxxxx xxxxxxxx (X ml) xxxxxx xxxxxxxxxxxx 0,5 xx xxxxx.
6.2.9 Xxxxxxx "X" xxxxx xxxxxxxxxx 50 xx. Xxxxx x xxxx dojde, je xxxxx xxxxxx koncentraci xxxxxxx xxxxxx a xxxxxxx zopakovat.
6.2.10 Xxxxxxxxx xxxxxxx xxxxxxxx xxxx xxxxxxxxxxxx vzorku xx xxxxxxxxx dána xxxxxxx (x %):
6.3 Zkušební xxxxxx
X přesností na 0,1 mg xx xxxxxx xxxxxx množství xxxxxxxxxxxx xxxxxx (xx), xxxxx xxxxxxxx 2,85 xx 3,15 x xxxxxxxxxxxx xxxxx vyjádřených xxxx xxxxxxx xxxxxxxx (Xxxxxxxx). Xxx xxxxxxx xx xxxxxxx xxx xxxxx xxxxxxxxx hodnota xxxxxxxx síly (2.1), xxxx xxxxxxxxx xxxxxxx xxxxxxx x xxxx 6.2.10.
6.4 Xxxxxxxx roztok
Zkušební xxxxxx xx x xxxxxxx xxxxx x xxxxxx 500 ml xxxxxxxx xx xxxx x xxxxx xxxxxx xx rysku.
6.5 Xxxxxxxxx
6.5.1 Xxxxxxxxx xx xxxx x bodě 6.1.1.
6.5.2 Xxxxxx (5.2) xx xxxxxx zkušební roztokem (6.4) x xxxxxxxx xx nastaví na xxxx.
6.5.3 X byrety xx do xxxxx xxxxx xxxxxxx 18,5 xx xxxxxxx zkušebního xxxxxxx. Vířením xx xxxxx xxxxx zamíchá.
6.5.4 Xxxxxxxxx xx xxxx x bodě 6.1.4.
6.5.5 Xxxxxxxxx xx xxxx x bodě 6.1.5.
6.5.6 Xxxxxxxxx se jako x bodě 6.1.6.
6.5.7 Xxxxxxxxx xx xxxx x bodě 6.1.7, x xxxxxxxx xxxxxxxxxx xxxxxxx xxxxxxx xxxxxxxxxxxx xxxxxxx xxxxxxxx.
6.5.8 Xxxxxxxxx xx xxxx v xxxx 6.1.8.
6.5.9 Xxxxxxxxx xx xxxx x xxxx 6.1.9, x xxxxxxxx xxxxxxxxxx roztoku xxxxxxx xxxxxxxxxxxx roztoku xxxxxxxx.
6.5.10 Xxxxxxxxx se xxxx x xxxx 6.1.10.
6.5.11 Postupuje xx xxxx v bodě 6.1.11, x xxxxxxxx xxxxxxxxxx xxxxxxx xxxxxxx xxxxxxxxxxxx roztoku xxxxxxxx.
6.5.12 Xxxxxxxxx se xxxxx (X1) spotřebovaného zkušebního xxxxxxx xxx xxxxxxxxx xxxxxxx.
6.5.13 Xxxxxxx V1 xxxx xxx x xxxxxxx 19,0 xx 21,0 xx xxxxxxxxxx xxxxxxx.
Xxxxx xx xxxxxxx X1 nachází mimo xxxx rozmezí, xxxxxx xx xxxxxxxxxxx xxxxxxxxxx xxxxxxx x xxxxx 6.5.1 xx 6.5.12 xx xxxxxxxx.
6.5.14 Provedou xx xxx xxxxxxxxx x xxxxxxxx téhož xxxxxxxxxx xxxxxxx.
6.6 Xxxxx xxxxxx
Xxxxxx metody 2 xx xxxxxxx xxxxx xxxxxx připraveného xxxxxx.
7. Xxxxxxxxx výsledků
7.1 Xxxxxx x postup xxxxxxx
7.1.1 Xxxxxxxx síla
Redukční xxxx xxxxxxxxx x procentech xxxxxxxxxxxx xxxxxxxxxxxx vzorku xx xxxx xxxxxxx:
xxx
X0 = xxxxx (xx) xxxxxxxxxxxx xxxxxxx xxxxxxxx (4.3) xxxxxxxxxxxx xxx xxxxxxxxxxxxxx titraci (6.1),
V1 = xxxxx (xx) xxxxxxxxxx xxxxxxx (6.4) xxxxxxxxxxxxxx xxx xxxxxxx x postupu xxxxxxxxx (6.5),
X = xxxxxxxx xxxxxxxxxx vzorku (x) (6.3) xxxxxxxxx x xxxxxxxx 500 xx xxxxxxxxxx xxxxxxx.
7.1.2 Dextrosový xxxxxxxxxx
Xxxxxxxxxx xxxxxxxxxx xxxxxxxxx x xxxxxxxxxx xxxxxxxxx xxxxxx připraveného xxxxxx xx dán xxxxxxx:
xxx
XX = redukční xxxx xxxxxxxxx x procentech xxxxxxxxxxxx xxxxxxxxxxxx vzorku (7.1.1),
X = obsah xxxxxx xxxxxxxxxxxx xxxxxx x xxxxxxxxxx xxxxxxxxxxxx.
7.1.3 Xxxxxxxxx je xxxxxxxxxxx xxxxxx xxxxxxxx xxxx xxxxxxxxx xx xxxxxxxxxxx, xx xx splněn xxxxxxxxx xxxxxxx na xxxxxxxxxxxxxx (7.2).
7.2 Xxxxxxxxxxxxxx
Xxxxxx xxxx výsledky dvou xxxxxxxxx xxxxxxxxxxx zároveň xxxx xxxxxx xx xxxxx x xxxxx xxxxxx xxxxxx xxxxxxxxxxx xx totožných xxxxxxxx xxxxx xxx větší xxx 1,0 % xxxxxx aritmetického xxxxxxx.
XXXXXX 9
XXXXXXXXX XXXXXXXXXX XXXXXX
1. Xxxxxxx a xxxxxx xxxxxxx
Xxxxxx slouží xx xxxxxxxxx xxxxxx síranového xxxxxx
- xx xxxxxxxxx xxxxxx,
- v sušeném xxxxxxxxx xxxxxx,
- x xxxxxxxx xxxxxxxxxxx,
- v xxxxxxxx xxxxxxx.
2. Definice
"Obsah xxxxxxxxxx xxxxxx": xxxxx xxxxxxxxxx popela stanovený xxxxxxxx metodou.
3. Xxxxxxxx xxxxxx
Xx zpopelnění xxxxxxx xxxxxxxxxx vzorku x xxxxxxxx atmosféře při 525 °C za xxxxxxxxxxx kyseliny xxxxxx xx xxxxxxxxx xxxx xxxxxxxx xxxxxxxx a xx xxxxxxxxx x xxxxxxxxxx xxxxxxxxxxxx vzorku.
4. Xxxxxxx xxxxxxx
4.1 Kyselina xxxxxx, xxxxxxx roztok: xxxxxx a xxxxxxx xx xxxxxxx 100 xx xxxxxxxxxxxxx xxxxxxxx xxxxxx (xxxxxxx při 20 °C = 1,84 g/ml; 96 % m/m) do 300 xx vody xx xxxxxxxxxx xxxxxxx x xxxxxxxx.
5. Přístroje x xxxxxxx
5.1 Xxxxxxxxxx xxxxxxx pec, vybavená xxxxxxxxxx x umožňující xxxxxx xxx xxxxxxx 525 ± 25 °X.
5.2 Xxxxxxxxxx xxxx, xxxxxx x xxxxxxxxx xx 0,1 xx.
5.3 Xxxxxxx xxx stanovení xxxxxx, xxxxxxxxx či xxxxxxxx, vhodného xxxxxx.
5.4 Xxxxxxxxx xxxxxxxxxx xxxxxxx xxxxxxxxxx xxxxxxxxx xxxx xxxxxxxxxxxx xxxxxxxxxx s xxxxxxxxxxx xxxxxx xxxxxxxx.
6. Xxxxxx
Xxxxxxx (5.3) xx xxxxxx xx xxxxxxxxxxxx xxxxxxx, xxxxxxx xx x xxxxxxxxxx xxxxxxxxxxx x xxxxx se. Xx xxxxxxx xx xxxxxx (xx 0,1 xx) odváží 5 x xxxxxxxxxx xxxxxx xxxx sušeného xxxxxxxxxx xxxxxx, xxxxxxxx 10 x xxxxxxxx xxxxxxxxxxx xxxx xxxxxxxx xxxxxxx.
Xxxxx xx 5 ml xxxxxxx kyseliny xxxxxx (4.1) (xxx xxxxxxxx 8.1) x vzorek xx x xxxxxxx xxxxxxx xxxxxxx xxx xxxxxxxx nebo xx xxxxx xxxxxxxx xxx xxxxxx, dokud xxxxx xxxxxxxxxxx. Zuhelnatění, během xxxxx xxxxxxxxxx výpary xx vzorku (viz xxxxxxxx 8.2), se xxxx provádět x xxxxxxxxx.
Xxxxxxx (5.3) xx xxxxxx xx muflové xxxx (5.1), předehřáté xx 525 ± 25 °X, a xxxxxxx xx v xx, xxxxx nevznikne xxxx popel. Xx xxxxxxx xxxx dvě xxxxxx (viz xxxxxxxx 8.3).
Xxxxxx xx xxxxx xxx 30 xxxxx xxxxxxxxxxx x exsikátoru (5.4) a xxxx xx xxxxx.
7. Xxxxxxxxx xxxxxxxx
7.1 Xxxxxx a xxxxxx xxxxxxx
Xxxxx xxxxxxxxxx xxxxxx xxxxxxxxx x xxxxxxxxxx hmotnostních xxxxxx xxxxxxxx x xxxxxxx xx xxx xxxxxxx:
xxx
x1 = xxxxxxxx xxxxxx (x),
x0 = hmotnost xxxxxxx zkušebního vzorku (x).
7.2 Xxxxxxxxxxxxxx
Xxxxxx mezi xxxxxxxx xxxx xxxxxxxxx xxxxxxxxxxx xxxxxxx xxxx xxxxxx xx xxxxx x xxxxx xxxxxx xxxxxx pracovníkem xx xxxxxxxxx podmínek xxxxx xxx xxxxx než 2,0 % xxxxxx xxxxxxxxxxxxx xxxxxxx.
8. Xxxxxxxx
8.1 Xxxxxxxx xxxxxx xx xxxxxxx xx malých xxxxxxx, aby se xxxxxxxxx přílišnému pěnění.
8.2 Xxx prvním xxxxxxxxxxx xx xxxxx xxxxxxxxxx xxxxxxxx obezřetně, xxx xxxxxxx xx ztrátám xxxxxx xxxx xxxxxx xxxxx xxxxxxxxxx bobtnání xxxxxx.
8.3 Xxxxx xx xxxxxxx xxxxxxxxx úplného xxxxxxxxxx (tj. xxxxxxxxx xxxxx xxxxxxx), xxxxxxx xx xxxxx x xxxxxxx xxxx xxxxxxx, xxxxxx xx xxxxxxxxx xxxxxxx xxxxxxxx xxxxxxx xxxx x opět xxxxxx xx pece.
METODA 10
XXXXXXXXX XXXXXXXXXX
1. Xxxxxxx x xxxxxx použití
Metoda xxxxxx xx xxxxxxxxx xxxxxxxxxx
- v cukru xxxxxxxxx,
- v xxxxx xxxx v cukru xxxxx,
- v xxxxx xxxxx xxxxx.
2. Xxxxxxxx
Xxxxxxxxxx xx rozumí schopnost xxxxxxxxx roztoku xxxxxxxxxxxx 26 g xxxxx xx 100 xx, xxxxx xx uzavřen x xxxxxxx x xxxxx 200 xx, xxxxxx xxxxxx xxxxxxxxxxxxxx xxxxxx.
3. Xxxxxxxx xxxxxx
Xxxxxxxxxx xx stanoví xxxxxx xxxxxxxxxxxx nebo xxxxxxxxxxx xx podmínek xxxxxxxxx x xxxx xxxxxxx xxxxxx.
4. Xxxxxxx činidla
4.1 Xxxxxx xxxxxxx: xxxxxxx xxxxxx octanu xxxxxxxxxx.
Xx xxx 1000 xx xxxxxxx xxxxxxxxx xxxx xx přidá 560 x xxxxxxx bazického xxxxxx xxxxxxxxxx. Směs xx 30 xxxxx xxxx x xxxx xx xxxxx stát xxxx noc.
Tekutý xxxxxxxxxxx xx xxxxxxxxx a xxxxx xxxxxxx převařenou xxxxx xxx, xxx xxxxxx xxxxxx x xxxxxxx 1,25 x/xx (xxx 20 °X).
Xxxxx xxxxxx xx xxxxx xxxxxxx xxxx xxxxxxxxx xxxxxxx.
4.2 Xxxxxxxxxxxx
5. Přístroje x xxxxxxx
5.1 Xxxxxxxxxxx xxxxxxxxxxxx xx normální xxxxxxxx 26 g xxxxxxxxx, xxxxxxxxx xxxxxxxxxx
Xxxxx xxxxxxxx xxxx xxx xxxxxxx x xxxxxxxxx, xx xxxxx xx xxxxx xxxxxxxx xxxxxxx xxxxx 20 °X. Xxxxxxxx xx okalibruje xxxxxx xxxxxxxxxxxx xxxxxxxxxx xxxxx.
5.2 Xxxxxxxx xxxxx xxxxxxxxxxx ze xxxxxxxx xxxxxxx.
5.3 Přesné xxxxxxxxxxxxxx xxxxxxx x délce 200 mm x xxxxxxxxx ± 0,02 xx.
5.4 Analytické xxxx, xxxxxx x xxxxxxxxx xx 0,1 xx.
5.5 Xxxxxxxxxx xxxxxxxxxxx xxxxxxx xxxxx o xxxxxx 100 xx se xxxxxxx. Xxxxx xx xxxxxxxxx xxxxxxx x xxxxxxx 100,00 ± 0,01 xx mohou xxx xxxxxxx bez xxxxxxx. Baňky s xxxxxxx mimo uvedené xxxxxxx xxxxx xxx xxxxxxx xxxxx x xxxxxxxxx korekcí xx 100 xx.
5.6 Vodní xxxxx xxxxxx termostatem, xxxxxxxxx xx 20 ± 0,1 °X.
6. Xxxxxx
6.1 Xxxxxxxx roztoku
Co xxxxxxxxxxx xx naváží 26 ± 0,002 x vzorku a xxxxxxxxxxxxx xx xxxxxxx xx xxxxxxx xxxxx x xxxxxx 100 xx (5.5) xxxxxxxxxx xxx 60 ml xxxx.
Xxxxxx se rozpustí xxxxxxx, xxxxxx xxxx xxxxxxxxxx.
Xxxxx xx xxxxx xxxxxx xxxxxxx, přidá xx 0,5 ml xxxxxxx xxxxxx olovnatého (4.1).
Xxxxxx se xxxxx xxxxxxxxx pohybem baňky x stěny xxxxx xx xxxxxxxxx xxx xxxxxx, dokud meniskus xxxxxxxxxx xxx 10 xx xxx xxxxxxxxxx xxxxx.
Xxxxx xx umístí xx xxxxx xxxxx (5.6) xxxxxxxxxx při 20 ± 0,1 °X x xxxxxxx xx zde xxx xxxxxx, xxxxx se xxxxxxx xxxxxxxxx xxxxxxx xxxxxxxx.
Xxxxxxx xxxxxxx xxxxxxxxx xx xxxxxxx xxxxxxxx xx xxxxxxxx kapkou xxxxxxxxxxxxx (4.2).
Xxxxxx se xxxxxx xxxxx xx xxxxx.
Xxxxx xx xxxxxxxxx x xxxxx xx xxxxxxxx alespoň xxxxxxxxxxxx xxxxxxxxx xxxx vzhůru.
Baňka xx xxxxx xxx xxxxx xxxx.
6.2 Stanovení xxxxxxxxxx
Xx xxxx xxxxx xxxx uvedených xxxxx xx xxxxxxx teplota 20 ± 0,1 °X.
6.2.1 Xxxxxxxxxx xx xxxxxxx xx xxxx.
6.2.2 Xxxxxx xx xxxxxxxxxxx xxxx xxxxxxxxx papír. Xxxxxxx 10 xx xxxxxxxx xx xxxxxxxxx. Xxxx xx xx xxxxxxx 50 xx xxxxxxxx.
6.2.3 Xxxxxxxxxxxxxx xxxxxxx xx xxxxxxx dvojnásobným xxxxxxxxxxxxx xxxxxxxx xxxxxx xxxxxxxx x xxxxxxx (6.2.2).
6.2.4 Xxxxxxx xx xxx xxxxxxx 20 ± 0,1 °X xxxxxxx xxxxxx roztokem xxxxxx určeného x xxxxxxx.
Xxx zasouvání xxxxxxxxx xxxxxxxx xx xxxxxxxx xxxxxxx vzduchové xxxxxxx. Xxxxxxxx xxxxxxx xx xxxxxx xx xxxxxxx xxxxxxxxx.
6.2.5 Xxxxxx se xxxxxxxxxx s xxxxxxxxx xx 0,05°X nebo 0,02 xxxxxxxx stupňů. Xxxxx se zopakuje xxxxx xxxxxxxxx. Vypočte xx průměr x xxxxxx pěti xxxxxx.
7. Xxxxxxxxx výsledků
7.1 Xxxxxx x xxxxxx výpočtu
Výsledky xxxx xxxxxxxxx ve xxxxxxxx X s xxxxxxxxx xx 0,1°X. Xxx xxxxxx xxxxxxxx xxxxxx na xxxxxx X xx xxxxxxx xxxxx xxxxxx:
X = xxxxxx xxxxxx × 2,889
7.2 Xxxxxxxxxxxxxx
Xxxxxx xxxx xxxxxxxx dvou xxxxxxxxx xxxxxxxxxxx zároveň xxxx xxxxxx xx xxxxx x xxxxx xxxxxx xxxxxx pracovníkem za xxxxxxxxx xxxxxxxx xxxxx xxx větší xxx 0,1°X, xxxxxxx xxxxxxxx xxxxxxx stanovení xx xxxxxxxx z xxxx xxxxxx.