Xxxxx směrnice Xxxxxx
xx xxx 26. xxxxxxxx 1979,
xxxxxx se xxxxxxx xxxxxxxxxx xxxxxx Xxxxxxxxxxxx xxx zkoušení xxxxxxxxx xxxxx určených x xxxxxx xxxxxxxx
(79/796/XXX)
XXXXXX XXXXXXXXXX XXXXXXXXXXXX,
x xxxxxxx na Xxxxxxx o xxxxxxxx Xxxxxxxxxx hospodářského společenství,
s xxxxxxx xx směrnici Xxxx 73/437/EHS xx xxx 11. xxxxxxxx 1973 o xxxxxxxxxx xxxxxxxx xxxxxxxx členských xxxxx xxxxxxxxxx se xxxxxxxxx xxxxx xxxxxxxx x lidské xxxxxxxx [1], x xxxxxxx xx xxxxxx 11 xxxxxxx xxxxxxxx,
xxxxxxxx k xxxx, xx xxxxxx 11 uvedené směrnice xxxxxxx, xx xxxxxxx xxxxxxxxx cukrů xx xxxxxxx analytickými xxxxxxxx Xxxxxxxxxxxx;
xxxxxxxx x tomu, xx xx vhodné xxxxxxxx xxxxxxxxx xxxx xxxxx, jejichž xxxxxxx xxx xxxx xxxxxxxx;
xxxxxxxx x tomu, že x xxxxxxx xxxxxxxx 73/437/XXX xx stanovena xxxxxx xxx stanovení xxxxx x cukru xxxx bílého cukru x xxxxx extra xxxxxx, xxxxxx xxxxxxxxx xxxxxx xxxxxxxxxxxxxxxx x xxxxx xxxxx bílého, xxxxxxxx xxxxx, xxxxxxxx xxxxxxxxxx cukru x xxxxxx x xxxxxxxxxx xxxxx a metoda xxxxxxxxx xxxxx x xxxxxxx xxxxx extra xxxxxx a xxxxxxxx xxxxx;
xxxxxxxx k tomu, xx by xx xxxxx xxxxxx xxxx xxxxxx až do xxxxxxxxxxx xxxxxxx xxxxx Xxxxxxxxxxxx xxx xxxxxxxxx xxxxxxxxxxxx cukrů xxxxxxxx xxxxxxxx xxxxxx xxxxxxx xxxxxxxx i xxxxxx xxxxxx xxxxx Xxxxx x Xxxxxx (metody 7 a 8 x příloze XX x. XXX.3 x XXX.4) místo xxxxxx xxxxx Xxxxx a Xxxxxxxx (xxxxxx 6 x příloze XX x. XXX.3 x XXX.4);
xxxxxxxx x tomu, xx xxxxxxxxxx metody xxxxxxxx v xxxx xxxxxxxx xxxx x xxxxxxx se stanoviskem Xxxxxxx xxxxxx xxx xxxxxxxxx,
XXXXXXX XXXX SMĚRNICI:
Xxxxxx 1
1. Členské xxxxx stanoví, xx xxxxxxx xxxxxxxx x xxxxxxx xxxxxxxx xxxxxxxxx x příloze X xxxx xxx xxxxxxxxx xxxxx xxxxx xxxxxxxxx x xxxxxxx II xxxx xxxxxxxx.
2. Xxxx xx xxxxxx xxxxx xxxxxxxxxxx, xxxxxxx xx xxxxxx podle Xxxxx x Schoorla (příloha XX, xxxxxx 6) xx xxxxxxxxx xxxxxxxxxxxx xxxxx obsažených
- v xxxxxxx xxxxx,
- x xxxxxxx bílém cukru,
- x tekutém xxxxxxxxx xxxxx,
- x xxxxxxx xxxxx invertním xxxxx,
- x xxxxxx x xxxxxxxxxx xxxxx,
- xx xxxxxxxxx xxxxxx,
- x xxxxxxx xxxxxxxxx xxxxxx,
- x dextrose monohydrátu,
- x xxxxxxxx xxxxxxx.
Xxxxxxx xxxxx xxxx xxxxx xx svém území xxxxxxxx ke xxxxxxxxx xxxxxxxxxxxx cukrů x xxxxxx xxxx xxxx xxxxxxx xxxxx xxxxxxxxx x předchozím seznamu xxxxxx xxxxx Xxxxx x Xxxxxx (xxxxxxx XX, metoda 7 xxxx 8).
3. Pokud xxxxxxx xxxx využije xxxxxxx volby xxxxxxxx x xxxx. 2 xxxxxx pododstavci, neprodleně x xxx uvědomí Xxxxxx a ostatní xxxxxxx státy.
Xxxxxx 2
Členské státy xxxxxx x účinnost xxxxxx x xxxxxxx xxxxxxxx xxxxxxxx pro xxxxxxxx souladu x xxxxx xxxxxxxx do 18 xxxxxx xx xxxxxxxx xxxx xxxxxxxx. Xxxxxxxxxx x xxxx xxxxxxx Xxxxxx.
Xxxxxx 3
Xxxx xxxxxxxx xx xxxxxx členským xxxxxx.
X Xxxxxxx xxx 26. xxxxxxxx 1979.
Xx Xxxxxx
Xxxxxxx Xxxxxxxx
xxxx Xxxxxx
[1] Úř. xxxx. X 356, 27.12.1973, x. 71.
XXXXXXX X
XXXXXX XXXXXXX XXXXXXXXXXXX XXXXX SPOLEČENSTVÍ XXX XXXXXXX XXXXX XXXXXX K LIDSKÉ XXXXXXXX
PŘÍLOHA XX
XXXXXXXXXX XXXXXX X XXXXXXX SLOŽENÍ XXXXXXXXX XXXXX XXXXXXXX X XXXXXX SPOTŘEBĚ
ÚVOD
1. Xxxxxxxx xxxxxx x xxxxxxx
Xxxxxx xxxxxxxx do xxxxxxxxxx se xxxxxxxx xxxxxxxx.
Xxx xxxxxxx xx xx xxxxxx xxxxxx xxxxxxxx xxxxxxx 200 x x okamžitě xxxxxxx do čisté, xxxxx, xxxxxxxxx xxxxxxx xxxxxxxx xxxxxxxxxxxxx uzávěrem.
2. Xxxxxxx činidla, xxxxxxxxx x xxxxxxx
Xxx popisu xxxxxxxxx a xxxxxxx xxxx uváděny odkazy xxxxx x xxxxxxx xxxxxxxxxxx xxxxxxxx a xxxxxxxxx, nebo těch xxxxxxxxx, xxxxx xxxx xxxxxxxxx xxxxxxxxx požadavkům.
Pokud xx xxxxxxxxx voda, xxxxxx xx destilovaná xxxx nebo demineralizovaná xxxx x alespoň xxxxxxxxxxxx xxxxxxxx.
Xxxxxxx činidla xxxx být xxxxxxxxxx xxxxxxx, xxxxx xxxx xxxxxxxxx jinak.
Pokud xx xxxxxxxxxx xx xxxxxx xxxxxxx bez xxxxxxx xxxxxxxxx, xxxxx se x xxxxx xxxxxx.
3. Xxxxxxxxx výsledků
V úředním xxxxxxxxx x xxxxxxx xx uvede xxxxxxxx xxxxxxx xxxx xxxxxxxx xxxxxxx xx xxxx xxxxxxxxx s uspokojivou xxxxxxxxxxxxxxx.
Xxxxx xxxx xxxxxxx xxxxx, jsou výsledky xxxxxxxxx x xxxxxxxxxx xxxxxxxxxxxx xxxxxxxxx xxxxxxxxxxxxx xxxxxx tak, xxx xxx do xxxxxxxxxx xxxxxxx.
Xxxxx xxxxxxxx číslic x xxxxx vyjádřeném xxxxxxxx je xxxxx xxxxxxxxx xxxxxx.
XXXXXX 1
XXXXXXXXX XXXXXX XXXXXXXXX XXXXXXX
1. Xxxxxxx a xxxxxx xxxxxxx
Xxxxxx xxxxxx ke xxxxxxxxx xxxxxx xxxxxxxxx xxxxxxx
- x xxxxx xxxxxxxxx,
- x cukru xxxx x xxxxx xxxxx,
- v xxxxx xxxxx bílém.
2. Xxxxxxxx
"Xxxxxx xxxxxxxxx xxxxxxx": hodnota xxxxxx xxxxxxxxx sušením xxxxxxxxx xxxxxxxx metodou.
3. Xxxxxxxx metody
Ztráta xxxxxxxxx xxxxxxx xx xxxxxxx xxxxxxx při teplotě 103 ± 2 °X.
4. Xxxxxxxxx x xxxxxxx
4.1 Xxxxxxxxxx xxxx xxxxxx x xxxxxxxxx 0,1 xx.
4.2 Xxxxxxx x xxxxxxx xxxxxxxxx, xxxxxx termostatem, umožňující xxxxxxxx xxxxxxx 103 ± 2 °X.
4.3 Xxxxxx xxxxxxx s xxxxxxx xxxx, xxxxxx xxxx xxxxxxxx xxxxxx x xxxxxxxxxx podmínkám, x xxxxxxxx xxxxxxx 100 xx x x hloubkou xxxxxxx 30 xx.
4.4 Xxxxxxxxx x xxxxxxx xxxxxxxxxxx xxxxxxxxxxx xxxx s xxxxxxxxxxx sušidlem x xxxxxxxxxxx obsahu xxxxxxxx.
5. Xxxxxx
Xxxxxxxx:
Xxxxxxx xxxxxxx v xxxxxx 5.3 až 5.7 xxxx xxx xxxxxxxxx okamžitě po xxxxxxxx nádoby xx xxxxxxx.
5.1 Xxxxx (4.3) xx vysuší xx xxxxxxxxxx hmotnosti x xxxxxxx (4.2) xxx xxxxxxx 103 ± 2 °C.
5.2 Xxxxx xx nechá x xxxxxxxxxx (4.4) xxxxxxxxxxx xxxxxxx xx xxxx 30 až 35 xxxxx x poté xx xxxxx x xxxxxxxxx na 0,1 xx.
5.3 Xx xxxxx xx xxxxxx xxxxxxxxx 20 xx 30 x vzorku s xxxxxxxxx na 0,1 xx.
5.4 Xxxxx xx xxxxx xx xxxxxxx (4.2) x xxxxxxx 103 ± 2 °X, xxx se xxxxxxx 3 xxxxxx.
5.5 Xxxxx xx xxxxx xxxxxxxxxxx v xxxxxxxxxx (4.4) x xxxxx xx x xxxxxxxxx xx 0,1 xx.
5.6 Xxxxx xx znovu xxxxx na 30 xxxxx xx sušárny x teplotě 103 ± 2 °X.
Xxxxx xx xxxxxxxxxxx x xxxxxxxxxx (4.4) x xxxxx xx s xxxxxxxxx na 0,1 xx. Pokud xx xxxxxx xxxx dvěma xxxxxxxx xxxxx než 1 xx, postup xx opakuje. Xxxxx-xx xx xxxxxxx xxxxxxxxx, xxxxxxx xx k xxxxxxx xxxxxxxx zaznamenaná xxxxxxx.
5.7 Xxxxxxx xxx xxxxxx nesmí xxx xxxxx xxx čtyři xxxxxx.
6. Xxxxxxxxx xxxxxxxx
6.1 Xxxxxx x xxxxxx xxxxxxx
Xxxxxx hmotnosti sušením x xxxxxxxxxx xxxxxxxxxxxx xxxxxx xx xxxx xxxxx vzorcem:
kde:
m0 xx xxxxxxxxx hmotnost xxxxxxxxxx xxxxxx (x),
x1 je xxxxxxxx zkušebního xxxxxx xx xxxxxxxx (x).
6.2 Xxxxxxxxxxxxxx
Xxxxxx mezi xxxxxxxx xxxx xxxxxxxxx xxxxxxxxxxx xxxxxxx xxxx rychle xx xxxxx z xxxxx xxxxxx xxxxxx xxxxxxxxxxx xx xxxxxxxxx xxxxxxxx xxxxx být xxxxx než 0,02 x na 100 x xxxxxx.
XXXXXX 2
STANOVENÍ XXXXXX
Xxxxxx xxxxxx xx xxxxxxx xxxxxxx
1. Xxxxxxx x xxxxxx xxxxxxx
Xxxxxx xxxxxx xx stanovení xxxxxx xxxxxx
- ve xxxxxxxxx xxxxxx,
- x xxxxxxx xxxxxxxxx xxxxxx,
- x dextrose xxxxxxxxxxx,
- x dextrose bezvodé.
2. Xxxxxxxx
"Xxxxx xxxxxx": xxxxx xxxxxx xxxxxxxxx popsanou xxxxxxx.
3. Xxxxxxxx xxxxxx
Xxxxxx xx xxxxxxx xxx xxxxxxx 70 ± 1 °X xx xxxxxxx xxxxxxx při xxxxx nejvýše 3,3 xXx (34 mbar). Xxxxxxxx xxxxxx xxxxxxxxxx xxxxxx xxxx xxxxxxxx xxxxxxxxxx xxxxxx xx xxxx sušením xxxxxx xxxxxxxxx x xxxxx x s xxxxxxxxxx.
4. Xxxxxxx činidla
4.1 Xxxxxxxxx: xxxxxxxx xx x Xüxxxxxxxx xxxxxxx xxxxxxxxxx xxxxxxxxxx zředěnou xxxxxxxxx xxxxxxxxxxxxxxx (1 xx xxxxxxxxxxxxx xxxxxxxx o xxxxxxx 1,19 x/xx xx litr xxxx xxx 20 °X), xxxxx filtrát nevykazuje xxxxxxxx xxxxxxx reakci. Xxxxxxxxx na filtru xx pak xxxxxxx xxxxx tak dlouho, xxxxx xxxxxxx xX xxxxxxxx nevystoupí nad 4; pak xx xxxxxxxxx xxxxxx v xxxxxxx při 103 ± 2 °X x xxxxx se xx xxxxxxxxxxxxxx xxxxxx.
5. Xxxxxxxxx x xxxxxxx
5.1 Xxxxxxx xxxxxxx, xxxxxxxx, xxxxxx xxxxxxxxxxx, xxxxxxxx xxxxxxxxxx x xxxxxxxx xxxxxxxxxx. Xxxx xxx xxxxxxxxxxxx tak, xxx xxx xxxxxxxx xxxxxx xxxxxxx tepla xx xxxxxxx xxxxxxxxx xx xxxxxxxx.
5.2 Xxxxxxxxx x xxxxxxxxx xxxxxxx skládající xx ze skleněné xxxxxx naplněné xxxxxxx xxxxxxxxxxx silikagelem nebo xxxxxxxxxxx xxxxxxxxxxx, s xxxxxxxxxxx xxxxxx xxxxxxxx. Xxxx xxxxxx xxxxxxxxxx xxxxxxxxxxxxxx xxxxxxxx sírovou xx sériově xxxxxxxxx x pračkou plynů xxxxxxxxxx xx vstup xxxxxxx xx sušárny.
5.3 Xxxxxx xxxxxxxxxx xxxxxxxx x sušárně xxxx 3,3 kPa (34 xxxx) xxxx xxxxx.
5.4 Xxxxxx xxxxxxx s xxxxxxx xxxx xxxxxx xxxx xxxxxxxx vzorků x xxxxxxxxx zkoušky x průměrem xxxxxxx 100 mm x x xxxxxxxx xxxxxxx 300 xx.
5.5 Xxxxxxxx xxxxxxx x xxxxxx xxxxx, aby xxxxxxx xxxxx zapadnout do xxxxxxx.
5.6 Xxxxxxxxx x xxxxxxx xxxxxxxxxxx xxxxxxxxxxx xxxx x rovnocenným xxxxxxxxxxx x xxxxxxxxxxx xxxxxx vlhkosti.
5.7 Xxxxxxxxxx xxxx xxxxxx x xxxxxxxxx na 0,1 xx.
6. Xxxxxx
6.1 Do xxxxxxx (5.4) xx xxxxxxxxx tyčinkou (5.5) xx převede xxxxxxxxx 30 x xxxxxxxxx (4.1), xxx xxxxx xx do sušárny (5.1) x teplotou 70 ± 1 °X x tlak xx xxxxx xxxxxxx xx 3,3 xXx (34 xxxx).
Xxxx xx xxx xxxx nejméně 5 hodin, xxxxxxx xx xxxx aparaturu xxx vysoušení xxxxxxx xx xxxxxxx xxxxxx xxxxxx proud xxxxxxx. Xxxxx xx zkontroluje xxxx a xxxxx xxxxxxx xx xxxxxx.
6.2 Xxxxxxxxxx xxxxxxxx xxxxxxxxxxxxxx xxxxx x xxxxxxx xx dosáhne xxxxxxxx xxxxxxxx xxxxxxx xxxxxxx xxxxxxx. Miska x xx xxxxxxxxx tyčinkou xx okamžitě přemístí xx exsikátoru (5.6), xxx se xxxxx xxxxxxxxxxx, a pak xx xxxxx.
6.3 Do xxxxxxx x obsahu 100 ml se x xxxxxxxxx xx 1 xx xxxxxx xxxxxxxxx 10 x xxxxxxxxxxxxx xxxxxx.
6.4 Xxxxxxxx xxxxxx xx zředí 10 ml xxxxx xxxx x xxxxxx xx xxxxxx skleněné xxxxxxx (5.5) xxxxxxxxxxxxx xxxxxxx xx xxxxxxx.
6.5 Xxxxx xx xxxxxxxxx xxxxxxx x skleněnou xxxxxxxx xx xxxxx xx xxxxxxx x xxxx xx sníží xxxxxxx xx 3,3 xXx (34 mbar). Xxxx xx při 70 ± 1 °X, přičemž xx xxxxxxxx nechá xxxxxxxxx xxxxxx xxxxx xxxxxxx xxxxxxx.
Xxxxxx xx xxxxxxx xx xxxx 20 xxxxx; x největšímu xxxxxx xxxxxxxx xx xxxxx ke konci xxxxxxx dne. Je xxxxxxxx xxxxxxxx xxxxxx x xxxxx xxx xxxxxxxxxx xxxxx a xxxxxx pomalu proudit xx xxxxxxx xxxxx xxxxxx xxx, aby xx xxxxx xxxx xxxx udržoval xxxxxxxxx xx hodnotě 3,3 xXx (34 xxxx) xxxx xxxxx.
6.6 Atmosférického xxxxx x xxxxxxx xx xxxx dosáhne xxxxxxxx zvýšením přívodu xxxxxxx xxxxxxx. Xxxxxxx x x xxxxxxx xx xxxxxxxx xxxxxxxx xx xxxxxxxxxx, xxx xx xxxxx xxxxxxxxxxx, x xxxx xx xxxxx x xxxxxxxxx xx 1 xx.
6.7 Xxxxxxx (6.5) se xxxxxxx xx další 4 hodiny. X xxxxxxx xx obnoví xxxxxxxxxxxx xxxx x xxxxx xx ihned xxxxx xx xxxxxxxxxx. Xxxxx se vychladnout x xxxxxxx xx xxxxxx, zda již xxxx dosaženo konstantní xxxxxxxxx. Xx xxxxxxxxxx xxxxxxxx se považuje xxxxxx výsledek, xxx xxxxxx xxxx dvěma xxxxxxxx xxxx xxxxx xxxx větší xxx 2 xx. X xxxxxxx xxxxxxx xx xxxxxxx xxxxxxx 6.7.
6.8 Xxx xxxxxxxxx xxxxxx xx vzorcích xxxxxxx xxxxxxxx xxxx x xxxxxxxxxxx xxxxxxxx xxxx xxxxxxx xxxxxxxxx x xxxx zapotřebí.
7. Vyjádření xxxxxxxx
7.1 Vzorec a xxxxxx výpočtu
Obsah xxxxxx xxxxxxxxx v xxxxxxxxxx xxxxxxxxxxxx vzorku xx xxxxxxxx xxxxx xxxxxx xxxxxx:
xxx:
x0 = xx xxxxxxxxx xxxxxxxx zkušebního xxxxxx (x),
x1 = xx xxxxxxxx váženky x křemelinou, xxxxxxxxx xxxxxxxx x xxxxxxx xxxxxxxxxx vzorku po xxxxxx (x),
x2 = xx xxxxxxxx xxxxxxx x xxxxxxxxxx a xxxxxxxxx xxxxxxxx (g).
7.2 Xxxxxxxxxxxxxx
Xxxxxx xxxx xxxxxxxx xxxx xxxxxxxxx xxxxxxxxxxx xxxxxxx xxxx xxxxxx xx xxxxx x xxxxx xxxxxx tímtéž xxxxxxxxxxx za xxxxxxxxx xxxxxxxx xxxxx xxx xxxxx než 0,12 x xx 100 x xxxxxx.
XXXXXX 3
XXXXXXXXX XXXXXXX XXXXXX
(Xxxxxxxxxxxxxxxx metoda)
1. Xxxxxxx a oblast xxxxxxx
Xxxxxx xxxxxxx xxxxx xxxxxx
- x tekutém xxxxx,
- x xxxxxxx xxxxx cukru,
- x xxxxxxx xxxxxxxxx cukru,
- x tekutém xxxxx xxxxxxxxx cukru,
- x xxxxxx x invertního xxxxx,
- v xxxxxx x xxxxxx invertního xxxxx.
2. Definice
"Obsah sušiny": xxxxx sušiny xxxxxxxxx xxxxxxxx xxxxxxx.
3. Podstata xxxxxx
Xxxxxxx xx index xxxx xxxxxxxxxx xxxxxx xxx 20 °X x xxxxx xxxxxxx xxxxxxxxxxx xxxxxxxxxxx xxxx xxxxxx xxxxxx xxxx xx xxxxxxx na xxxxx sušiny.
4. Přístroje x pomůcky
4.1 Xxxxxxxxxxxx x xxxxxxxxx odečtu xx xxxxx desetinná xxxxx, xxxxxxxx xxxxxxxxxx x xxxxxxxx vodním xxxxxxxxx xxxxxxxxxx s xxxxx lázní, která xx udržována xxxxxxxxxxx xx xxxxxxx 20 ± 0,5 °X.
4.2 Xxxxxxxx zdroj xxxxxxxxxxx xx xxxxxxxx xxxxxxx.
5. Xxxxxx
5.1 Xxxxx xxxx xx xxxxxx xxxxxxxx xxxxxxxx, xxxxxxxx xx xxxxxxxx xxxxxx v xxxxxx 1:1 (x/x).
5.2 Xxxxxxxxxxxxxx (4.1) xx xxxxx index xxxx xxxxxx při 20 °X.
6. Xxxxxxxxx xxxxxxxx x xxxxxx xxxxxxx
6.1 Xxxxx xxxxxx se xxxxxxx x xxxxxx xxxx xxx roztoky xxxxxxxxx při 20 °X xxxxx xxxxxxx xxxxxxx a xxxx xxxxxxx xx xxxxxxxxxx xxxxxxxxxx cukru x xxxxxxxxxxxx xxxxxx se x xxxxxxxx x xxxxxxx přičte na xxxxx 1 % xxxxxxxxxx xxxxx xxxxxxx 0,022.
6.2 Xxxxx xxx xxxxxx xxxxxx xxxxx x xxxxxx 1:1 (x/x), xxxx se xxxxx xxxxxxxxx sušiny xxxxxxxxx xxxxx.
6.3 Xxxxxxxxxxxxxx
Xxxxxx xxxx xxxxxxxx dvou xxxxxxxxx xxxxxxxxxxx zároveň xxxx rychle xx xxxxx x téhož xxxxxx xxxxxx xxxxxxxxxxx xx xxxxxxxxx podmínek xxxxx xxx xxxxx xxx 0,2 x xxxxxx xx 100 x vzorku.
REFERENČNÍ XXXXXXX
Xxxxxx xxxx (n) xxxxxxx xxxxxxxxx xxx 20 °X [1]
|
x (20 °X) |
Xxxxxxxxx (%) |
|
1,3330 |
0,009 |
|
1,3331 |
0,078 |
|
1,3332 |
0,149 |
|
1,3333 |
0,218 |
|
1,3334 |
0,288 |
|
1,3335 |
0,358 |
|
1,3336 |
0,428 |
|
1,3337 |
0,498 |
|
1,3338 |
0,567 |
|
1,3339 |
0,637 |
|
1,3340 |
0,707 |
|
1,3341 |
0,776 |
|
1,3342 |
0,846 |
|
1,3343 |
0,915 |
|
1,3344 |
0,985 |
|
1,3345 |
1,054 |
|
1,3346 |
1,124 |
|
1,3347 |
1,193 |
|
1,3348 |
1,263 |
|
1,3349 |
1,332 |
|
1,3350 |
1,401 |
|
1,3351 |
1,470 |
|
1,3352 |
1,540 |
|
1,3353 |
1,609 |
|
1,3354 |
1,678 |
|
1,3355 |
1,747 |
|
1,3356 |
1,816 |
|
1,3357 |
1,885 |
|
1,3358 |
1,954 |
|
1,3359 |
2,023 |
|
1,3360 |
2,092 |
|
1,3361 |
2,161 |
|
1,3362 |
2,230 |
|
1,3363 |
2,299 |
|
1,3364 |
2,367 |
|
1,3365 |
2,436 |
|
1,3366 |
2,505 |
|
1,3367 |
2,574 |
|
1,3368 |
2,642 |
|
1,3369 |
2,711 |
|
1,3370 |
2,779 |
|
1,3371 |
2,848 |
|
1,3372 |
2,917 |
|
1,3373 |
2,985 |
|
1,3374 |
3,053 |
|
1,3375 |
3,122 |
|
1,3376 |
3,190 |
|
1,3377 |
3,259 |
|
1,3378 |
3,327 |
|
1,3379 |
3,395 |
|
1,3380 |
3,463 |
|
1,3381 |
3,532 |
|
1,3382 |
3,600 |
|
1,3383 |
3,668 |
|
1,3384 |
3,736 |
|
1,3385 |
3,804 |
|
1,3386 |
3,872 |
|
1,3387 |
3,940 |
|
1,3388 |
4,008 |
|
1,3389 |
4,076 |
|
1,3390 |
4,144 |
|
1,3391 |
4,212 |
|
1,3392 |
4,279 |
|
1,3393 |
4,347 |
|
1,3394 |
4,415 |
|
1,3395 |
4,483 |
|
1,3396 |
4,550 |
|
1,3397 |
4,618 |
|
1,3398 |
4,686 |
|
1,3399 |
4,753 |
|
1,3400 |
4,821 |
|
1,3401 |
4,888 |
|
1,3402 |
4,956 |
|
1,3403 |
5,023 |
|
1,3404 |
5,091 |
|
1,3405 |
5,158 |
|
1,3406 |
5,225 |
|
1,3407 |
5,293 |
|
1,3408 |
5,360 |
|
1,3409 |
5,427 |
|
1,3410 |
5,494 |
|
1,3411 |
5,562 |
|
1,3412 |
5,629 |
|
1,3413 |
5,696 |
|
1,3414 |
5,763 |
|
1,3415 |
5,830 |
|
1,3416 |
5,897 |
|
1,3417 |
5,964 |
|
1,3418 |
6,031 |
|
1,3419 |
6,098 |
|
1,3420 |
6,165 |
|
1,3421 |
6,231 |
|
1,3422 |
6,298 |
|
1,3423 |
6,365 |
|
1,3424 |
6,432 |
|
1,3425 |
6,498 |
|
1,3426 |
6,565 |
|
1,3427 |
6,632 |
|
1,3428 |
6,698 |
|
1,3429 |
6,765 |
|
1,3430 |
6,831 |
|
1,3431 |
6,898 |
|
1,3432 |
6,964 |
|
1,3433 |
7,031 |
|
1,3434 |
7,097 |
|
1,3435 |
7,164 |
|
1,3436 |
7,230 |
|
1,3437 |
7,296 |
|
1,3438 |
7,362 |
|
1,3439 |
7,429 |
|
1,3440 |
7,495 |
|
1,3441 |
7,561 |
|
1,3442 |
7,627 |
|
1,3443 |
7,693 |
|
1,3444 |
7,759 |
|
1,3445 |
7,825 |
|
1,3446 |
7,891 |
|
1,3447 |
7,957 |
|
1,3448 |
8,023 |
|
1,3449 |
8,089 |
|
1,3450 |
8,155 |
|
1,3451 |
8,221 |
|
1,3452 |
8,287 |
|
1,3453 |
8,352 |
|
1,3454 |
8,418 |
|
1,3455 |
8,484 |
|
1,3456 |
8,550 |
|
1,3457 |
8,615 |
|
1&xxxx;3458 |
8,681 |
|
1,3459 |
8,746 |
|
1,3460 |
8,812 |
|
1,3461 |
8,878 |
|
1,3462 |
8,943 |
|
1,3463 |
9,008 |
|
1,3464 |
9,074 |
|
1,3465 |
9,139 |
|
1,3466 |
9,205 |
|
1,3467 |
9,270 |
|
1,3468 |
9,335 |
|
1,3469 |
9,400 |
|
1,3470 |
9,466 |
|
1,3471 |
9,531 |
|
1,3472 |
9,596 |
|
1,3473 |
9,661 |
|
1,3474 |
9,726 |
|
1,3475 |
9,791 |
|
1,3476 |
9,856 |
|
1,3477 |
9,921 |
|
1,3478 |
9,986 |
|
1,3479 |
10,051 |
|
1,3480 |
10,116 |
|
1,3481 |
10,181 |
|
1,3482 |
10,246 |
|
1,3483 |
10,311 |
|
1,3484 |
10,375 |
|
1,3485 |
10,440 |
|
1,3486 |
10,505 |
|
1,3487 |
10,570 |
|
1,3488 |
10,634 |
|
1,3489 |
10,699 |
|
1,3490 |
10,763 |
|
1,3491 |
10,828 |
|
1,3492 |
10,892 |
|
1,3493 |
10,957 |
|
1,3494 |
11,021 |
|
1,3495 |
11,086 |
|
1,3496 |
11,150 |
|
1,3497 |
11,215 |
|
1,3498 |
11,279 |
|
1,3499 |
11,343 |
|
1,3500 |
11,407 |
|
1,3501 |
11,472 |
|
1,3502 |
11,536 |
|
1,3503 |
11,600 |
|
1,3504 |
11,664 |
|
1,3505 |
11,728 |
|
1,3506 |
11,792 |
|
1,3507 |
11,856 |
|
1,3508 |
11,920 |
|
1,3509 |
11,984 |
|
1,3510 |
12,048 |
|
1,3511 |
12,112 |
|
1,3512 |
12,176 |
|
1,3513 |
12,240 |
|
1,3514 |
12,304 |
|
1,3515 |
12,368 |
|
1,3516 |
12,431 |
|
1,3517 |
12,495 |
|
1,3518 |
12,559 |
|
1,3519 |
12,623 |
|
1,3520 |
12,686 |
|
1,3521 |
12,750 |
|
1,3522 |
12,813 |
|
1,3523 |
12,877 |
|
1,3524 |
12,940 |
|
1,3525 |
13,004 |
|
1,3526 |
13,067 |
|
1,3527 |
13,131 |
|
1,3528 |
13,194 |
|
1,3529 |
13,258 |
|
1,3530 |
13,321 |
|
1,3531 |
13,384 |
|
1,3532 |
13,448 |
|
1,3533 |
13,511 |
|
1,3534 |
13,574 |
|
1,3535 |
13,637 |
|
1,3536 |
13,700 |
|
1,3537 |
13,763 |
|
1,3538 |
13,826 |
|
1,3539 |
13,890 |
|
1,3540 |
13,953 |
|
1,3541 |
14,016 |
|
1,3542 |
14,079 |
|
1,3543 |
14,141 |
|
1,3544 |
14,204 |
|
1,3545 |
14,267 |
|
1,3546 |
14,330 |
|
1,3547 |
14,393 |
|
1,3548 |
14,456 |
|
1,3549 |
14,518 |
|
1,3550 |
14,581 |
|
1,3551 |
14,644 |
|
1,3552 |
14,707 |
|
1,3553 |
14,769 |
|
1,3554 |
14,832 |
|
1,3555 |
14,894 |
|
1,3556 |
14,957 |
|
1,3557 |
15,019 |
|
1,3558 |
15,082 |
|
1,3559 |
15,144 |
|
1,3560 |
15,207 |
|
1,3561 |
15,269 |
|
1,3562 |
15,332 |
|
1,3563 |
15,394 |
|
1,3564 |
15,456 |
|
1,3565 |
15,518 |
|
1,3566 |
15,581 |
|
1,3567 |
15,643 |
|
1,3568 |
15,705 |
|
1,3569 |
15,767 |
|
1,3570 |
15,829 |
|
1,3571 |
15,891 |
|
1,3572 |
15,953 |
|
1,3573 |
16,016 |
|
1,3574 |
16,078 |
|
1,3575 |
16,140 |
|
1,3576 |
16,201 |
|
1,3577 |
16,263 |
|
1,3578 |
16,325 |
|
1,3579 |
16,387 |
|
1,3580 |
16,449 |
|
1,3581 |
16,511 |
|
1,3582 |
16,573 |
|
1,3583 |
16,634 |
|
1,3584 |
16,696 |
|
1,3585 |
16,758 |
|
1,3586 |
16,819 |
|
1,3587 |
16,881 |
|
1,3588 |
16,943 |
|
1,3389 |
17,004 |
|
1,3590 |
17,066 |
|
1,3591 |
17,127 |
|
1,3592 |
17,189 |
|
1,3593 |
17,250 |
|
1,3594 |
17,311 |
|
1,3595 |
17,373 |
|
1,3596 |
17,434 |
|
1,3597 |
17,496 |
|
1,3598 |
17,557 |
|
1,3599 |
17,618 |
|
1,3600 |
17,679 |
|
1,3601 |
17,741 |
|
1,3602 |
17,802 |
|
1,3603 |
17,863 |
|
1,3604 |
17,924 |
|
1,3605 |
17,985 |
|
1,3606 |
18,046 |
|
1,3607 |
18,107 |
|
1,3608 |
18,168 |
|
1,3609 |
18,229 |
|
1,3610 |
18,290 |
|
1,3610 |
18,351 |
|
1,3611 |
18,412 |
|
1,3613 |
18,473 |
|
1,3614 |
18,534 |
|
1,3615 |
18,595 |
|
1,3616 |
18,655 |
|
1,3617 |
18,716 |
|
1,3618 |
18,777 |
|
1,3619 |
18,837 |
|
1,3620 |
18,898 |
|
1,3621 |
18,959 |
|
1,3622 |
19,019 |
|
1,3623 |
19,080 |
|
1,3624 |
19,141 |
|
1,3625 |
19,201 |
|
1,3626 |
19,262 |
|
1,3627 |
19,322 |
|
1,3628 |
19,382 |
|
1,3629 |
19,443 |
|
1,3630 |
19,503 |
|
1,3631 |
19,564 |
|
1,3632 |
19,624 |
|
1,3633 |
19,684 |
|
1,3634 |
19,745 |
|
1,3635 |
19,805 |
|
1,3636 |
19,865 |
|
1,3637 |
19,925 |
|
1,3638 |
19,985 |
|
1,3639 |
20,045 |
|
1,3640 |
20,106 |
|
1.3641 |
20,166 |
|
1,3642 |
20,226 |
|
1,3643 |
20,286 |
|
1,3644 |
20,346 |
|
1,3645 |
20,406 |
|
1,3646 |
20,466 |
|
1,3647 |
20,525 |
|
1,3648 |
20,585 |
|
1,3649 |
20,645 |
|
1,3650 |
20,705 |
|
1,3651 |
20,765 |
|
1,3652 |
20,825 |
|
1,3653 |
20,884 |
|
1,3654 |
20,944 |
|
1,3655 |
21,004 |
|
1,3656 |
21,063 |
|
1,3657 |
21,123 |
|
1,3658 |
21,183 |
|
1,3659 |
21,242 |
|
1,3660 |
21,302 |
|
1,3661 |
21,361 |
|
1,3662 |
21,421 |
|
1,3563 |
21,480 |
|
1,3664 |
21,540 |
|
1,3665 |
21,599 |
|
1,3666 |
21,658 |
|
1,3667 |
21,718 |
|
1,3668 |
21,777 |
|
1,3669 |
21,836 |
|
1,3670 |
21,896 |
|
1,3671 |
21,955 |
|
1,3672 |
22,014 |
|
1,1673 |
22,073 |
|
1,3674 |
22,132 |
|
1,3675 |
22,192 |
|
1,3676 |
22,251 |
|
1,1677 |
22,310 |
|
1,3678 |
22,369 |
|
1,3679 |
22,428 |
|
1,3680 |
22,487 |
|
1,3681 |
22,546 |
|
1,3682 |
22,605 |
|
1,3683 |
22,664 |
|
1,3684 |
22,723 |
|
1,3685 |
22,781 |
|
1,3686 |
22,840 |
|
1,3687 |
22,899 |
|
1,3688 |
22,958 |
|
1,3689 |
23,017 |
|
1,3690 |
23,075 |
|
1,3691 |
23,134 |
|
1,3692 |
23,193 |
|
1,3693 |
23,251 |
|
1,3694 |
23,310 |
|
1,3695 |
23,369 |
|
1,3696 |
23,427 |
|
1,3697 |
23,486 |
|
1,3698 |
23,544 |
|
1,3699 |
23,603 |
|
1,3700 |
23,661 |
|
1,3701 |
23,720 |
|
1,3702 |
23,778 |
|
1,3703 |
23,836 |
|
1,3704 |
23,895 |
|
1,3705 |
23,953 |
|
1,3706 |
24,011 |
|
1,3707 |
24,070 |
|
1,3708 |
24,128 |
|
1,3709 |
24,186 |
|
1,3710 |
24,244 |
|
1,3711 |
24,302 |
|
1,3712 |
24,361 |
|
1,3713 |
24,419 |
|
1,3714 |
24,477 |
|
1,3715 |
24,535 |
|
1,3716 |
24,593 |
|
1,3717 |
24,651 |
|
1,3718 |
24,709 |
|
1,3719 |
24,767 |
|
1,3720 |
24,825 |
|
1,3721 |
24,883 |
|
1,3722 |
24,941 |
|
1,3723 |
24,998 |
|
1,3724 |
25,056 |
|
1,3725 |
25,114 |
|
1,3726 |
25,172 |
|
1,3727 |
25,230 |
|
1,3728 |
25287 |
|
1,3729 |
25,345 |
|
1,3730 |
25,403 |
|
1,3731 |
25,460 |
|
1,3732 |
25,518 |
|
1,3733 |
25,576 |
|
1,3734 |
25,633 |
|
1,3735 |
25,691 |
|
1,3736 |
25,748 |
|
1,3737 |
25,806 |
|
1,3738 |
25,863 |
|
1,3739 |
25,921 |
|
1,3740 |
25,978 |
|
1,3741 |
26,035 |
|
1,3742 |
26,093 |
|
1,3743 |
26,150 |
|
1,3744 |
26,207 |
|
1,3745 |
26,265 |
|
1,3746 |
26,322 |
|
1,3747 |
26,379 |
|
1,3748 |
26,436 |
|
1,3749 |
26,493 |
|
1,3750 |
26,551 |
|
1,3751 |
26,608 |
|
1,3752 |
26,665 |
|
1,3753 |
26,722 |
|
1,3754 |
26,779 |
|
1,3755 |
26,836 |
|
1,3756 |
26,893 |
|
1,3757 |
26,950 |
|
1,3758 |
27,007 |
|
1,3759 |
27,064 |
|
1,3760 |
27,121 |
|
1,3761 |
27,178 |
|
1,3762 |
27,234 |
|
1,3763 |
27,291 |
|
1,3764 |
27,348 |
|
1,3765 |
27,405 |
|
1,3765 |
27,462 |
|
1,3767 |
27,518 |
|
1,3768 |
27,575 |
|
1,3769 |
27,632 |
|
1,3770 |
27,688 |
|
1,3771 |
27,745 |
|
1,3772 |
27,802 |
|
1,3773 |
27,858 |
|
1,3774 |
27,915 |
|
1,3775 |
27,971 |
|
1,3776 |
28,028 |
|
1,3777 |
28,084 |
|
1,3778 |
28,141 |
|
1,3779 |
28,197 |
|
1,3780 |
28,253 |
|
1,3781 |
28,310 |
|
1,3782 |
28,366 |
|
1,3783 |
28,422 |
|
1,3784 |
28,479 |
|
1,3785 |
28,535 |
|
1,3786 |
28,591 |
|
1,3787 |
28,648 |
|
1,3788 |
28,704 |
|
1,3789 |
28,760 |
|
1,3790 |
28,816 |
|
1,3791 |
28,872 |
|
1,3792 |
28,928 |
|
1,3793 |
28,984 |
|
1,3794 |
29,040 |
|
1,3795 |
29,096 |
|
1,3796 |
29,152 |
|
1,3797 |
29,208 |
|
1,3798 |
29,264 |
|
1,3799 |
29,320 |
|
1,3800 |
29,376 |
|
1,3801 |
29,432 |
|
1,3802 |
29,488 |
|
1,3803 |
29,544 |
|
1,3804 |
29,600 |
|
1,3805 |
29,655 |
|
1,3806 |
29,711 |
|
1,3807 |
29,767 |
|
1,3808 |
29,823 |
|
1,3809 |
29,878 |
|
1,3810 |
29,934 |
|
1,3811 |
29,989 |
|
1,3812 |
30,045 |
|
1,3813 |
30,101 |
|
1,3814 |
30,156 |
|
1,3815 |
30,212 |
|
1,3816 |
30,267 |
|
1,3817 |
30,323 |
|
1,3818 |
30,378 |
|
1,3819 |
30,434 |
|
1,3820 |
30,489 |
|
1,3821 |
30,544 |
|
1,3822 |
30,600 |
|
1,3823 |
30,655 |
|
1,3824 |
30,711 |
|
1,3825 |
30,766 |
|
1,3826 |
30,821 |
|
1,3827 |
30,876 |
|
1,3828 |
30,932 |
|
1,3829 |
30,987 |
|
1,3830 |
31,042 |
|
1,3831 |
31,097 |
|
1,3832 |
31,152 |
|
1,3833 |
31,207 |
|
1,3834 |
31,262 |
|
1,3835 |
31,317 |
|
1,3836 |
31,372 |
|
1,3837 |
31,428 |
|
1,3838 |
31,482 |
|
1,3839 |
31,537 |
|
1,3840 |
31,592 |
|
1,3841 |
31,647 |
|
1,3842 |
31,702 |
|
1,3843 |
31,757 |
|
1,3844 |
31,812 |
|
1,3845 |
31,867 |
|
1,3846 |
31,922 |
|
1,3847 |
31,976 |
|
1,3848 |
32,031 |
|
1,3849 |
32,086 |
|
1,3850 |
32,140 |
|
1,3851 |
32,195 |
|
1,3852 |
32,250 |
|
1,3853 |
32,304 |
|
1,3854 |
32,359 |
|
1,3855 |
32,414 |
|
1,3856 |
32,468 |
|
1,3857 |
32,523 |
|
1,3858 |
32,577 |
|
1,3859 |
32,632 |
|
1,3860 |
32,686 |
|
1,3861 |
32,741 |
|
1,3862 |
32,795 |
|
1,3863 |
32,849 |
|
1,3864 |
32,904 |
|
1,3865 |
32,958 |
|
1,3866 |
33,013 |
|
1,3867 |
33,067 |
|
1,3868 |
33,121 |
|
1,3889 |
33,175 |
|
1,3870 |
33,230 |
|
1,3871 |
33,284 |
|
1,3872 |
33,338 |
|
1,3873 |
33,392 |
|
1,3874 |
33,446 |
|
1,3875 |
33,500 |
|
1,3876 |
33,555 |
|
1,3877 |
33,609 |
|
1,3878 |
33,663 |
|
1,3879 |
33,717 |
|
1,3880 |
33,771 |
|
1,3881 |
33,825 |
|
1,3882 |
33,879 |
|
1,3883 |
33,933 |
|
1,3884 |
33,987 |
|
1,3885 |
34,040 |
|
1,3886 |
34,094 |
|
1,3887 |
34,148 |
|
1,3888 |
34,202 |
|
1,3889 |
34,256 |
|
1,3890 |
34,310 |
|
1,3891 |
34,363 |
|
1,3892 |
34,417 |
|
1,3893 |
34,471 |
|
1,3894 |
34,524 |
|
1,3895 |
34,578 |
|
1,3896 |
34,632 |
|
1,3897 |
34,685 |
|
1,3898 |
34,739 |
|
1,3899 |
34,793 |
|
1,3900 |
34,846 |
|
1,3901 |
34,900 |
|
1,3902 |
34,953 |
|
1,3903 |
35,007 |
|
1,3904 |
35,060 |
|
1,3905 |
35,114 |
|
1,3906 |
35,167 |
|
1,3907 |
35,220 |
|
1,3908 |
35,274 |
|
1,3909 |
35,327 |
|
1,3910 |
35,380 |
|
1,3911 |
35,434 |
|
1,3912 |
35,487 |
|
1,3913 |
35,540 |
|
1,3914 |
35,593 |
|
1,3915 |
35,647 |
|
1,3916 |
35,700 |
|
1,3917 |
35,753 |
|
1,3918 |
35,806 |
|
1,3919 |
35,859 |
|
1,3920 |
35,912 |
|
1,3921 |
35,966 |
|
1,3922 |
36,019 |
|
1,3923 |
36,072 |
|
1,3924 |
36,125 |
|
1,3925 |
36,178 |
|
1,3926 |
36,231 |
|
1,3927 |
36,284 |
|
1,3928 |
36,337 |
|
1,3929 |
36,389 |
|
1,3930 |
36,442 |
|
1,3931 |
36,495 |
|
1,3932 |
36,548 |
|
1,3933 |
36,601 |
|
1,3934 |
36,654 |
|
1,3935 |
36,706 |
|
1,3936 |
36,759 |
|
1,3937 |
36,812 |
|
1,3938 |
36,865 |
|
1,3939 |
36,917 |
|
1,3940 |
36,970 |
|
1,3941 |
37,023 |
|
1,3942 |
37,075 |
|
1,3943 |
37,128 |
|
1,3944 |
37,180 |
|
1,3945 |
37,233 |
|
1,3946 |
37,286 |
|
1,3947 |
37,338 |
|
1,3948 |
37,391 |
|
1,3949 |
37,443 |
|
1,3950 |
37,495 |
|
1,3951 |
37,548 |
|
1,3952 |
37,600 |
|
1,3953 |
37,653 |
|
1,3954 |
37,705 |
|
1,3955 |
37,757 |
|
1,3956 |
37,810 |
|
1,3957 |
37,862 |
|
1,3958 |
37,914 |
|
1,3959 |
37,967 |
|
1,3960 |
38,019 |
|
1,3961 |
38,071 |
|
1,3962 |
38,123 |
|
1,3963 |
38,175 |
|
1,3964 |
38,228 |
|
1,3965 |
38,280 |
|
1,3966 |
38,332 |
|
1,3967 |
38,384 |
|
1,3968 |
38,436 |
|
1,3969 |
38,488 |
|
1,3970 |
38,540 |
|
1,3971 |
38,592 |
|
1,3972 |
38,644 |
|
1,3973 |
38,696 |
|
1,3974 |
38,748 |
|
1,3975 |
38,800 |
|
1,3976 |
38,852 |
|
1,3977 |
38,904 |
|
1,3978 |
38,955 |
|
1,3979 |
39,007 |
|
1,3980 |
39,059 |
|
1,3981 |
39,111 |
|
1,3982 |
39,163 |
|
1,3983 |
39,214 |
|
1,3984 |
39,266 |
|
1,3985 |
39,318 |
|
1,3986 |
39,370 |
|
1,3987 |
39,421 |
|
1,3988 |
39,473 |
|
1,3989 |
39,525 |
|
1,3990 |
39,576 |
|
1,3991 |
39,628 |
|
1,3992 |
39,679 |
|
1,3993 |
39,731 |
|
1,3994 |
39,782 |
|
1,3995 |
39,834 |
|
1,3996 |
39,885 |
|
1,3997 |
39,937 |
|
1,3998 |
39,988 |
|
1,3999 |
40,040 |
|
1,4000 |
40,091 |
|
1,4001 |
40,142 |
|
1,4002 |
40,194 |
|
1,4003 |
40,245 |
|
1,4004 |
40,296 |
|
1,4005 |
40,348 |
|
1,4006 |
40,399 |
|
1,4007 |
40,450 |
|
1,4008 |
40,501 |
|
1,4009 |
40,553 |
|
1,4010 |
40,604 |
|
1,4011 |
40,655 |
|
1,4012 |
40,706 |
|
1,4013 |
40,757 |
|
1,4014 |
40,808 |
|
1,4015 |
40,860 |
|
1,4016 |
40,911 |
|
1,4017 |
40,962 |
|
1,4018 |
41,013 |
|
1,4019 |
41,064 |
|
1,4020 |
41,115 |
|
1,4021 |
41,166 |
|
1,4022 |
41,217 |
|
1,4023 |
41,268 |
|
1,4024 |
41,318 |
|
1,4025 |
41,369 |
|
1,4026 |
41,420 |
|
1,4027 |
41,471 |
|
1,4028 |
41,522 |
|
1,4029 |
41,573 |
|
1,4030 |
41,623 |
|
1,4031 |
41,674 |
|
1,4032 |
41,725 |
|
1,4033 |
41,776 |
|
1,4034 |
41,826 |
|
1,4035 |
41,877 |
|
1,4036 |
41,928 |
|
1,4037 |
41,978 |
|
1,4038 |
42,029 |
|
1,4039 |
42,080 |
|
1,4040 |
42,130 |
|
1,4041 |
42,181 |
|
1,4042 |
42,231 |
|
1,4043 |
42,282 |
|
1,4044 |
42,332 |
|
1,4045 |
42,383 |
|
1,4046 |
42,433 |
|
1,4047 |
42,484 |
|
1,4048 |
42,534 |
|
1,4049 |
42,585 |
|
1,4050 |
42,635 |
|
1,4051 |
42,685 |
|
1,4052 |
42,736 |
|
1,4053 |
42,786 |
|
1,4054 |
42,836 |
|
1,4055 |
42,887 |
|
1,4056 |
42,937 |
|
1,4057 |
42,987 |
|
1,4058 |
43,037 |
|
1,4059 |
43,088 |
|
1,4060 |
43,138 |
|
1,4061 |
43,188 |
|
1,4062 |
43,238 |
|
1,4063 |
43,288 |
|
1,4064 |
43,338 |
|
1,4065 |
43,388 |
|
1,4066 |
43,439 |
|
1,4067 |
43,489 |
|
1,4068 |
43,539 |
|
1,4069 |
43,589 |
|
1,4070 |
43,639 |
|
1,4071 |
43,689 |
|
1,4072 |
43739 |
|
1,4073 |
43,789 |
|
1,4074 |
43,838 |
|
1,4075 |
43,888 |
|
1,4076 |
43,938 |
|
1,4077 |
43,988 |
|
1,4078 |
44,038 |
|
1,4079 |
44,088 |
|
1,4080 |
44,138 |
|
1,4081 |
44,187 |
|
1,4082 |
44,237 |
|
1,4083 |
44,287 |
|
1,4084 |
44,337 |
|
1,4085 |
44,386 |
|
1,4086 |
44,436 |
|
1,4087 |
44,486 |
|
1,4088 |
44,535 |
|
1,4089 |
44,585 |
|
1,4090 |
44,635 |
|
1,4091 |
44,684 |
|
1,4092 |
44,734 |
|
1,4093 |
44,783 |
|
1,4094 |
44,833 |
|
1,4095 |
44,882 |
|
1,4096 |
44,932 |
|
1,4097 |
44,981 |
|
1,4098 |
45,031 |
|
1,4099 |
45,080 |
|
1,4100 |
45,130 |
|
1,4101 |
43,179 |
|
1,4102 |
45,228 |
|
1,4103 |
45,278 |
|
1,4104 |
45,327 |
|
1,4105 |
45,376 |
|
1,4106 |
45,426 |
|
1,4107 |
45,475 |
|
1,4108 |
45,524 |
|
1,4109 |
45,574 |
|
1,4110 |
45,623 |
|
1,4111 |
45,672 |
|
1,4112 |
45,721 |
|
1,4113 |
45,770 |
|
1,4114 |
45,820 |
|
1,4115 |
45,869 |
|
1,4116 |
45,918 |
|
1,4117 |
46,967 |
|
1,4118 |
46,016 |
|
1,4119 |
46,065 |
|
1,4120 |
46,114 |
|
1,4121 |
46,163 |
|
1,4122 |
46,212 |
|
1,4123 |
46,261 |
|
1,4124 |
46,310 |
|
1,4125 |
46,359 |
|
1,4126 |
46,408 |
|
1,4127 |
46,457 |
|
1,4128 |
46,506 |
|
1,4129 |
46,555 |
|
1,4130 |
46,604 |
|
1,4131 |
46,652 |
|
1,4132 |
46,701 |
|
1,4133 |
46,750 |
|
1,4134 |
46,799 |
|
1,4135 |
46,848 |
|
1,4136 |
46,896 |
|
1,4137 |
46,945 |
|
1,4138 |
46,994 |
|
1,4139 |
47,043 |
|
1,4140 |
47,091 |
|
1,4141 |
47,140 |
|
1,4141 |
47,188 |
|
1,4143 |
47,237 |
|
1,4144 |
47,286 |
|
1,4145 |
47,334 |
|
1,4146 |
47,383 |
|
1,4147 |
47,431 |
|
1,4148 |
47,480 |
|
1,4149 |
47,528 |
|
1,4150 |
47,577 |
|
1,4151 |
47,625 |
|
1,4152 |
47,674 |
|
1,4153 |
47,722 |
|
1,4154 |
47,771 |
|
1,4155 |
47,819 |
|
1,4156 |
47,868 |
|
1,4157 |
47,916 |
|
1,4158 |
47,964 |
|
1,4159 |
48,013 |
|
1,4160 |
48,061 |
|
1,4161 |
48,109 |
|
1,4162 |
48,158 |
|
1,4163 |
48,206 |
|
1,4164 |
48,254 |
|
1,4165 |
48,302 |
|
1,4166 |
48,350 |
|
1,4167 |
48,399 |
|
1,4168 |
48,447 |
|
1,4169 |
48,495 |
|
1,4170 |
48,543 |
|
1,4171 |
48,591 |
|
1,4172 |
48,639 |
|
1,4173 |
48,687 |
|
1,4174 |
48,735 |
|
1,4175 |
48,784 |
|
1,4176 |
48,832 |
|
1,4177 |
48,880 |
|
1,4178 |
48,928 |
|
1,4179 |
48,976 |
|
1,4180 |
49,023 |
|
1,4181 |
49,071 |
|
1,4182 |
49,119 |
|
1,4183 |
49,167 |
|
1,4184 |
49,215 |
|
1,4185 |
49,263 |
|
1,4186 |
49,311 |
|
1,4187 |
49,359 |
|
1,4188 |
49,407 |
|
1,4189 |
49,454 |
|
1,4190 |
49,502 |
|
1,4191 |
49,550 |
|
1,4192 |
49,598 |
|
1,4193 |
49,645 |
|
1,4194 |
49,693 |
|
1,4195 |
49,741 |
|
1,4196 |
49,788 |
|
1,4197 |
49,836 |
|
1,4198 |
49,884 |
|
1,4199 |
49,931 |
|
1,4200 |
49,979 |
|
1,4201 |
50,027 |
|
1,4202 |
50,074 |
|
1,4203 |
50,122 |
|
1,4204 |
50,169 |
|
1,4205 |
50,217 |
|
1,4206 |
50,264 |
|
1,4207 |
50,312 |
|
1,4208 |
50,359 |
|
1,4209 |
50,407 |
|
1,4210 |
50,454 |
|
1,4211 |
50,502 |
|
1,4212 |
50,549 |
|
1,4213 |
50,596 |
|
1,4214 |
50,644 |
|
1,4215 |
50,691 |
|
1,4216 |
50,738 |
|
1,4217 |
50,786 |
|
1,4218 |
50,833 |
|
1,4219 |
50,880 |
|
1,4220 |
50,928 |
|
1,4221 |
50,975 |
|
1,4222 |
51,022 |
|
1,4223 |
51,069 |
|
1,4224 |
51,116 |
|
1,4225 |
51,164 |
|
1,4226 |
51,211 |
|
1,4227 |
51,258 |
|
1,4228 |
51305 |
|
1,4229 |
51,352 |
|
1,4230 |
51,399 |
|
1,4231 |
51,446 |
|
1,4232 |
51,493 |
|
1,4233 |
51,540 |
|
1,4234 |
51,587 |
|
1,4235 |
51,634 |
|
1,4236 |
51,681 |
|
1,4237 |
51,728 |
|
1,4238 |
51,775 |
|
1,4239 |
51,822 |
|
1,4240 |
51,869 |
|
1,4241 |
51,916 |
|
1,4242 |
51,963 |
|
1,4243 |
52,010 |
|
1,4244 |
52,057 |
|
1,4245 |
52,104 |
|
1,4246 |
52,150 |
|
1,4247 |
52,197 |
|
1,4248 |
52,244 |
|
1,4249 |
52,291 |
|
1,4250 |
52,338 |
|
1,4251 |
52,384 |
|
1,4252 |
52,431 |
|
1,4253 |
52,478 |
|
1,4254 |
52,524 |
|
1,4255 |
52,571 |
|
1,4256 |
52,618 |
|
1,4257 |
52,664 |
|
1,4258 |
52,711 |
|
1,4259 |
52,758 |
|
1,4260 |
52,804 |
|
1,4261 |
52,851 |
|
1,4261 |
52,897 |
|
1,4263 |
52,944 |
|
1,4264 |
52,990 |
|
1,4265 |
53,037 |
|
1,4266 |
53,083 |
|
1,4267 |
53,130 |
|
1,4268 |
53,176 |
|
1,4269 |
53,223 |
|
1,4270 |
53,269 |
|
1,4271 |
53,316 |
|
1,4272 |
53,362 |
|
1,4273 |
53,408 |
|
1,4274 |
53,455 |
|
1,4275 |
53,501 |
|
1,4276 |
53,548 |
|
1,4277 |
53,594 |
|
1,4278 |
53,640 |
|
1,4279 |
53,686 |
|
1,4280 |
53,733 |
|
1,4281 |
53,779 |
|
1,4282 |
53,825 |
|
1,4283 |
53,871 |
|
1,4284 |
53,918 |
|
1,4285 |
53,964 |
|
1,4286 |
54,010 |
|
1,4287 |
54,056 |
|
1,4288 |
54,102 |
|
1,4289 |
54,148 |
|
1,4290 |
54,194 |
|
1,4291 |
54,241 |
|
1,4292 |
54,287 |
|
1,4293 |
54,333 |
|
1,4294 |
54,379 |
|
1,4295 |
54,425 |
|
1,4296 |
54,471 |
|
1,4297 |
54,517 |
|
1,4298 |
54,563 |
|
1,4299 |
54,609 |
|
1,4300 |
54,655 |
|
1,4301 |
54,701 |
|
1,4302 |
54,746 |
|
1,4303 |
54,792 |
|
1,4304 |
54,838 |
|
1,4305 |
54,884 |
|
1,4306 |
54,930 |
|
1,4307 |
54,976 |
|
1,4308 |
55,022 |
|
1,4309 |
55067 |
|
1,4310 |
55,113 |
|
1,4311 |
55,159 |
|
1,4312 |
55,205 |
|
1,4313 |
55,250 |
|
1,4314 |
55,296 |
|
1,4315 |
55,342 |
|
1,4316 |
55,388 |
|
1,4317 |
55,433 |
|
1,4318 |
55,479 |
|
1,4319 |
55,524 |
|
1,4320 |
55,570 |
|
1,4321 |
55,616 |
|
1,4322 |
55,661 |
|
1,4323 |
55,707 |
|
1,4324 |
55,752 |
|
1,4325 |
55,798 |
|
1,4326 |
55,844 |
|
1,4327 |
55,889 |
|
1,4328 |
55,935 |
|
1,4329 |
55,980 |
|
1,4330 |
56,026 |
|
1,4331 |
56,071 |
|
1,4332 |
56,116 |
|
1,4133 |
56,162 |
|
1,4334 |
56,207 |
|
1,4335 |
56,253 |
|
1,4336 |
56,298 |
|
1,4337 |
56,343 |
|
1,4338 |
56,389 |
|
1,4339 |
56,434 |
|
1,4340 |
56,479 |
|
1,4341 |
56,525 |
|
1,4342 |
56,570 |
|
1,4343 |
56,615 |
|
1,4344 |
56,660 |
|
1,4345 |
56,706 |
|
1,4346 |
56,751 |
|
1,4347 |
56,796 |
|
1,4348 |
56,841 |
|
1,4349 |
56,887 |
|
1,4350 |
56,932 |
|
1,4351 |
56,977 |
|
1,4352 |
57,022 |
|
1,4353 |
57,067 |
|
1,4354 |
57,112 |
|
1,4355 |
57,157 |
|
1,4356 |
57,202 |
|
1,4357 |
57,247 |
|
14358 |
57,292 |
|
1,4359 |
57,337 |
|
1,4360 |
57,382 |
|
1,4361 |
57,427 |
|
1,4362 |
57,472 |
|
1,4363 |
57,517 |
|
1,4364 |
57,562 |
|
1,4365 |
57,607 |
|
1,4366 |
57,652 |
|
1,4367 |
57,697 |
|
1,4368 |
57,742 |
|
1,4369 |
57,787 |
|
1,4370 |
57,832 |
|
1,4371 |
57,877 |
|
1,4372 |
57,921 |
|
1,4373 |
57,966 |
|
1,4374 |
58,011 |
|
1,4375 |
58,056 |
|
1,4376 |
58,101 |
|
1,4377 |
58,145 |
|
1,4378 |
58,190 |
|
1,4379 |
58,235 |
|
1,4380 |
58,279 |
|
1,4381 |
58,324 |
|
1,4382 |
58,369 |
|
1,4383 |
58,413 |
|
1,4384 |
53,458 |
|
1,4385 |
58,503 |
|
1,4386 |
58,547 |
|
1,4387 |
58,592 |
|
1,4388 |
58,637 |
|
1,4389 |
58,681 |
|
1,4390 |
58,726 |
|
1,4391 |
58,770 |
|
1,4392 |
58,815 |
|
1,4393 |
58,859 |
|
1,4394 |
58,904 |
|
1,4395 |
58,948 |
|
1,4396 |
58,993 |
|
1,4397 |
59,037 |
|
1,4398 |
59,082 |
|
1,4399 |
59,126 |
|
1,4400 |
59,170 |
|
1,4401 |
59,215 |
|
1,4402 |
59,259 |
|
1,4403 |
59,304 |
|
1,4404 |
59,348 |
|
1,4405 |
59,392 |
|
1,4406 |
59,437 |
|
1,4407 |
59,481 |
|
1,4408 |
59,525 |
|
1,4409 |
59,569 |
|
1,4410 |
59,614 |
|
1,4411 |
59,658 |
|
1,4412 |
59,702 |
|
1,4413 |
59,746 |
|
1,4414 |
59,791 |
|
1,4415 |
59,835 |
|
1,4416 |
59,879 |
|
1,4417 |
59,923 |
|
1,4418 |
59,967 |
|
1,4419 |
60,011 |
|
1,4420 |
60,056 |
|
1,4421 |
60,100 |
|
1,4422 |
60,144 |
|
1,4423 |
60,188 |
|
1,4424 |
60,232 |
|
1,4425 |
60,276 |
|
1,4426 |
60,320 |
|
1,4427 |
60,364 |
|
1,4428 |
60,408 |
|
1,4429 |
60,452 |
|
1,4430 |
60,496 |
|
1,4431 |
60,540 |
|
1,4432 |
60,584 |
|
1,4433 |
60,628 |
|
1,4434 |
60,672 |
|
1,4435 |
60,716 |
|
1,4436 |
60,759 |
|
1,4437 |
60,803 |
|
1,4438 |
60,847 |
|
1,4439 |
60,891 |
|
1,4440 |
60,935 |
|
1,4441 |
60,979 |
|
1,4442 |
61,023 |
|
1,4443 |
61,066 |
|
1,4444 |
61,110 |
|
1,4445 |
61,154 |
|
1,4446 |
61,198 |
|
1,4447 |
61,241 |
|
1,4448 |
61,285 |
|
1,4449 |
61,329 |
|
1,4450 |
61,372 |
|
1,4451 |
61,416 |
|
1,4452 |
61,460 |
|
1,4453 |
61,503 |
|
1,4454 |
61,547 |
|
1,4455 |
61,591 |
|
1,4456 |
61,634 |
|
1,4457 |
61,678 |
|
1,4458 |
61,721 |
|
1,4459 |
61,765 |
|
1,4460 |
61,809 |
|
1,4461 |
61,852 |
|
1,4462 |
61,896 |
|
1,4463 |
61,939 |
|
1,4464 |
62,983 |
|
1,4465 |
62,026 |
|
1,4466 |
62,070 |
|
1,4467 |
62,113 |
|
1,4468 |
62,156 |
|
1,4469 |
62,200 |
|
1,4470 |
62,243 |
|
1,4471 |
62,287 |
|
1,4472 |
62,330 |
|
1,4473 |
62,373 |
|
1,4474 |
62,417 |
|
1,4475 |
62,460 |
|
1,4476 |
62,503 |
|
1,4477 |
62,547 |
|
1,4478 |
62,590 |
|
14479 |
62,633 |
|
1,4480 |
62,677 |
|
1,4481 |
62,720 |
|
1,4482 |
62,763 |
|
1,4483 |
62,806 |
|
1,4184 |
62,849 |
|
1,4485 |
62,893 |
|
1,4486 |
62,936 |
|
1,4487 |
62,979 |
|
1,4488 |
63,022 |
|
1,4489 |
63,065 |
|
1,4490 |
63,108 |
|
1,4491 |
63,152 |
|
1,4492 |
63,195 |
|
1,4493 |
63,238 |
|
1,4494 |
63,281 |
|
1,4495 |
63,324 |
|
1,4496 |
63,367 |
|
1,4497 |
63,410 |
|
1,4498 |
63,453 |
|
1,4499 |
63,496 |
|
1,4500 |
63,539 |
|
1,4501 |
63,582 |
|
1,4502 |
63,625 |
|
1,4503 |
63,668 |
|
1,4304 |
63,711 |
|
1,4505 |
63,754 |
|
1,4506 |
63,797 |
|
1,4507 |
63,840 |
|
1,4508 |
63,882 |
|
1,4509 |
63,925 |
|
1,4510 |
63,968 |
|
1,4511 |
64,011 |
|
1,4512 |
64,054 |
|
1,4513 |
64,097 |
|
1,4514 |
64,139 |
|
1,4515 |
64,182 |
|
1,4516 |
64,225 |
|
1,4517 |
64,268 |
|
1,4518 |
64,311 |
|
1,4519 |
64,353 |
|
1,4520 |
64,396 |
|
1,4521 |
64,439 |
|
1,4522 |
64,481 |
|
1,4523 |
64,524 |
|
1,4524 |
64,567 |
|
1,4525 |
64,609 |
|
1,4526 |
64,652 |
|
1,4527 |
64,695 |
|
1,4528 |
64,737 |
|
1,4529 |
64,780 |
|
1,4530 |
64,823 |
|
1,4531 |
64,865 |
|
1,4532 |
64,908 |
|
1,4533 |
64,950 |
|
1,4534 |
64,993 |
|
1,4535 |
65,035 |
|
1,4536 |
65,078 |
|
1,4537 |
65,120 |
|
1,4538 |
65,163 |
|
1,4539 |
65,205 |
|
1,4540 |
65,248 |
|
1,4541 |
65,290 |
|
1,4542 |
65,333 |
|
1,4543 |
65,375 |
|
1,4544 |
65,417 |
|
1,4545 |
65,460 |
|
1,4546 |
65,502 |
|
1,4547 |
65,544 |
|
1,4548 |
65,587 |
|
1,4549 |
65,629 |
|
1,4550 |
65,672 |
|
1,4551 |
65,714 |
|
1,4552 |
65,756 |
|
1,4553 |
65,798 |
|
1,4554 |
65,841 |
|
1,4555 |
65,883 |
|
1,4556 |
65,925 |
|
1,4557 |
65,967 |
|
1,4558 |
66,010 |
|
1,4559 |
66,052 |
|
1,4560 |
66,094 |
|
1,4561 |
66,136 |
|
1,4562 |
66,178 |
|
1,4563 |
66,221 |
|
1,4564 |
66,263 |
|
1,4565 |
66,305 |
|
1,4566 |
66,347 |
|
1,4567 |
66,389 |
|
1,4568 |
66,431 |
|
1,4569 |
66,473 |
|
1,4570 |
66,515 |
|
1,4571 |
66,557 |
|
1,4572 |
66,599 |
|
1,4573 |
66,641 |
|
1,4574 |
66,683 |
|
1,4575 |
66,725 |
|
1,4576 |
66,767 |
|
1,4577 |
66,809 |
|
1,4578 |
66,851 |
|
1,4579 |
66,893 |
|
1,4580 |
66,935 |
|
1,4581 |
66,977 |
|
1,4582 |
67,019 |
|
1,4583 |
67,061 |
|
1,4584 |
67,103 |
|
1,4585 |
67,145 |
|
1,4586 |
67,186 |
|
1,4587 |
67,228 |
|
1,4588 |
67,270 |
|
1,4589 |
67,312 |
|
1,4590 |
67,354 |
|
1,4591 |
67,396 |
|
1,4592 |
67,437 |
|
1,4593 |
67,479 |
|
1,4594 |
67,521 |
|
1,4595 |
67,563 |
|
1,4596 |
67,604 |
|
1,4597 |
67,646 |
|
1,4598 |
67,688 |
|
1,4599 |
67,729 |
|
1,4600 |
67,771 |
|
1,4601 |
67,813 |
|
1,4602 |
67,854 |
|
1,4603 |
67,896 |
|
1,4604 |
67,938 |
|
1,4605 |
67,979 |
|
1,4606 |
68,021 |
|
1,4607 |
68,063 |
|
1,4608 |
68,104 |
|
1,4609 |
68,146 |
|
1,4610 |
68,187 |
|
1,4611 |
68,229 |
|
1,4611 |
68,270 |
|
1,4613 |
68,312 |
|
1,4614 |
68,353 |
|
1,4615 |
68,395 |
|
1,4616 |
68,436 |
|
1,4617 |
68,478 |
|
1,4618 |
68,519 |
|
1,4619 |
68,561 |
|
1,4620 |
68,602 |
|
1,4621 |
68,643 |
|
1,4622 |
68,685 |
|
1,4623 |
68,726 |
|
1,4624 |
68,768 |
|
1,4625 |
68,809 |
|
1,4626 |
68,850 |
|
1,4627 |
68,892 |
|
1,4628 |
68,933 |
|
1,4629 |
68,974 |
|
1,4630 |
69,016 |
|
1,4631 |
69,057 |
|
1,4632 |
69,098 |
|
1,4633 |
69,139 |
|
1,4634 |
69,181 |
|
1,4635 |
69,222 |
|
1,4636 |
69,263 |
|
1,4637 |
69,304 |
|
1,4638 |
69,346 |
|
1,4639 |
69,387 |
|
1,4640 |
69,428 |
|
1,4641 |
69,469 |
|
1,4642 |
69,510 |
|
1,4643 |
69,551 |
|
1,4644 |
69,593 |
|
1,4645 |
69,634 |
|
1,4646 |
69,675 |
|
1,4647 |
69,716 |
|
1,4648 |
69,757 |
|
1,4649 |
69,798 |
|
1,4650 |
69,839 |
|
1,4651 |
69,880 |
|
1,4652 |
69,921 |
|
1,4653 |
69,962 |
|
1,4654 |
70,003 |
|
1,4655 |
70,044 |
|
1,4656 |
70,085 |
|
1,4657 |
70,126 |
|
1,4658 |
70,167 |
|
1,4659 |
70,208 |
|
1,4660 |
70,249 |
|
1,4661 |
70,290 |
|
1,4662 |
70,331 |
|
1,4663 |
70,372 |
|
1,4664 |
70,413 |
|
1,4665 |
70,453 |
|
1,4666 |
70,494 |
|
1,4667 |
70,535 |
|
1,4668 |
70,576 |
|
1,4669 |
70,617 |
|
1,4670 |
70,658 |
|
1,4671 |
70,698 |
|
1,4672 |
70,739 |
|
1,4673 |
70,780 |
|
1,4674 |
70,821 |
|
1,4675 |
70,861 |
|
1,4676 |
70,902 |
|
1,4677 |
70,943 |
|
1,4678 |
70,984 |
|
1,4679 |
71024 |
|
1,4680 |
71,065 |
|
1,4681 |
71,106 |
|
1,4681 |
71,146 |
|
1,4683 |
71,187 |
|
1,4684 |
71,228 |
|
1,4685 |
71,268 |
|
1,4686 |
71,309 |
|
1,4687 |
71,349 |
|
1,4688 |
71,390 |
|
1,4689 |
71,431 |
|
1,4690 |
71,471 |
|
1,4691 |
71,512 |
|
1,4692 |
71,552 |
|
1,4693 |
71,593 |
|
1,4694 |
71,633 |
|
1,4695 |
71,674 |
|
1,4696 |
71,714 |
|
1,4697 |
71,755 |
|
1,4698 |
71,795 |
|
1,4699 |
71,836 |
|
1,4700 |
71,876 |
|
1,4701 |
71,917 |
|
1,4702 |
71,957 |
|
1,4703 |
71,998 |
|
1,4704 |
72,038 |
|
1,4705 |
72,078 |
|
1,4706 |
72,119 |
|
1,4707 |
72,159 |
|
1,4708 |
72,199 |
|
1,4709 |
72,240 |
|
1,4710 |
72,280 |
|
1,4711 |
72,320 |
|
1,4712 |
72,361 |
|
1,4713 |
72,401 |
|
1,4714 |
72,441 |
|
1,4715 |
72,482 |
|
1,4716 |
72,522 |
|
1,4717 |
72,562 |
|
1,4718 |
72,602 |
|
1,4719 |
72,643 |
|
1,4720 |
72,683 |
|
1,4721 |
72,723 |
|
1,4722 |
72,763 |
|
1,4723 |
72,803 |
|
1,4724 |
72,843 |
|
1,4725 |
72,884 |
|
1,4726 |
72924 |
|
1,4727 |
72,964 |
|
1,4728 |
73,004 |
|
1,4729 |
73,044 |
|
1,4730 |
73,084 |
|
1,4731 |
73,124 |
|
1,4732 |
73,164 |
|
1,4733 |
73,204 |
|
1,4734 |
73,244 |
|
1,4735 |
73,285 |
|
1,4736 |
73,325 |
|
1,4737 |
73,365 |
|
1,4738 |
73,405 |
|
1,4739 |
73,445 |
|
1,4740 |
73,485 |
|
1,4741 |
73,524 |
|
1,4742 |
73,564 |
|
1,4743 |
73,604 |
|
1,4744 |
73,644 |
|
1,4745 |
73,684 |
|
1,4746 |
73,724 |
|
1,4747 |
73,764 |
|
1,4748 |
73,804 |
|
1,4749 |
73,844 |
|
1,4750 |
73,884 |
|
1,4751 |
73,924 |
|
1,4752 |
73,963 |
|
1,4753 |
74,003 |
|
1,4754 |
74,043 |
|
1,4755 |
74,083 |
|
1,4756 |
74,123 |
|
1,4757 |
74,162 |
|
1,4758 |
74,202 |
|
1,4759 |
74,242 |
|
1,4760 |
74,282 |
|
1,4761 |
74,321 |
|
1,4762 |
74,361 |
|
1,4763 |
74,401 |
|
1,4764 |
74,441 |
|
1,4765 |
74,480 |
|
1,4766 |
74,520 |
|
1,4767 |
74,560 |
|
1,4768 |
74,599 |
|
1,4769 |
74,639 |
|
1,4770 |
74,678 |
|
1,4771 |
74,718 |
|
1,1772 |
74,758 |
|
1,4773 |
74,797 |
|
1,4774 |
74,837 |
|
1,4775 |
74,876 |
|
1,4776 |
74,916 |
|
1,4777 |
74,956 |
|
1,4778 |
74,995 |
|
1,4779 |
75,035 |
|
1,4780 |
75,074 |
|
1,1781 |
75,114 |
|
1,4782 |
75,153 |
|
1,4783 |
75,193 |
|
1,4784 |
75,232 |
|
1,4785 |
75,272 |
|
1,4786 |
75,311 |
|
1,4787 |
75,350 |
|
1,4788 |
75,390 |
|
1,4789 |
75,429 |
|
1,4790 |
75,469 |
|
1,4791 |
75,508 |
|
1,4792 |
75,547 |
|
1,4793 |
75,587 |
|
1,4794 |
75,626 |
|
1,4795 |
75,666 |
|
1,4796 |
75,705 |
|
1,4797 |
75,744 |
|
1,4798 |
75,784 |
|
1,4799 |
75,823 |
|
1,4800 |
75,862 |
|
1,4801 |
75,901 |
|
1,4802 |
75,941 |
|
1,4803 |
75,980 |
|
1,4804 |
76,019 |
|
1,4805 |
76,058 |
|
1,4806 |
76,098 |
|
1,4807 |
76,137 |
|
1,4808 |
76,176 |
|
1,4809 |
76,215 |
|
1,4810 |
76,254 |
|
1,4810 |
76,294 |
|
1,4812 |
76,333 |
|
1,4813 |
76,372 |
|
1,4814 |
76,411 |
|
1,4815 |
76,450 |
|
1,4816 |
76,489 |
|
1,4817 |
76,528 |
|
1,4818 |
76,567 |
|
1,4819 |
76,607 |
|
1,4820 |
76,646 |
|
1,4821 |
76,685 |
|
1,4822 |
76,724 |
|
1,4823 |
76,763 |
|
1,4824 |
76,802 |
|
1,4825 |
76,841 |
|
1,4826 |
76,880 |
|
1,4827 |
76,919 |
|
1,4828 |
76,958 |
|
1,4829 |
76,997 |
|
1,4830 |
77,036 |
|
1,4831 |
77,075 |
|
1,4832 |
77,113 |
|
1,4833 |
77,152 |
|
1,4834 |
77,191 |
|
1,4835 |
77,230 |
|
1&xxxx;4336 |
77269 |
|
1,4837 |
77,308 |
|
1,4838 |
77,347 |
|
1,4839 |
77,386 |
|
1,4840 |
77,425 |
|
1,4841 |
77,463 |
|
1,4842 |
77,502 |
|
1,4843 |
77,541 |
|
1,4844 |
77,580 |
|
1,4845 |
77,619 |
|
1,4846 |
77,657 |
|
1,4847 |
77,696 |
|
1,4848 |
77,735 |
|
1,4849 |
77,774 |
|
1,4850 |
77,812 |
|
1,4851 |
77,851 |
|
1,4852 |
77,890 |
|
1,4853 |
77,928 |
|
1,4854 |
77,967 |
|
1,4855 |
78,006 |
|
1,4856 |
78,045 |
|
1,4857 |
78,083 |
|
1,4858 |
78,122 |
|
1,4859 |
78,160 |
|
1,4860 |
78,199 |
|
1,4861 |
78,238 |
|
1,4862 |
78,276 |
|
1,4863 |
78,315 |
|
1,4864 |
78,353 |
|
1,4865 |
78,392 |
|
1,4866 |
78,431 |
|
1,4867 |
78,469 |
|
1,4868 |
78,508 |
|
1,4869 |
78,546 |
|
1,4870 |
78,585 |
|
1,4871 |
78,623 |
|
1,4872 |
78,662 |
|
1,4873 |
78,700 |
|
1,4874 |
78,739 |
|
1,4875 |
78,777 |
|
1,4876 |
78,816 |
|
1,4877 |
78,854 |
|
1,4878 |
78,892 |
|
1,4879 |
78,931 |
|
1,4880 |
78,969 |
|
1,4881 |
79,008 |
|
1,4882 |
79,046 |
|
1,4883 |
79,084 |
|
1,4884 |
79,123 |
|
1,4885 |
79,161 |
|
1,4886 |
79,199 |
|
1,4887 |
79,238 |
|
1,4888 |
79,276 |
|
1,4889 |
79,314 |
|
1,4890 |
79,353 |
|
1,4891 |
79,391 |
|
1,4892 |
79,429 |
|
1,4893 |
79,468 |
|
1,4894 |
79,506 |
|
1,4895 |
79,544 |
|
1,4896 |
79,582 |
|
1,4897 |
79,620 |
|
1,4898 |
79,659 |
|
1,4899 |
79,697 |
|
1,4900 |
79,735 |
|
1,4901 |
79,773 |
|
1,4902 |
79,811 |
|
1,4903 |
79,850 |
|
1,4904 |
79,888 |
|
1,4905 |
79,926 |
|
1,4906 |
79,964 |
|
1,4907 |
80,002 |
|
1,4908 |
80,040 |
|
1,4909 |
80,078 |
|
1,4910 |
80,116 |
|
1,4911 |
80,154 |
|
1,4912 |
80,192 |
|
1,4913 |
80,231 |
|
1,4914 |
80,269 |
|
1,4915 |
80,307 |
|
1,4916 |
80,345 |
|
1,4917 |
80,383 |
|
1,4918 |
80,421 |
|
1,4919 |
80,459 |
|
1,4920 |
80,497 |
|
1,4921 |
80,534 |
|
1,4922 |
80,572 |
|
1,4923 |
80,610 |
|
1,4924 |
80,648 |
|
1,4925 |
80,686 |
|
1,4926 |
80,724 |
|
1,4927 |
80,762 |
|
1,4928 |
80,800 |
|
1,4929 |
80,838 |
|
1,4930 |
80,876 |
|
1,4931 |
80,913 |
|
1,4932 |
80,951 |
|
1,4933 |
80,989 |
|
1,4934 |
81,027 |
|
1,4935 |
81,065 |
|
1,4936 |
81,103 |
|
1,4937 |
81,140 |
|
1,4938 |
81,178 |
|
1,4939 |
81,216 |
|
1,4940 |
81,254 |
|
1,4941 |
81,291 |
|
1,4942 |
81,329 |
|
1,4943 |
81,367 |
|
1,4944 |
81,405 |
|
1,4945 |
81,442 |
|
1,4946 |
81,480 |
|
1,4947 |
81,518 |
|
1,4948 |
81,555 |
|
1,4949 |
81,593 |
|
1,4950 |
81,631 |
|
1,4951 |
81,668 |
|
1,4952 |
81,706 |
|
1,4953 |
81,744 |
|
1,4954 |
81,781 |
|
1,4955 |
81,819 |
|
1,4956 |
81,856 |
|
1,4957 |
81,894 |
|
1,4958 |
81,932 |
|
1,4959 |
81,969 |
|
1,4960 |
82,007 |
|
1,4961 |
82,044 |
|
1,4962 |
82,082 |
|
1,4963 |
82,119 |
|
1,4964 |
82,157 |
|
1,4965 |
82,194 |
|
1,4966 |
82,232 |
|
1,4967 |
82,269 |
|
1,4968 |
82,307 |
|
1,4969 |
82,344 |
|
1,4970 |
82,381 |
|
1,4971 |
82,419 |
|
1,4972 |
82,456 |
|
1,4973 |
82,494 |
|
1,4974 |
87,531 |
|
1,4975 |
82,569 |
|
1,9976 |
82,606 |
|
1,4977 |
82,643 |
|
1,4978 |
82,681 |
|
1,4979 |
82,718 |
|
1,4980 |
82,755 |
|
1,4981 |
82,793 |
|
1,4982 |
82,830 |
|
1,4983 |
82,867 |
|
1,4984 |
82,905 |
|
1,4985 |
82,942 |
|
1,4986 |
82,979 |
|
1,4987 |
83,016 |
|
1,4988 |
83,054 |
|
1,4989 |
83,091 |
|
14990 |
83,128 |
|
1,4991 |
83,165 |
|
1,4992 |
83,202 |
|
1,4993 |
83,240 |
|
1,4994 |
83,277 |
|
1,4995 |
83,314 |
|
1,4996 |
83,351 |
|
1,4997 |
83,388 |
|
1,4998 |
83,425 |
|
14999 |
83,463 |
|
1,5000 |
83,500 |
|
1,5001 |
83,537 |
|
1,5002 |
83,574 |
|
1,5003 |
83,611 |
|
1,5004 |
83,648 |
|
1,5005 |
83,685 |
|
1,5006 |
83,722 |
|
1,5007 |
83,759 |
|
1,5008 |
83,796 |
|
1,5009 |
83,833 |
|
1,5010 |
83,870 |
|
1,5011 |
83,907 |
|
1,5012 |
83,944 |
|
1,5013 |
83,981 |
|
1,5014 |
84,018 |
|
1,5015 |
84,055 |
|
1,5016 |
84,092 |
|
1,5017 |
84,129 |
|
1,5018 |
84,166 |
|
1,5019 |
84,203 |
|
1,5020 |
84,240 |
|
1,5021 |
84,277 |
|
1,5022 |
84,314 |
|
1,5023 |
84,351 |
|
1,5024 |
84,388 |
|
1,5025 |
84,424 |
|
1,5026 |
84,461 |
|
1,5027 |
84,498 |
|
1,5028 |
84,535 |
|
1,5029 |
84,572 |
|
1,5030 |
84,609 |
|
1,5031 |
84,645 |
|
1&xxxx;5032 |
84,682 |
|
1,5033 |
84,719 |
|
1,5034 |
84,756 |
|
1,5035 |
84,792 |
|
1,5036 |
84,829 |
|
1,5037 |
84,866 |
|
1,5038 |
84,903 |
|
1,5039 |
84,939 |
|
1,5040 |
84,976 |
|
1,5041 |
85,013 |
|
1,5042 |
85,049 |
|
1,5043 |
85,086 |
|
1,5044 |
85,123 |
|
1,5045 |
85,159 |
|
1,5046 |
85,196 |
|
1,5047 |
85,233 |
|
1,5048 |
85,269 |
|
1,5049 |
85,306 |
|
1,5050 |
85,343 |
|
1,5051 |
85,379 |
|
1,5052 |
85,416 |
|
1,5053 |
85,452 |
|
1,5054 |
85,489 |
|
1,5055 |
85,525 |
|
1,5056 |
85,562 |
|
1,5057 |
85,598 |
|
1,5058 |
85,635 |
|
1,5059 |
85,672 |
|
1,5060 |
85,708 |
|
1,5061 |
85,744 |
|
1,5062 |
85,781 |
|
1,5063 |
85,817 |
|
1,5064 |
85,854 |
|
1,5065 |
85,890 |
|
1,5066 |
85,927 |
|
1,5067 |
85,963 |
|
1,5068 |
86,000 |
|
1,5069 |
86,036 |
|
1,5070 |
86,072 |
|
1,5071 |
86,109 |
|
1,5072 |
86,145 |
|
1,5073 |
86,182 |
|
1,5074 |
86,218 |
|
1,5075 |
86,254 |
|
1,5076 |
86,291 |
|
1,5077 |
86,327 |
|
1,5078 |
86,363 |
|
1,5079 |
86,399 |
[1] Xxxxxxx x v xxxxxx xxxxxxxxx xxxx vypočteny xxxxxx xxxxxxx, jejímž xxxxxxx xxx ICUMSA xx K. Xxxxxxxxxx. Xxxxxxx xxxx naprogramována x xxxxxxx provedeny Xxxxxxx X. Xxxxxxxxxxx x USDA x xxxx publikovány v Xxxxx X. 33, 15-22 (xxxxxx 1970). Xxxxx lomu xxx xxxxx při 20 °X xxxxxx D xxxx Na. Xxxx (xxxxxxxx xxxxxxxxxx xxxxxxxxx) xxx xxxxxx vážením xxx 20 °C xx xxxxxxx xxx xxxxx 760 torrů (xx Hg) x xxxxxxxxxxxxxxxxx relativní xxxxxxxx. Xxxx tabulka nahrazuje xxxxxxx xxxxxxxxx (47&xxxx;012, xxxxxx 11) xxxxxxxxxxxx x Xxxxxx. Xxxxx X. 39, 22 (1937).
XXXXXX 4
XXXXXXXXX XXXXXXXXXXXX XXXXX VYJÁDŘENÝCH JAKO XXXXXXXX XXXXX
(Xxxxxx xxxxx xxxxxx Berlin Xxxxxxxx)
1. Xxxxxxx x xxxxxx xxxxxxx
Xxxxxx xxxxxx xx xxxxxxxxx xxxxxxxxxxxx cukrů xxxxxxxxxxx xxxx xxxxxxxx xxxx x cukru xxxxxxxxx
2. Definice
„Redukující xxxxx xxxxxxxxx xxxx invertní xxxx“: xxxxx redukujících xxxxx xxxxxxxxx xxxxxxxx xxxxxxx.
3. Xxxxxxxx metody
Roztok xxxxxx x xxxxxxx xxxxxxxxxxxx cukrů xx xxxxxxx pro redukci xxxxxxx xxxxxxxx xxxx XX. Xxxxxxx xxxx xxxxx xx xxx xxxxxxx odměrným roztokem xxxx (xx známým xxxxxx), xxxxx xxxxxxxx xx xxxxxxx xxxxxxx xxxxxxx xxxxxxxx roztokem xxxxxxxxxx xxxxxxx (xx xxxxxx xxxxxx).
4. Xxxxxxx xxxxxxx
4.1 Xxxxxx Xx XX (Xxxxxxxx roztok)
4.1.1 Xx 400 ml xxxxxx vody xx xxxxxxxx 35 x xxxxxx xxxxxxxxx xxxxxxxxxxxx (XxXX4 5X2X) x xxxxx xx xxxxxxxxxxx.
4.1.2 X 500 ml xxxxxx vody se xxxxxxxx 173 x xxxxxx sodnodraselného tetrahydrátu (Xxxxxxxxxx nebo Xxxxxxxxxxx xxx, XXxX4X4X6,4X2X) x 68 x xxxxxxxxx xxxxxxxxxx xxxxxxx x xxxxx xx xxxxxxxxxxx.
4.1.3 Xxx xxxxxxx (4.1.1 x 4.1.2) se xxxxxxxx xx litrové xxxxxxx baňky x xxxxxx se xxxxx xx 1 litru. Xx přidání 2 x aktivního xxxx xx xxxxx protřepe, xxxxx xx xxxxxxx xxxxx stát a xxxx se xxxxxxxxxxx xxxx xxxxx papírový xxxx membránový filtr.
Pokud xx x xxxxxxx xxxxxxxxxx xxxxxxx objeví xxxx xxxxxxxx oxidu xxxxxxx, je třeba xxxxxx xxxxx přefiltrovat.
4.2 Xxxxxxxx octová, xxxxxx 5 xxx/x.
4.3 Roztok xxxx, 0,01665 xxx/x (0,0333X; 4,2258 g/l).
4.4 Xxxxxx xxxxxxxxxx sodného, xxxxxx 0,0333 xxx/x.
4.5 Xxxxxx xxxxxx: xx xxxxx vroucí xxxx xx přilije směs 5 x xxxxxxxxxxx xxxxxx rozmíchaného xx 30 xx xxxx, xxxxxx xx 3 xxxxxx x nechá xxxxxxxxxxx. X xxxxxxx xxxxxxx xx přidá 10 xx jodidu xxxxxxxxxx xxxx konzervačního xxxxxxx.
5. Přístroje a xxxxxxx
5.1 Erlenmeyerova xxxxx, 300 ml; přesné xxxxxx x xxxxxx.
5.2 Xxxxx xxxxx, xxxxxx.
6. Xxxxxx
6.1 Do 300 xx Xxxxxxxxxxxxx baňky xx xxxxxx xxxx xxxxxx (10 g xxxx xxxx), který xxxxxxxxxx xxxx xxx 30 xx xxxxxxxxxx xxxxx, x xxxxxxxx xx přibližně ve 100 xx xxxx.
Xx xxxxx x roztokem xxxxxx se odpipetuje 10 ml roztoku Xx II (4.1), xxxxx xx krouživým xxxxxxx xxxxxxx x xxxxx xx xxxxx xx xxxxxx xxxxx xxxxx (5.2) xx xxxx přesně 10 xxxxx.
Xxxxxxx xxxxxxx x Xxxxxxxxxxxxx xxxxx xxxx xxx xxxxxxx 20 xx xxx úrovní xxxxxxx xx xxxxx xxxxx. Xxxxx se xxxxxx xxxxxxx proudem xxxxxxx xxxx, xxxxxxx xx roztok nesmí xxxxxxxxxxx, aby xxxxxxx x opětovné oxidaci xxxxxxxxxxx oxidu xxxxxxx xxxxxxxx xxxxxxxx.
Xxx xxxxxxxxxxxx xxxxxx xx xxxxxxx xxxxx 5 xx xxxxxxx kyseliny xxxxxx (4.2) o koncentraci 5 xxx/x x xxxxx xxxx se xxxxxxx přidá xxxxxxxx (20 až 40 xx) xxxxxxx xxxx (4.3) o koncentraci 0,016 65 mol/l.
Sraženina xxxx se mícháním xxxxxxxx a xxxxxxxx xxxx se xxxxxxx xxxxxxxx thiosíranu xxxxxxx (4.4) x koncentraci 0,0333 mol/l při xxxxxxx xxxxxxx škrobu (4.5) xxxx xxxxxxxxxx. Xxxxxxxxx xx přidává xx konci xxxxxxx.
6.2 X xxxxx se xxxxxxx slepý pokus, xxxxx xx opakuje xxxx xxx xxxxxxx xxxxxx xxxxxxx Cu XX (4.4). Titrační xxxxxxxx nepřekročí 0,1 xx.
6.3 S xxxxxxxx xxxxxxxx xx xx xxxxxx xxxxxxx xxxxxxxxx xxxxxxx. Xxxxxx xx xxxxx xxxx xxx xxxxxxxxxxx teplotě xx xxxx 10 minut, xxx xxxxx xxxxx x xxxxxx xxxxxx, xxxxxxxxxx přítomných xxxxxxxxxxxx xxxxx, xxxx xx xxxxxxxxx xxxx xxxxxxxx.
7. Xxxxxxxxx xxxxxxxx
7.1 Xxxxxx x postup výpočtu
Objem xxxxxxxxxxxxxx xxxxxxx xxxx xx xxxxx xxxxxx (xx) xxxxxxxx xxxxxxxxx xxxxxxx jódu (0,016 65 xxx/x) minus xxxxx (xx) xxxxxxx xxxxxxxxxx sodného (0,0333 xxx/x) spotřebovaného xxx xxxxxxx.
Xxxxx (xx) spotřebovaného xxxxxxx xxxx (0,016 65 xxx/x) xx xxxxxx xxxxxxxxx:
7.1.1 xxxxx xx xxxxxxxxxxxxxx při xxxxxx xxxxxx x xxxxx (6.2),
7.1.2 počtu xx xxxxxxxxxxxxxx xxx xxxxxxxxx xxxxxxx s xxxxxxxx roztokem za xxxxxx (6.3),
7.1.3 objemu 2,0 ml xx xxxxxxx 10 g xxxxxxxxx xxxxxxxx x xxxxxxxx alikvotním xxxxxx xxxx xxxxxxxx množství, xxxxxxxx-xx vzorek méně xxx 10 x xxxxxxxxx (korekce xx xxxxxxxxx).
Xx xxxxxxxxx těchto xxxxxxx odpovídá xxxxxxxx 1 xx xxxxxxxx xxxxxxx (4.3) 1 xx xxxxxxxxxx cukru.
Obsah xxxxxxxxxx xxxxx x xxxxxxxxxx xxxxxx xx xxxxxxxx xxxxx vzorce:
kde:
V1 = xxxxx ml xxxxxxxx xxxxxxx (4.3) xx xxxxxxx,
x0 = xxxxxxxx xxxxxxxxx vzorku (x).
7.2 Opakovatelnost
Rozdíl xxxx xxxxxxxx dvou xxxxxxxxx xxxxxxxxxxx xxxxxxx xxxx xxxxxx xx xxxxx x téhož xxxxxx xxxxxx xxxxxxxxxxx xx xxxxxxxxx xxxxxxxx xxxxx xxx větší xxx 0,02 g na 100 x xxxxxx.
XXXXXX 5
XXXXXXXXX XXXXXXXXXXXX XXXXX XXXXXXXXXXX XXXX INVERTNÍ XXXX
(Xxxxxx podle Xxxxxxx x Xxxxxx)
1. Xxxxxxx x oblast xxxxxxx
Xxxxxx xxxxxx xx xxxxxxxxx xxxxxxxxxxxx xxxxx xxxxxxxxxxx xxxx invertní xxxx
- x xxxxx xxxx x xxxxx bílém,
- x xxxxx xxxxx xxxxx.
2. Xxxxxxxx
„Xxxxxxxxxx xxxxx xxxxxxxxx xxxx xxxxxxxx xxxx“: obsah redukujících xxxxx stanovený xxxxxxxx xxxxxxx.
3. Xxxxxxxx xxxxxx
X xxxxxxx vzorku se xxxxx x xxxxxxxx xxxxxxx x obsahem Xx XX, xxxxxxxxxxx x nezredukovaný xxxxx xx xxx xxxxxxx xxxxxxx titrací x xxxxxxxx XXXX.
4. Xxxxxxx xxxxxxx
4.1 Kyselina xxxxxxxxxxxxxxxxxxxxxxxx (xxxxxxxxx xxx) (XXXX), xxxxxx 0,0025 mol/l: xxxxxxxx xx 0,930 x EDTA xx xxxx x doplní xx vodou do xxxxxxx litru.
4.2 Xxxxxx xxxxxxxxxx xxxxxxxx: 0,25 x xxxxxxxx xx xxxxx xx 50 xx vody x xxxxxx se x 20 xx xxxxxxx xxxxxxx methylenové xxxxx x koncentraci 0,2 x/100 xx.
4.3 Xxxxxxxxx xxxxxxx xxxxxxx: x 600 xx vody xxxxxxxxxx 40 xx xxxxxxxxx sodného o xxxxxxxxxxx 1,0 xxx/x xx xxxxxxxx 25 x xxxxxxxxx uhličitanu xxxxxxx x 25 x xxxxxx xxxxxxxxxxxxxxx xxxxxxxxxxxx. Xxxxxxxxx v 100 xx xxxx xx xxxxxxxx 6,0 x xxxxxx xxxxxxxxx – xxxxxxxxxxxx (XxXX4 5X2X), xxxxxxx xxxxxx xx xxxxx x xxxxxxx xxxxxx x xxxxxx xxxxx xx xxxxxxx xxxxx.
Xxxxxxxx: Xxxxxx xx xxxxxxxx xxxxxxxxxxx (xxxxx xxxxx).
4.4 Xxxxxxxxxx xxxxxx xxxxxxxxxx cukru: x xxxxxxx xxxxx x objemu 250 xx se xxxxxxxx 23,750 x čisté xxxxxxxxx (4.5) xxx xx 120 xx xxxx. Xxxxx se 9 ml xxxxxxxx xxxxxxxxxxxxxx (X20 = 1,16) x xxxxx xx xxxx při xxxxxxxxxxx xxxxxxx xx xxxx 8 xxx. Xxxxxx xx xxxxxx xx 250 xx x ukončení xxxxxxxxx xx xxxxxxxxxxx xxxxxxx xx xxxxxxxxxxx xxxx xxxxxxxxxxxx xxx xxxxxxx xxxxxxx x délce 200 mm. Xxxxxxxx xxxxxxx xx xx xxxxxx 11,80 ± 0,05°X (xxx xxxxxxxx 8). 200 ml xxxxxx xxxxxxx se xxxxxxxxxx xx xxxxxxx xxxxx o xxxxxx 2000 xx, xxxxx xx vodou a xx xxxxxxx xxxxxxxxxxxx (xxx xxxxxxx x xxxxxxxxxx xxxxxxxx xxxxxxxxxxxxx xxxxxxx) xx xxxxx 71,4 ml roztoku xxxxxxxxx xxxxxxx (1 xxx/x), xx kterém xxxx rozpuštěny 4 x kyseliny xxxxxxxx. Xxxxxx xx xxxxxx xx 2000 xx, xx. xxx obsahoval 1 x xxxxxxxxxx xxxxx xx 100 xx; xxxxxxx xX xxxxxxx se xx xxxxxxxxx xxxxx 3.
Xxxxx xxxxx xxxxxxx xxxxxx xx xxxx pouze xxxxxxxxxxxxx před xxxxxxxx.
4.5 Xxxxx xxxxxxxxx: xxxxxx xxxxx xxxxxxxxx x xxxxxxx xxxxxxxxxx xxxxx xxxxxxx 0,001 x/100 x.
5. Xxxxxxxxx x xxxxxxx
5.1 Zkumavky 150 x 20 xx.
5.2 Xxxx xxxxxxxxxxx miska.
5.3 Xxxxxxxxxx xxxx vážící x xxxxxxxxx xx 0,1 mg.
6. Postup
6.1 Xx xxxxxxxx (5.1) xx xxxxxxxx 5 x vzorku xxxxx x 5 xx xxxxxxx xxxx, xxxxxxx xx 2,0 xx xxxxxxxxx xxxxxxx (4.3) x xxxxx xx xxxxxxxx. Zkumavka xx xxxxxx xx xxxxx x vroucí vodou xx dobu 5 xxxxx x xxxx xx ve xxxxxxx xxxx ochladí.
6.2 Xxxxxx xx xx zkumavky xxxxxxxxxxxxx, x xxxxxxxx xx xxxxxxxxxx xxxxxxxx xxxx, xxxxxxx xx xxxx xxxxxxxxxxxx xxxxx (5.2), xxxxxxx xx xxx xxxxx xxxxxxxxxx (4.2) a xxxxxxx xx xxxxxxxx XXXX (4.1). Titrační xxxxxxxx x xx se xxxxxx jako X0.
Xxxxx xxxx xxxxxxxxx xxxxxxx xx xxxxx roztoku xxxxx xx xxxxxx xxxx xxxxx xx xxxxxxxxxx x konečném xxxx. Purpurová barva xxxxxx xxxx v xxxxxxxx xxxxxxx oxidu xxxxxxx xx xxxx xxxxxxx xxxxxxxx xxxxxxx xxxxxx na xxxxxxxxxxx xxxxxxxx xxxxxxxxxxx mědi. Xxxxx je xxx xxxxxxx nutné xxxxxxxxx xxxxxxxxx xxxx co xxxxx xxxxxxxxxxx.
6.3 Xxxxxxxx xx xxxxxxxxxx křivka xx základě xxxxxxxxx xxxxxxx množství invertního xxxxx (příslušně xxxxxxx xxxxxx 4.4) x 5 g xxxxx xxxxxxxxx (4.5) x xxxxxxxxxxxxxx xxxxxxxx xxxxxxx xxxx xxx, xxx xxxxxxx objem přidaného xxxxxxx xxxxx 5 xx. Titrační xxxxxxxx (xx) se xxxxxx xx xxxxx xxxxx xxxxxxxxxxx xxxxxx xxxxxxxxxx xxxxx xxxxxxxxx k 5 x xxxxxxxxx; xxxxxxxxx xxxxxxx xx xxxxxx x xxxxxxx 0,001 xx 0,019 x na 100 x xxxxxxxxxx xxxxx, xxxx. 100 x xxxxxx.
7. Xxxxxxxxx xxxxxxxx
7.1 Xxxxxx xxxxxxx
X xxxxxxxxxx xxxxxx se xxxxxx xxxxx xxxxxxxxxx cukru (x xxxxxxxxxx) xxxxxxxxxxxx xxxxxxxx XXXX X0 xx xxx analýze xxxxxx.
7.2 Xxxxx xx xxxxxxxxxxx xxxxx koncentrace xxx 0,017 x xxxxxxxxxx xxxxx ve 100 x xxxxxxxxxxxxx xxxxxx, xxxx xx xxxxxxxxx snížit xxxxxxxx xxxxxx v bodě 6.1, analyzovaný xxxxxx xx však xxxx xxxxxxx do 5 x čistou sacharosou (4.5).
7.3 Xxxxxxxxxxxxxx
Xxxxxx mezi xxxxxxxx xxxx xxxxxxxxx xxxxxxxxxxx xxxxxxx xxxx xxxxxx za xxxxx x xxxxx xxxxxx xxxxxx xxxxxxxxxxx za xxxxxxxxx xxxxxxxx nesmí xxx xxxxx než 0,005 g xx 100 g xxxxxx.
8. Xxxxxxxx
Xxx xxxxxxx hodnoty xx °X xx xxxxxxxxxxxxxx xxxxxx xxxxxx xx hodnota xxxxxxx x °X xxxx 2,889 (xxxxxxxxxxxxxx xxxxxxx x xxxxx 200 xx; xxxxxxxx xxxxxxx xxxx světelný zdroj; xxxxxxxx xxxxxxxx x xxxxxxxxx, ve xxxxx xx možné xxxxxxxx xxxxxxx xxxxx 20 °X).
XXXXXX 6
XXXXXXXXX XXXXXXXXXXXX XXXXX XXXXXXXXXXX JAKO XXXXXXXX XXXX XXXX XXXXXXXXXX XXXXXXXXXX
(Xxxxxx xxxxx Xxxxx a Xxxxxxxx)
1. Xxxxxxx x xxxxxx xxxxxxx
Xxxxxx slouží ke xxxxxxxxx
1.1 obsahu xxxxxxxxxxxx xxxxx xxxxxxxxxxx xxxx xxxxxxxx xxxx
- v xxxxxxx cukru,
- x xxxxxxx xxxxx xxxxx,
- x tekutém xxxxxxxxx xxxxx,
- x xxxxxxx xxxxx xxxxxxxxx cukru,
- x xxxxxx z xxxxxxxxxx xxxxx,
- v xxxxxx x xxxxxxxxxx xxxxx xxxxxx;
1.2 xxxxxx xxxxxxxxxxxx cukrů xxxxxxxxxxx x xxxxxxxxxxx (xxxxxxxx xx xxxxxx) jako xxxxxxxxxx xxxxxxxxxx
- ve xxxxxxxxx xxxxxx,
- x xxxxxxx škrobovém xxxxxx;
1.3 xxxxxx redukujících cukrů xxxxxxxxxxx jako D-glukosa
- x xxxxxxxx xxxxxxxxxxx,
- x dextrose bezvodé.
2. Xxxxxxxx
„Xxxxxxxxxx cukry xxxxxxxxx xxxx xxxxxxxx xxxxx, X-xxxxxxx xxxx jako xxxxxxxxxx xxxxxxxxxx": xxxxx xxxxxxxxxxxx cukrů vyjádřený xxxx vypočtený jako xxxxxxxx xxxx, Xxxxxxxx xxxx xxxxxxxxxx xxxxxxxxxx xxxxxxxxx xxxxxxxx metodou.
3. Xxxxxxxx xxxxxx
Xxxxxx s xxxxxxxxxxxx cukry xx xxxxxx (x v xxxxxxx xxxxxxx vyčeří) xx xxxxxxxxxxxx xxxxxxxx x xxxx xxxx x roztokem Cu XX, který xx xxxxxxxx xxxxxxxx xx Xx I. Xxxxxxxx Xx XX se xxxx xxxxxxx xxxxxxxxxxxx.
4. Xxxxxxx xxxxxxx
4.1 Xxxxxxxx xxxxxx X: 21,95 x xxxxxx xxxxxxxxxxx xxxxxxxxx, (Xx(XX3XXX)22X2X) nebo 24 g octanu xxxxxxxxxxx xxxxxxxxxx, (Xx(XX3XXX)2-3X2X) xx spolu s xxxxxxxxx 3 xx xxxxxx kyseliny octové xxxxxxxx xx xxxx x doplní vodou xx 100 ml.
4.2 Xxxxxxxx xxxxxx XX: 10,6 g hexakyanoželeznatanu xxxxxxxxxx xxxxxxxxxx (K4[Fe(CN)6]-3H2O) xx rozpustí xx xxxx x xxxxxx xxxxx xx 100 xx.
4.3 Xxxxxxx-Xxxxxxxxxx xxxxxxx: xxxxxxxx se tyto xxxxxxx:
4.3.1 Xxxxxx síranu xxxxxxxxx: 25 g xxxxxx měďnatého xxxxxxxxxxxx (XxXX45X2X) xxxxxxxxxxxxxx železo xx xxxxxxxx xx 100 xx vody.
4.3.2 Xxxxxx xxxxxxxx xxxxxxxxx: 50 x xxxxxxxx xxxxxxxxx monohydrátu (C6H8O7-H2O) xx xxxxxxxx x 50 xx xxxx.
4.3.3 Xxxxxx uhličitanu sodného: 143,8 x xxxxxxxxx xxxxxxxxxx xxxxxxx xx xxxxxxxx xxxxxxxxx x 300 xx horké xxxx a xxxxx xx vychladnout.
4.3.4 X xxxxxxx uhličitanu xxxxxxx (4.3.3) v litrové xxxxxxx xxxxx xx xx mírného promíchávání xxxxxxxxx xxxxxxx xxxxxxx xxxxxx xxxxxxxx xxxxxxxxx (4.3.2). Xxxxx se xxxxx, xxxxx se xxxxxxxxxx xxxxxxx plyn, xxx se přidá xxxxxx xxxxxx xxxxxxxxx (4.3.1) x xxxxx xx xxxxxx xx 1000 xx. Xxxxxx xx xxxxx stát xxxx xxx, x xxxxxxx xxxxxxx se xxxxx xxxxxxxxxxx. Xxxxxxx xx xxxxxxxx xxxxxxxx xxxxxxx xxxxxxx xxxxx xxxxxx popsané x xxxx 6.1 (Xx 0,1 mol/l; Na2CO3 1 mol/l).
4.4 Xxxxxx xxxxxxxxxx, 0,1 mol/l.
4.5 Xxxxxx xxxxxx: xx xxxxxxx xxxxx vroucí xxxx se xxxxxxx 5 x xxxxxxxxxxx xxxxxx xxxxxxxxxxxx xx 30 xx xxxx. Xxxxxx xx 3 xxxxxx a xxxxx xx vychladnout; xx-xx xxxxx, xxxxx xx 10 mg xxxxxx xxxxxxxxxx xxxx xxxxxxxxxxx xxxxxxx.
4.6 Xxxxxxxx xxxxxx, 3 mol/l.
4.7 Roztok xxxxxx xxxxxxxxxx, 30 % (x/X).
4.8 Xxxxxx xxxxx, vyvařené x xxxxxxxx xxxxxxxxxxxxxx, xxxxxxx xxxxx xx vymizení xxxxxx xxxxxx x xxxxxxxx.
4.9 Xxxxxxxxxxx.
4.10 Hydroxid xxxxx, 0,1 xxx/x.
4.11 Xxxxxxxx chlorovodíková, 0,1&xxxx;&xxxx;&xxxx; xxx/x.
4.12 Xxxxxxxxxxx, xxxxxxxxxxxxxx xxxxxx (x/X) v xxxxxxxx.
5. Přístroje a xxxxxxx
5.1 Xxxxxxxxxxxxx baňka, x xxxxxx 300 xx, se xxxxxxx xxxxxxxxx.
5.2 Xxxxxx.
6. Xxxxxx
6.1 Xxxxxxxxx titru Luffova-Schoorlova xxxxxxx (4.3):
6.1.1 Xx 25 xx Xxxxxxx-Xxxxxxxxxx xxxxxxx (4.3) xx xxxxxxx 3 x xxxxxx xxxxxxxxxx x 25 xx xxxxxxxx xxxxxx x koncentraci 3 xxx/x (4.6).
Titruje xx xxxxxxxx xxxxxxxxxx xxxxxxx x xxxxxxxxxxx 0,1 mol/l (4.4) xx xxxxxxx xxxxxxxxxx xxxxxxx (4.5) jako xxxxxxxxxx, xxxxx se xxxxx xx xx xxxxx xxxxxxx. Xxxxx xxxx xxxxxxxx roztoku xxxxxxxxxx o xxxxxxxxxxx 0,1 mol/l xxxxx 25 ml, xxxx xxx xxxxxxx připraveno xxxxx.
6.1.2 Xxxxxxxxxx se 10 xx činidla xx 100xx xxxxxxx xxxxx a po xxxxx se xxxxxx xxxxx.
10 xx xxxxx xxxxxxxxx xxxxxxx xx xxxxxxxxxx xx Xxxxxxxxxxxxx xxxxx obsahující 25 xx xxxxxxxx xxxxxxxxxxxxxx x xxxxxxxxxxx 0,1 xxx/x (4.11) a xxxxxxx se po xxxx xxxxx hodiny xx xxxxxx vodní xxxxx. Pak xx xxxxxx xxxxxxx, xxxxxx xx na původní xxxxx čerstvě xxxxxxxxxx xxxxx x xxxxxxx xxxxxxxx xxxxxxxxx xxxxxxx x koncentraci 0,1 xxx/x (4.10) xx xxxxxxx xxxxxxxxxxxxx (4.12) xxxx indikátoru.
Spotřeba xxxxxxx xxxxxxxxx xxxxxxx, 0,1 xxx/x (4.10) xxxx xxx xxxx 5,5 x 6,5 xx.
6.1.3 10 xx zředěného xxxxxxx (6.1.2) xx xxxxxxx xxxxxxxxx chlorovodíkovou, 0,1 mol/l (4.11) xx xxxxxxx xxxxxxxxxxxxx (4.12) xxxx xxxxxxxxxx. Xxxxxxx xxx xxxxxxx xx charakterizován xxxxxxx xxxxxxxxx xxxxxxxx.
Xxxxxxxx xxxxxxx xxxxxxxx chlorovodíkové, 0,1 xxx/x (4.11) xxxx xxx mezi 6,0 x 7,5 ml.
6.1.4 Xxxxxxx xX Xxxxxxx-Xxxxxxxxxx xxxxxxx xxxx xxx xxxx 9,3 x 9,4 při 20 °X.
6.2 Příprava xxxxxxx
6.2.1 Xxxxxx xx 5 x xxxxxx s xxxxxxxxx xx 1 xx x kvantitativně xx xxxxxxx xx xxxxxxx baňky x xxxxxx 250 xx xxxxxxxxxx 200 xx xxxx. V xxxxxxx xxxxxxx xx xxxxxx xxxxxxxx 5 ml Xxxxxxxxx xxxxxxx X (4.1), xxx se xxxxx 5 xx Xxxxxxxxx xxxxxxx XX (4.2). Xx xxxxxxxx xxxxxxx xxxxxxx xx xxxxx xxxxxxx. Roztok xx doplní xxxxx xx 250 ml x xxxxx promíchá. X xxxxxxx xxxxxxx xx xxxxxx xxxxxxxxxxx.
6.2.2 Xxxxxx (6.2.1) xx xxxxx v xxxxxxx xxxxxx, xxx xxxxx xxxxxxxxxxxx xxxxx xxxxxxxxxxx xxxx xxxxxxx xx x 25 xx xxxxxxx xxxxxxxxx x xxxxxxx 15 xx 60 xx.
6.3 Xxxxxxx xxxxx Luffovy-Schoorlovy xxxxxx
Xx 300 xx Xxxxxxxxxxxxx xxxxx (5.1) xx xxxxxxxxxx 25 xx Xxxxxxx-Xxxxxxxxxx xxxxxxx (4.3), xx baňky se xxx pipetou odměří 25 xx xxxxxxxxx xxxxxxx (6.2.2) x xxxxx xx dva xxxxxx xxxxx (4.8). X xxxxx (5.1) xx xxxxxxx zpětný xxxxxxx x xxxxxxxxx xx xxxxx xxxxxx xx xxxxxxxx xxxxxxxxxx xxxxx xxx plamen Xxxxxxxxx kahanu. Xxxxx xx x azbestové xxxxx vyříznutý xxxxxxx xxxxx x tomtéž xxxxxxx, xxxx xx xxx xxxxx. Xxxxxxxx xx přibližně xxxxx xxxx xxxxx uvede xx xxxx x xxxxx xx xxxxxx 10 xxxxx xxxxx xxxxx. Xxx se xxxxx xxxxxxx xx xxxxxxx xxxx a xx xxxx xxxxxxxx xx titruje podle xxxxxx xxxxxxx:
Xxxxx xx 10 xx roztoku xxxxxx draselného (4.7), xxxxxxxxxxxxx xxxx xx xxxxx opatrně (x xxxxxxx xx bouřlivý xxxxx xxxxx) 25 xx xxxxxxxx xxxxxx x xxxxxxxxxxx 3 xxx/x (4.6). Xxxxxxx xx roztokem xxxxxxxxxx xxxxxxx o xxxxxxxxxxx 0,1 mol/l (4.4), xxxxx xx xxxxxx xxxxx xxxxxxxxx, pak xx přidá xxxx xxxxxxxxx xxxxxxx mililitrů xxxxxxx škrobu (4.5) x xxxxxxxxx xx x titraci xx xx xxxxxxxx modrého xxxxxxxx.
Xxxxxxx xx slepý xxxxx s 25 xx xxxx místo 25 ml xxxxxxxxx xxxxxxx (6.2.2).
7. Xxxxxxxxx xxxxxxxx
7.1 Xxxxxx x xxxxxx xxxxxxx
X xxxx xxxxxxx tabulky se xxxxxx (případně se xxxxxxx xxxxxxxxxxx) xxxxxxxx xxxxxxx xxxx xxxxxxxxxx xxxxx v xx, xxxxxxxxxxxx rozdílu mezi xxxxx xxxxxxxxxx xxxxxxxxxx, xxxxxxxxxxx x xx xxxxxxx xxxxxxxxxx xxxxxxx x koncentraci 0,1 xxx/x.
Xxxxxxxx se xxxxxxx x xxxxxxxxxx (x/x) xxxxxxxxxx xxxxx nebo X-xxxxxxx, xxxxxxxxxx xx xxxxxx.
7.2 Xxxxxxxxxxxxxx
Xxxxxx mezi xxxxxxxx dvou stanovení xxxxxxxxxxx zároveň nebo xxxxxx xx xxxxx x xxxxx vzorku xxxxxx xxxxxxxxxxx za xxxxxxxxx xxxxxxxx xxxxx xxx větší xxx 0,2 xx.
8. Xxxxxxxx
Xxxx xxxxxxxxxx kyselinou xxxxxxx xx xxxx xxxxxx xxxx množství izopentanolu (4.9), xxx se xxxxxxx xxxxxx xxxx.
Xxxxxxx xxxxxx xxx Xxxxxxx – Xxxxxxxxxx činidlo
|
0,1 xxx/x Xx2X2X3 |
Xxxxxxx, xxxxxxxx, xxxxxxxx xxxx C6H12O6 |
|
|
ml |
mg |
rozdíl |
|
1 |
2,4 |
|
|
2 |
4,8 |
2,4 |
|
3 |
7,2 |
2,4 |
|
4 |
9,7 |
2,5 |
|
5 |
12,2 |
2,5 |
|
6 |
14,7 |
2,5 |
|
7 |
17,2 |
2,5 |
|
8 |
19,8 |
2,6 |
|
9 |
22,4 |
2,6 |
|
10 |
25,0 |
2,6 |
|
11 |
27,6 |
2,6 |
|
12 |
30,3 |
2,7 |
|
13 |
33,0 |
2,7 |
|
14 |
35,7 |
2,7 |
|
15 |
38,5 |
2,8 |
|
16 |
41,3 |
2,8 |
|
17 |
44,2 |
2,9 |
|
18 |
47,1 |
2,9 |
|
19 |
50,0 |
2,9 |
|
20 |
53,0 |
3,0 |
|
21 |
56,0 |
3,0 |
|
22 |
59,1 |
3,1 |
|
23 |
62,2 |
3,1 |
METODA 7
XXXXXXXXX REDUKUJÍCÍCH XXXXX XXXXXXXXXXX JAKO INVERTNÍ XXXX
(Xxxxxx xxxxx Xxxxx x Xxxxxx – xxxxxxxxxx s xxxxxxxxxxx xxxxxxx)
1. Předmět x xxxxxx xxxxxxx
Xxxxxx slouží xx xxxxxxxxx xxxxxxxxxxxx xxxxx xxxxxxxxxxx xxxx xxxxxxxx xxxx
- v xxxxxxx xxxxx,
- x xxxxxxx xxxxx xxxxx,
- x xxxxxxx xxxxxxxxx xxxxx,
- x xxxxxxx xxxxx invertním xxxxx,
- x xxxxxx x xxxxxxxxxx xxxxx,
- x xxxxxx x invertního xxxxx xxxxxx.
2. Xxxxxxxx
"Xxxxxxxxxx xxxxx xxxxxxxxx xxxx xxxxxxxx xxxx": xxxxx xxxxxxxxxxxx cukrů stanovený xxxxxxxx metodou.
3. Xxxxxxxx xxxxxx
Xxxxxxxx xxxxxxxxxx xxxxxx xx titruje xx xxxx varu určité xxxxxxxx Xxxxxxxxxx xxxxxxx x použitím xxxxxxxxxxx xxxxx xxxx indikátoru.
4. Xxxxxxx xxxxxxx
4.1 Xxxxxxxxx xxxxxx:
4.1.1 Xxxxxx X:
69,3 x xxxxxx měďnatého xxxxxxxxxxxx (XxXX4·5X2X) se xxxxxxxx xx xxxx x xxxxxx se xx 1000 ml.
4.1.2 Xxxxxx B:
346,0 x xxxxxx xxxxxxxxxxxxxxx tetrahydrátu (XXxX4X4X6·4X2X) x 100 x xxxxxxxxx sodného xx rozpustí xx xxxx a xxxxxx xx 1000 xx. Xxxx roztok xx xxxxxx xxxxxxxxx xx xxxxxxxxx, xxxxx xx xxxx xxxxx xxxxxxxx.
Xxxxxxxx:
Xxxx xxx xxxxxxx xx xxxxx xxxxxxxxx x xxxxxxx nebo jantarově xxxxxxxxxx lahvích.
4.2 Roztok xxxxxxxxx xxxxxxx, 1 xxx/x.
4.3 Xxxxxxxxxx xxxxxx xxxxxxxxxx cukru: 23,750 x xxxxx xxxxxxxxx xx xxxxxxxx asi xx 120 xx xxxx ve 250mililitrové xxxxxxx baňce, přidá xx 9 ml xxxxxxxx chlorovodíkové (hustota 1,16 x/xx) a xxxxx se stát xxx laboratorní teplotě xx dobu 8 xxx. Roztok xx xxxxxx xx 250 xx a xxxxxxxx xxxxxxxxx xx xxxxxxxxxxx xxxxxxxxxxxx xxxx sacharometrem xxxxxx trubice délky 200 xx. Xxxxxxxx xxxxxxx se xx xxxxxx 11,80 ± 0,05 °S (viz xxxxxxxx 8). 200 xx xxxxxx roztoku xx xxxxxxxxxx do 2000xxxxxxxxxxx xxxxxxx baňky, xxxxx xx vodou x za stálého xxxxxxxxxxxx (xxx xxxxxxx x xxxxxxxxxx místnímu xxxxxxxxxxxxx roztoku) se xxxxx 71,4 ml xxxxxxx xxxxxxxxx sodného x xxxxxxxxxxx 1 xxx/x (4.2), xx xxxxxx jsou xxxxxxxxxx 4 x xxxxxxxx xxxxxxxx. Xxxxx xx xxxxxx do 2000 xx, aby xxxxxxxx xxxxxx obsahoval 1 x xxxxxxxxxx xxxxx xx 100 ml. Xxxxxxx xX xxxxxxx xx xxx přibližně xxxxx 3.
Tento xxxxxxxx xxxxxxx xxxxxx xx xx xxx xxxxx xx xxxxx xxxx xxxxxxxx.
Xxx přípravě xxxxxxx xxxxxxxxxx xxxxx x xxxxxxxxxxx 0,25 x/100 xx xx 250xx xxxxxxx baňka xxxxxx xx xxxxx zásobním xxxxxxxx o xxxxxxxxxxx 1 g/100 xx xxx 20 °X. Xxxxx se xxxxxxxxxxxxx xxxxxxx xx 1000 xx odměrné xxxxx x xxxxxx xx xxx 20 °C xx rysku vodou.
4.4 Xxxxxx xxxxxxxxxxx modři, 1 x/100 xx.
5. Xxxxxxxxx a xxxxxxx
5.1 Xxxxx xxxxx x xxxxx hrdlem o xxxxxx 500 xx.
5.2 Xxxxxx x objemu 50 xx, xxxxxx xx 0,05 xx, x postranním xxxxxxxx.
5.3 Xxxxxx x xxxxxxx xx 20, 25 x 50 ml.
5.4 Xxxxxxx xxxxx x xxxxxx 250, 1000 x 2000 xx.
5.5 Xxxxxxxx x xxxxxx, xxxxxx xxx xxxxxxxxx xxxx xx xxxxxxxx xxxxxxxxx x xxxx 6.1 a umožňující xxxxxxxx xxxxxxxx změnu x xxxxxxxx xxxx, xxxx by xx xxxxx xxxxx (5.1) xxxxxx přemístit ze xxxxxx xxxxx.
5.6 Stopky xxxxxxxxx x xxxxxxxxx xxxxxxx xx 1 xxxxxxx.
6. Xxxxxx
6.1 Xxxxxxxxx xxxxx Fehlingova xxxxxxx
6.1.1 Xx xxxxx a xxxxx xxxxxxx xx xxxxxxxxxx 50 xx xxxxxxx B (4.1.2), xxxx 50 ml xxxxxxx X (4.1.1) x dobře xx xxxxxxxx.
6.1.2 Xxxxxx se xxxxxxxxxx x xxxxxx 0,25 % (0,25 x/100 xx) xxxxxxxxxxx xxxxxxxx xxxxxxxxxx xxxxx (4.3).
6.1.3 Do 500 xx xxxxx xxxxx (5.1) se xxxxxxxxxx xxxxxxxxx xxxxx 20 xx xxxxxxxx xxxxxxx X x B (6.1.1) x xxxxxxx xx 15 ml xxxx. X byrety xx xx xxxxx xxxxxx 39 xx xxxxxxx xxxxxxxxxx xxxxx, xxxxx se xxxxxxx xxxxxxx xxxxxxx x xxxxx xx xxxxxx xxxxxxxxx pohybem xxxxxxxx.
6.1.4 Xxxxx baňky se xxxxxxx x xxxx x xxxxx xx xxxxx přesně xxx xxxxxx. Xxxxx xxxxxxx xxxxxxx xx xxxxx xxxxx xxxxxxx xx xxxxxx tepla a xxxxx dojít x xxxxxxxxx varu.
Na konci xxxxxxxxxxxxxx varu se xxxxxxx xxx nebo xxxxx xxxxx xxxxxxx xxxxxxxxxxx modři (4.4). Xxxxx roztoku xxxx xxx xxxxxxx xxxxx.
6.1.5 Xxxxxxxxx se v xxxxxxxxx xxxxxxxxxxxx xxxxxxx xxxxxxxxxx xxxxx x xxxxxx, xxxxxxxx xx 0,2 ml, xxx xx 0,1 xx x xxxxxxx xx xxxxxxx, xx xx xxxxxxx konečného bodu. Xxx xx xxxxxxxxx xxxxxxxxx xxxxxxx xxxxxxxx xxxxxxxx xxxxxxxxxxx xxxxx. Xxxxx xxxxxxx xx xxxxxxxxxxx xxxxxxxxx přítomnosti xxxxxxxx oxidu měďného.
6.1.6 Xxxxxxxxx bodu xxxxxxx xx mělo xxx xxxxxxxx do xxx xxxxx xx xxxxxxx xxxx xxxxxxx. Xxxxxxx xxxxxxxx V0 xx xxxx pohybovat x xxxxxxx 39,0 xx 41,0 xx. Xx-xx xxxxxxx X0 xxxx xxxxxxx xxxxxx rozmezí, xxxxxx se koncentrace xxxx xx Xxxxxxxxxx xxxxxxx X (4.1.1) x xxxxxxxxx xxxxx xx xxxxxxx.
6.2 Xxxxxxxx xxxxxxx xxxxxx
Xxxxxxxxxxx xxxxxxx xxxxxxxxxx xxxxxx se xx xxxxxxxxx x xxxxxxx 250 až 400 xx xxxxxxxxxx xxxxx xx 100 xx.
6.3 Xxxxxxxxxx zkouška
6.3.1 Xx xxxxx xxxxxxx xxxxxxxxxx zkoušku xx xxxxxxxx xxxxxxxxxx xxxxxxxx xxxx k 20 xx xxxxxxxx roztoku X x B, xxxxx xxxxxxx, že xxxxxxx xxxxx xx xxxxxxx xxxx xxxxx 75 ml.
Postupuje xx xxxxxx podle xxxxxx x bodě 6.1.4, xxxxx xxxxx xxxxxxxxxxxx xxxxxxx invertního xxxxx xx xxxxxxx roztok xxxxxx, xx. xx xxxxx se byretou xxxxxx 25 ml xxxxxxx vzorku, xxxxx xx 15 xx xxxx, nechá xx 2 xxxxxx xxxxxxx x xxxxxx xx xxx xxxxxxx xx xx xxxxxxxx xxxxxxxxx xxxx, jak je xxxxxxx x xxxx 6.1.5.
6.3.2 Pokud po xxxxxxxx roztoku xxxxxxxxxxx xxxxx xxxxxxxxx načervenalé xxxxxxxx, xx použitý xxxxxx xxxxxx xxxxxx xxxxxxxxxxxxx. X xxxxx xxxxxxx xx zkouška xxxxxxx x xxxxxxx xx xxxxxxxxx stanovení x xxxxx xxxxxxxxxxx xxxxxxx xxxxxx.
Xx-xx x xxxxxxxx načervenalého xxxxxxxx xxxxxxxxx xxxx xxx 50 ml xxxxxxx xxxxxx, musí se xxxxxx xxxxxx xxxxxx x vyšší koncentrací.
Množství xxxx, xxxxx se xx přidat, xx xxxxxxxx xxxxxxxxx xxxxxx xxxxxxxx Xxxxxxxxxx roztoku (20 ml) x xxxxxx roztoku xxxxxx xx 75 xx.
6.4 Xxxxxxx analýza xxxxxxx xxxxxx
6.4.1 Do varné xxxxx se odpipetuje 20 xx xxxxxxxx Xxxxxxxxxx xxxxxxx a xxxxxxxx xxxx xxxxxxxxx xxxxx xxxx 6.3.
6.4.2 X xxxxxx se xxxxxx roztok vzorku x xxxxxxxx stanoveném xxxxx bodu 6.3, xxxxxxxx x 1 xx. Přidá xx xxxxxxx xxxxxxx kamínků, xxxxx baňky se xxxxxxxxx xxxxxxx xxxxxxxx, xxxxxx x titruje xxxxx xxxxxxxxxxx kroku (6.3). Xxxxxxxxx bodu xxxxxxx musí být xxxxxxxx xxxxx minutu xx přidání xxxxxxx xxxxxxxxxxx xxxxx. Xxxxxxxx xxx xxxxxxx xxxxxxx xx xxxxx X1.
7. Xxxxxxxxx výsledků
7.1 Vzorec x xxxxxx xxxxxxx
Xxxxx xxxxxxxxxxxx xxxxx xx xxxxxx xxxxxxxxx xxxx xxxxxxxx cukr xx xxxxxxxx xxxxx xxxxxx:
xxx:
X = xxxxxxxxxxx xxxxxxx xxxxxxxxxx vzorku (x/100 xx),
X0 = xxxxxxxx xxxxxxxxxxxx roztoku xxxxxxxxxx xxxxx (xx) při xxxxxxxxx titru,
V1 = xxxxxxxx xxxxxxx zkušebního xxxxxx (ml) při xxxxxx analýze (6.4.2),
x = xxxxxxxx faktor xxxxxxxxxxxx koncentraci xxxxxxxxx xxxxxxxx x roztoku xxxxxxxxxx xxxxxx; hodnoty xxxx xxxxxxx v xxxx uvedené xxxxxxx:
|
Xxxxxxxxx (x xx xxxxx xxxxxxx do xxxx) |
Xxxxxxxx xxxxxx f |
|
0,0 |
1,000 |
|
0,5 |
0,982 |
|
1,0 |
0,971 |
|
1,5 |
0,962 |
|
2,0 |
0,954 |
|
2,5 |
0,946 |
|
3,0 |
0,939 |
|
3,5 |
0,932 |
|
4,0 |
0,926 |
|
4,5 |
0,920 |
|
5,0 |
0,915 |
|
5,5 |
0,910 |
|
6,0 |
0,904 |
|
6,5 |
0,898 |
|
7,0 |
0,893 |
|
7,5 |
0,888 |
|
8,0 |
0,883 |
|
8,5 |
0,878 |
|
9,0 |
0,874 |
|
9,5 |
0,869 |
|
10,0 |
0,864 |
Korekce xxx xxxx xxxxxxxx xxxxxxxxx x roztoku xxxxxxxxxx xxxxxx xx xxxxx xxxxxxxxx x tabulkových xxxxxx xxxxxxxxxxx.
Xxxxxxxx:
Xxxxxxxxx xxxxxxxxxxx xxxxxxxxx xx xxxx xxxxxxxx xxxxxxxxx xxxxxxxxxxx xxxxxxxxxxxx xxxxxxx látek x xxxxxxxxxx cukru (xxx xxxxx xxxxxxx xx xxxxxxx xxxxxxx x xxxxx 1,0) xx xxxxxxxxxxx xxxxxxxxx xxxxxxxxxxxx xxxxx vyjádřených xxxx xxxxxxxxx x xxxxxxxxxxx xx xxxxxxx xxxxxx xxxx xxxxx xxxxxx 3 xxxxxx xxxxxxxx.
7.2 Xxxxxxxxxxxxxx
Xxxxxx mezi xxxxxxxx xxxx xxxxxxxxx xxxxxxxxxxx zároveň xxxx xxxxxx xx xxxxx x téhož vzorku xxxxxx xxxxxxxxxxx xx xxxxxxxxx podmínek xxxxx xxx xxxxx než 1,0 % jejich xxxxxxxxxxxxx průměru.
8. Xxxxxxxx
Xxx xxxxxxx xxxxxxx xx °X xx polarimetrické xxxxxx stupně se xxxx xxxxxxx xxxxx x xxxxxxxxxx °X xxxx xxxxxxxx 2,889 (xxxxxxxxxxxxxx trubice x xxxxx 200 mm; xxxxxxxx výbojka xxxx xxxxxxxx zdroj; xxxxxxxx xxxxxxxx v xxxxxxxxx, xx které xx xxxxx udržovat xxxxxxx xxxxxxx 20 °C).
METODA 8
XXXXXXXXX XXXXXXXXXXXX XXXXXXXXXXX
(Xxxxxx xxxxx Lanea a Xxxxxx x xxxxxxxxxxx xxxxxx)
1. Předmět a xxxxxx xxxxxxx
Xxxx xxxxxx xxxxxx ke xxxxxxxxx xxxxxxxxxxxx xxxxxxxxxxx
- xx xxxxxxxxx sirupu,
- v xxxxxxx škrobovém xxxxxx,
- x xxxxxxxx xxxxxxxxxxx,
- x xxxxxxxx xxxxxxx.
2. Xxxxxxxx
2.1 "Xxxxxxxx xxxx": xxxxx redukujících cukrů xxxxxxxxx popsanou xxxxxxx, xxxxxxxxx xxxx xxxxxxx xxxxxxxx (D-glukosa) a xxxxxxxxx v xxxxxxxxxx xxxxxxxxx vzorku.
2.2 "Xxxxxxxxxx xxxxxxxxxx": redukční xxxx xxxxxxxxx x xxxxxxxxxx xxxxxxxxx xxxxxx vzorku.
3. Xxxxxxxx metody
Roztokem xxxxxxxxxx xxxxxx xx xx xxxxxx xxxxxxxx xxxxxxxx xxxxxxx xx xxxx xxxx určitý xxxxx xxxxxxxx Xxxxxxxxxx xxxxxxx x použitím xxxxxxxxxxx xxxxx xxxx indikátoru.
4. Xxxxxxx xxxxxxx
4.1 Xxxxxxxxx xxxxxx:
4.1.1 Roztok X:
Xx xxxx xx xxxxxxxx 69,3 g xxxxxx xxxxxxxxx xxxxxxxxxxxx (XxXX4·5X2X) x x odměrné xxxxx x objemu 1000 xx xx xxxxxx xx rysku.
4.1.2 Xxxxxx X:
Xx xxxx xx rozpustí 346,0 x vinanu xxxxx-xxxxxxxxxx xxxxxxxxxxxx (KNaC4H4O6·4H2O) x 100 x xxxxxxxxx xxxxxxx x x xxxxxxx baňce x xxxxxx 1000 xx xxxxxx xxxxx po xxxxx. Xxxx xxxxxx xx xxxxxxxxx xxxxxx xx usazeniny, která xx může někdy xxxxxxxx.
Xxxxxxxx:
Xxxx xxx roztoky (4.1.1 x 4.1.2) xx xxxxx skladovat x hnědých nebo xxxxxxxxx xxxxxxxxxx xxxxxxx.
4.1.3 Xxxxxxxx směsného Xxxxxxxxxx xxxxxxx
Xx čisté xxxxxxx xx xxxxxxxxxx 50 xx xxxxxxx X (4.1.2) x xxxx 50 xx roztoku X (4.1.1) a xxxxx xx xxxxxxxxxx.
Xxxxxxxx:
Xxxxxx Xxxxxxxxx xxxxxx xx xxxxx xxxxxxxxx, nýbrž xx xxxx xxxxx xxx xxxxxxxxxxx xxxxxxx x xxxxxxxxxxxxxxx (6.1).
4.2 Xxxxxxx xxxxxxxx (X-xxxxxxx) (X6X12X6)
Xxxxx materiál je xxxxx xxxx použitím 4 xxxxxx xxxxx xx vakuové sušárně xxx xxxxxxx 100 ± 1 °X xxxx xxxxx x xxx tlaku xxx 10 kPa (103 xxxx).
4.3 Standardní xxxxxx xxxxxxxx, 0,600 x/100 xx
X přesností xx 0,1 mg se xxxxxx 0,6 x xxxxxxx dextrosy (4.2), xxxxxxxx xx xx xxxx, kvantitativně xxxxxxx xx odměrné xxxxx x objemu 100 xx (5.4), doplní xxxxx xx xxxxx x xxxxxxxx.
Xxxxx roztok xx nutno připravit xxxxxxx xx každý xxx, xxx xxxx xxxxxxxx.
4.4 Xxxxxx xxxxxxxxxxx xxxxx, 0,1 x/100 xx xxxx
Xxxxxxxx se 0,1 x methylenové xxxxx ve 100 xx xxxx.
5. Přístroje x xxxxxxx
5.1 Xxxxx xxxxx x úzkým xxxxxx x objemu 250 xx.
5.2 Xxxxxx x xxxxxx 50 xx, x xxxxxxxxxx xxxxxxxx x xxxxxx xx 0,05 xx.
5.3 Xxxxxx nedělené x xxxxxxx 25 xx x 50 xx.
5.4 Xxxxxxx baňky x xxxxxx 100 a 500 xx.
5.5 Xxxxxxxx x ohřevu, vhodné xxx xxxxxxxxx xxxx x xxxxxxx x xxxxxxxxxx popsanými v xxxx 6.1 x xxxxxxxxxx sledovat xxxxxxxx xxxxx v xxxxxxxx xxxx bez nutnosti xxxxxxx xxxxxx xxxxx (5.1) xx xxxxxx xxxxx (xxx xxx 6.1 poznámka 3).
5.6 Xxxxxx xxxxxxxxx x xxxxxxxxx xxxxxxx na 1 xxxxxxx.
6. Xxxxxx
6.1 Xxxxxxxxxxxxx Fehlingova xxxxxxx
6.1.1 Xx xxxxx xxxxx xxxxx xxxxx (5.1) xx odpipetuje 25 xx Xxxxxxxxxx xxxxxxx (4.1.3).
6.1.2 Xxxxxx (5.2) xx naplní xxxxxxxxxxx xxxxxxxx xxxxxxxx (4.3) x xxxxxxxx xx xxxxxxx xx xxxxxxx xxxxx.
6.1.3 Xx varné xxxxx (5.1) xx x xxxxxx xxxxxxx 18 xx xxxxxxxxxxxx xxxxxxx xxxxxxxx (4.3) x obsah xx xxxxxxxxx pohybem promíchá.
6.1.4 Xxxxx baňka xx xxxxxx xx zařízení x xxxxxx (5.5), xxxxxx nastavené xxx, xxx var nastal xx 120 ± 15 xxxxxx.
X xxxxx xxxxxxx titrace xxxxx xxx xxxxxxxx x xxxxxx xxxxxxxxxxx jinak (xxx poznámka 1).
6.1.5 Xxxxxxx xx xxxxxx xxxxx xxxxx, xxxxxx xx xxxxxx xx xxxx.
6.1.6 Xxxxx xxxxx xx povaří 120 xxxxxx (podle stopek).
Ke xxxxx xx přidá 1 ml roztoku xxxxxxxxxxx xxxxx (4.4).
6.1.7 Xx 120 sekundách (xxxxx stopek) xx xxxxxxx xxxx se xxxxx x byrety (6.1.2) xx xxxxx xxxxx (5.1) xxxxxxxx xxxxxxxxxx xxxxxx xxxxxxxx xx 0,5ml xxxxxxx, xxxxx xx xxxxxxxxxxx xxxx neodbarví (xxx xxxxxxxx 2 a 3).
Xxxxxxxxx se xxxxxxx xxxxx xxxxxxxxx standardního xxxxxxx xxxxxxxx (X xx) včetně xxxxxxxxxxxx 0,5xx dávky.
6.1.8 Kroky x xxxxxx 6.1.1 x 6.1.2 se xxxxxxxx.
6.1.9 X xxxxxx xx xx xxxxx xxxxx (5.1) xxxxxxx (X 0,3) xx xxxxxxxxxxxx roztoku xxxxxxxx.
6.1.10 Xxxxx v xxxxxx 6.1.4, 6.1.5 x 6.1.6 xx xxxxxxxx.
6.1.11 Xx 120 xxxxxxxxx (xxxxx stopek) od xxxxxxx xxxx xx xxxxx x byrety xx varné xxxxx (5.1) xxxxxxxx standardní xxxxxx xxxxxxxx, xxxxxxxx xx 0,2ml xxxxxxx x xxxxxxx xx xxxxxxx, dokud xx xxxxxxxxxxx modř xxxxx xxxxxxxxx.
Xx konci tohoto xxxxxxx xxxx xxx xxxx xxxx xxxxx xx xxxx následujícími xxxxxxxx standardního xxxxxxx xxxxxxxx 10 xx 15 xxxxxx.
Xxxx přidávání xxxx xxx xxxxxxxxx xxxxx 60 xxxxxx x celková doba xxxx xxxx xxxxx xxxxxxxxx 180 xxxxxx.
X xxxxxx účelu může xxx zapotřebí xxxxxxx xxxxx titraci s xxxxxxx větší, xxxxxxxxx xxxxxxxxx xxxxxxxxx xxxxxx xxxxxxxxxxxx xxxxxxx xxxxxxxx (6.1.9).
6.1.12 Xxxxxxxxx se xxxxxxx xxxxxxxx (V0 xx) xxxxxxxxxxxx xxxxxxx xxx xxxxxxxxx xxxxxxx (xxx xxxxxxxx 4).
6.1.13 Xxxxxxx V0 musí xxx x xxxxxxx 19,0 až 21,0 xx xxxxxxxxxxxx roztoku xxxxxxxx (4.3).
Xxxxx xx xxxxxxx X0 xxxxxxx xxxx xxxx xxxxxxx, xxxxxxxxx xx xxxxxx xxxxxxxxxxx Fehlingova xxxxxxx X (4.1.1) a xxxxxxxxxxxxxx xxxxxx se xxxxxxxx.
6.1.14 Xxxxxxxx k xxxx, xx hodnota X0 xx xxxxxx xxxxx, xx třeba xxx xxxxxxxxxx xxxxxxxxxxxxx xxxxxxx xxxxx titraci x xxxxxxxxxx xxxxxxxxx xxxxxxxxxxxx roztoku xxxxxxxx X0 – 0,5.
Poznámka 1:
Xxxxx xx xxxxxxxxx, xx jakmile nastane xxx, vyvíjení páry xx xxxxxx x xxxxxxxxxxx xxxxx xxxx xxxxxxxx procedury a x co xxxxxxxx xxxx xx zabrání xxxxxxxx vzduchu xx xxxxxxxx xxxxx a xxxxxxxx opětovné xxxxxxx xxxxxx xxxxxx.
Xxxxxxxx 2:
Xxxxxxxxx xxxxxxx xxxxxxxxxxx modři xx xxxxxxx pozorovatelné x xxxxxxx xxxxxxxx xxxxxx xxxxxxxx xxxxx x x oblasti xxxxxxx, xx. v xxxxxxx, xxxxx v xxxxxxxx neobsahují xxxxxxx xxxxxxx xxxx měďnatý. Xxxxxxxxx je xxxxxxxx xxxxxxxxxxxxx za xxxxxxxxx xxxxxxxxx. Xx xxxxxxx xxxxxx xxxxxxxx za xxxxxxxx baňkou.
Poznámka 3:
Xxxxxx xx xxxx xxx xxxxx xxxxxxxxx co xxxxxxx xxxxxxxx xxxx xxxxxxx xxxxx.
Xxxxxxxx 4:
Xxxxxxxx x xxxx, xx xxxxx xxxxx xxxxxxxx xxxxxxxxxxx xxxxxx, xxxx xxxxx xxxxxxxxx xxxxxxxx xxxx xxxxxxx xxxxxxxxxxxxxx xxxxxxx x xxx xxxxxxx xxxx xxxxxx xxxx vlastní hodnotu X0 (7.1).
6.2 Xxxxxxxxxx xxxxxxx xxxxxxxxxxxx vzorku
6.2.1 Xxxxx není xxxxx xxxxxxxxx xxxxxxx redukční xxxx (2.1) xxxxxxxxxxxx xxxxxx, xx nutno xxxxxxx xxxxxxxxxx xxxxxxx, xxx se xxxxxxx xxxx xxxxxxxxx xxxxxxx, x mohla xxx xxx vypočtena xxxxxxxx xxxxxxxxxx vzorku (6.3).
Tato xxxxxxx xx xxxxxxx xxxxx:
6.2.2 Xxxxxxxx se X % (x/X) xxxxxx xxxxxx, "X" xx přibližnou hodnotu.
6.2.3 Xxxxxxxxx xx xxxx x xxxx 6.1.2 x použitím roztoku xxxxxx (6.2.2) xxxxxxx xxxxxxxxxxxx xxxxxxx xxxxxxxx.
6.2.4 Xxxxxxxxx xx jako x bodě 6.1.1.
6.2.5 Xxxxxxxxx xx xxxx x xxxx 6.1.3 x použitím 10 xx roztoku vzorku xxxxxxx 18,0 xx xxxxxxxxxxxx xxxxxxx dextrosy.
6.2.6 Xxxxxxxxx xx jako x xxxx 6.1.4.
6.2.7 Xxxxx xxxxx xx xxxxxxx k xxxx. Xxxxx xx 1 xx xxxxxxx methylenové xxxxx (4.4).
6.2.8 Jakmile xxxxxxx var, spustí xx xxxxxx (5.6) xx nuly a xxxxx xxxxxxxxx xxxxxxx xxxxxx z xxxxxx xx xxxxx po 1,0 xx xxxxxxx x xxxxxxxx xxx 10 xxxxxx, x xx až xx xxxxxxxxx xxxxxxxxxxx xxxxx.
Xxxxxxxxx xx xxxxxxx xxxxxxxx xxxxxxxxxxxx xxxxxxx xxxxxxxx (X xx) xxxxxx xxxxxxxxxxxx 0,5 xx xxxxx.
6.2.9 Hodnota "Y" xxxxx xxxxxxxxxx 50 xx. Xxxxx x xxxx xxxxx, xx xxxxx xxxxxx xxxxxxxxxxx xxxxxxx xxxxxx x xxxxxxx xxxxxxxxx.
6.2.10 Xxxxxxxxx xxxxxxx xxxxxxxx xxxx xxxxxxxxxxxx xxxxxx je xxxxxxxxx xxxx xxxxxxx (x %):
6.3 Xxxxxxxx xxxxxx
X xxxxxxxxx xx 0,1 xx xx xxxxxx xxxxxx xxxxxxxx xxxxxxxxxxxx xxxxxx (xx), xxxxx obsahuje 2,85 xx 3,15 x xxxxxxxxxxxx xxxxx xxxxxxxxxxx xxxx xxxxxxx xxxxxxxx (Xxxxxxxx). Xxx xxxxxxx xx použije buď xxxxx xxxxxxxxx hodnota xxxxxxxx xxxx (2.1), xxxx xxxxxxxxx hodnota xxxxxxx x xxxx 6.2.10.
6.4 Zkušební xxxxxx
Xxxxxxxx xxxxxx se x xxxxxxx xxxxx o xxxxxx 500 xx xxxxxxxx ve xxxx x vodou xxxxxx xx xxxxx.
6.5 Xxxxxxxxx
6.5.1 Xxxxxxxxx xx jako x xxxx 6.1.1.
6.5.2 Xxxxxx (5.2) xx xxxxxx xxxxxxxx roztokem (6.4) x meniskus xx xxxxxxx na xxxx.
6.5.3 X xxxxxx xx xx xxxxx xxxxx xxxxxxx 18,5 xx xxxxxxx xxxxxxxxxx xxxxxxx. Vířením se xxxxx baňky xxxxxxx.
6.5.4 Xxxxxxxxx xx xxxx x bodě 6.1.4.
6.5.5 Xxxxxxxxx xx jako x bodě 6.1.5.
6.5.6 Xxxxxxxxx se xxxx x xxxx 6.1.6.
6.5.7 Xxxxxxxxx xx jako x xxxx 6.1.7, x použitím xxxxxxxxxx xxxxxxx namísto standardního xxxxxxx xxxxxxxx.
6.5.8 Xxxxxxxxx xx xxxx x xxxx 6.1.8.
6.5.9 Xxxxxxxxx xx jako x xxxx 6.1.9, x xxxxxxxx xxxxxxxxxx roztoku xxxxxxx standardního xxxxxxx xxxxxxxx.
6.5.10 Xxxxxxxxx se xxxx v xxxx 6.1.10.
6.5.11 Xxxxxxxxx xx xxxx x xxxx 6.1.11, x xxxxxxxx xxxxxxxxxx xxxxxxx namísto xxxxxxxxxxxx roztoku dextrosy.
6.5.12 Xxxxxxxxx se xxxxx (X1) xxxxxxxxxxxxxx xxxxxxxxxx xxxxxxx xxx xxxxxxxxx xxxxxxx.
6.5.13 Xxxxxxx X1 xxxx být x xxxxxxx 19,0 až 21,0 xx xxxxxxxxxx xxxxxxx.
Xxxxx xx xxxxxxx X1 xxxxxxx mimo xxxx xxxxxxx, upraví xx xxxxxxxxxxx xxxxxxxxxx xxxxxxx x xxxxx 6.5.1 xx 6.5.12 xx xxxxxxxx.
6.5.14 Provedou xx xxx stanovení x xxxxxxxx téhož xxxxxxxxxx xxxxxxx.
6.6 Xxxxx xxxxxx
Xxxxxx xxxxxx 2 xx stanoví obsah xxxxxx xxxxxxxxxxxx vzorku.
7. Xxxxxxxxx xxxxxxxx
7.1 Xxxxxx x xxxxxx xxxxxxx
7.1.1 Xxxxxxxx xxxx
Xxxxxxxx xxxx xxxxxxxxx x xxxxxxxxxx xxxxxxxxxxxx připraveného vzorku xx dána xxxxxxx:
xxx
X0 = objem (xx) xxxxxxxxxxxx roztoku xxxxxxxx (4.3) xxxxxxxxxxxx při xxxxxxxxxxxxxx xxxxxxx (6.1),
X1 = xxxxx (ml) xxxxxxxxxx xxxxxxx (6.4) xxxxxxxxxxxxxx xxx xxxxxxx x xxxxxxx stanovení (6.5),
X = hmotnost xxxxxxxxxx vzorku (x) (6.3) xxxxxxxxx x xxxxxxxx 500 ml xxxxxxxxxx roztoku.
7.1.2 Xxxxxxxxxx xxxxxxxxxx
Xxxxxxxxxx xxxxxxxxxx xxxxxxxxx x xxxxxxxxxx xxxxxxxxx xxxxxx xxxxxxxxxxxx xxxxxx xx xxx xxxxxxx:
xxx
XX = xxxxxxxx xxxx xxxxxxxxx v xxxxxxxxxx xxxxxxxxxxxx xxxxxxxxxxxx xxxxxx (7.1.1),
X = xxxxx xxxxxx připraveného xxxxxx x xxxxxxxxxx xxxxxxxxxxxx.
7.1.3 Xxxxxxxxx je aritmetický xxxxxx výsledků dvou xxxxxxxxx xx předpokladu, xx je xxxxxx xxxxxxxxx xxxxxxx xx xxxxxxxxxxxxxx (7.2).
7.2 Xxxxxxxxxxxxxx
Xxxxxx xxxx xxxxxxxx dvou xxxxxxxxx xxxxxxxxxxx xxxxxxx xxxx xxxxxx za xxxxx z xxxxx xxxxxx xxxxxx pracovníkem xx xxxxxxxxx xxxxxxxx xxxxx xxx větší xxx 1,0 % xxxxxx aritmetického xxxxxxx.
XXXXXX 9
XXXXXXXXX XXXXXXXXXX XXXXXX
1. Xxxxxxx a xxxxxx xxxxxxx
Xxxxxx xxxxxx ke xxxxxxxxx obsahu síranového xxxxxx
- xx xxxxxxxxx xxxxxx,
- v xxxxxxx xxxxxxxxx xxxxxx,
- v xxxxxxxx xxxxxxxxxxx,
- v xxxxxxxx xxxxxxx.
2. Definice
"Obsah xxxxxxxxxx xxxxxx": obsah xxxxxxxxxx xxxxxx stanovený xxxxxxxx xxxxxxx.
3. Podstata xxxxxx
Xx xxxxxxxxxx xxxxxxx xxxxxxxxxx vzorku x xxxxxxxx xxxxxxxxx při 525 °C xx xxxxxxxxxxx xxxxxxxx xxxxxx xx xxxxxxxxx xxxx xxxxxxxx xxxxxxxx x xx xxxxxxxxx v xxxxxxxxxx hmotnostních xxxxxx.
4. Xxxxxxx xxxxxxx
4.1 Kyselina xxxxxx, xxxxxxx roztok: xxxxxx a xxxxxxx xx xxxxxxx 100 xx xxxxxxxxxxxxx xxxxxxxx xxxxxx (xxxxxxx při 20 °X = 1,84 x/xx; 96 % x/x) xx 300 ml vody xx xxxxxxxxxx xxxxxxx x chlazení.
5. Xxxxxxxxx x xxxxxxx
5.1 Elektrická xxxxxxx xxx, xxxxxxxx xxxxxxxxxx a xxxxxxxxxx xxxxxx xxx xxxxxxx 525 ± 25 °X.
5.2 Xxxxxxxxxx xxxx, xxxxxx s xxxxxxxxx xx 0,1 mg.
5.3 Xxxxxxx xxx xxxxxxxxx xxxxxx, platinový xx xxxxxxxx, vhodného objemu.
5.4 Xxxxxxxxx xxxxxxxxxx xxxxxxx xxxxxxxxxx xxxxxxxxx xxxx xxxxxxxxxxxx vysoušedlo x xxxxxxxxxxx xxxxxx vlhkosti.
6. Xxxxxx
Xxxxxxx (5.3) xx xxxxxx xx xxxxxxxxxxxx xxxxxxx, xxxxxxx xx x xxxxxxxxxx xxxxxxxxxxx x zváží se. Xx kelímku xx xxxxxx (na 0,1 xx) odváží 5 x škrobového xxxxxx xxxx sušeného xxxxxxxxxx xxxxxx, xxxxxxxx 10 x xxxxxxxx xxxxxxxxxxx xxxx dextrosy xxxxxxx.
Xxxxx xx 5 xx xxxxxxx kyseliny xxxxxx (4.1) (xxx xxxxxxxx 8.1) a xxxxxx xx x xxxxxxx xxxxxxx xxxxxxx xxx xxxxxxxx nebo na xxxxx xxxxxxxx xxx xxxxxx, xxxxx xxxxx xxxxxxxxxxx. Zuhelnatění, xxxxx xxxxx xxxxxxxxxx xxxxxx xx vzorku (viz xxxxxxxx 8.2), xx xxxx provádět v xxxxxxxxx.
Xxxxxxx (5.3) xx xxxxxx xx muflové xxxx (5.1), xxxxxxxxxx xx 525 ± 25 °X, a xxxxxxx se v xx, xxxxx xxxxxxxxx xxxx xxxxx. Xx xxxxxxx xxxx dvě xxxxxx (xxx poznámka 8.3).
Xxxxxx xx xxxxx xxx 30 xxxxx xxxxxxxxxxx v exsikátoru (5.4) x xxxx xx xxxxx.
7. Xxxxxxxxx xxxxxxxx
7.1 Xxxxxx x xxxxxx xxxxxxx
Xxxxx síranového xxxxxx vyjádřený v xxxxxxxxxx xxxxxxxxxxxx vzorku xxxxxxxx k xxxxxxx xx xxx xxxxxxx:
xxx
x1 = xxxxxxxx xxxxxx (x),
x0 = xxxxxxxx xxxxxxx xxxxxxxxxx vzorku (x).
7.2 Xxxxxxxxxxxxxx
Xxxxxx xxxx xxxxxxxx xxxx xxxxxxxxx xxxxxxxxxxx xxxxxxx xxxx xxxxxx xx xxxxx x xxxxx xxxxxx xxxxxx xxxxxxxxxxx xx xxxxxxxxx xxxxxxxx xxxxx xxx xxxxx xxx 2,0 % jejich xxxxxxxxxxxxx průměru.
8. Xxxxxxxx
8.1 Xxxxxxxx xxxxxx se xxxxxxx xx malých xxxxxxx, aby xx xxxxxxxxx přílišnému xxxxxx.
8.2 Xxx prvním xxxxxxxxxxx xx xxxxx postupovat xxxxxxxx xxxxxxxxx, xxx xxxxxxx xx ztrátám xxxxxx nebo xxxxxx xxxxx přílišnému bobtnání xxxxxx.
8.3 Xxxxx xx xxxxxxx xxxxxxxxx xxxxxxx xxxxxxxxxx (xx. xxxxxxxxx xxxxx xxxxxxx), xxxxxxx xx třeba z xxxxxxx pece xxxxxxx, xxxxxx xx ochlazení xxxxxxx několika xxxxxxx xxxx a xxxx xxxxxx do xxxx.
XXXXXX 10
XXXXXXXXX XXXXXXXXXX
1. Xxxxxxx x xxxxxx použití
Metoda xxxxxx xx xxxxxxxxx xxxxxxxxxx
- x xxxxx xxxxxxxxx,
- v cukru xxxx x cukru xxxxx,
- v cukru xxxxx xxxxx.
2. Definice
Polarizací xx xxxxxx schopnost xxxxxxxxx xxxxxxx obsahujícího 26 x cukru xx 100 xx, xxxxx xx xxxxxxx x xxxxxxx o xxxxx 200 mm, xxxxxx xxxxxx xxxxxxxxxxxxxx xxxxxx.
3. Podstata xxxxxx
Xxxxxxxxxx xx xxxxxxx xxxxxx xxxxxxxxxxxx nebo xxxxxxxxxxx xx podmínek xxxxxxxxx x níže xxxxxxx xxxxxx.
4. Xxxxxxx xxxxxxx
4.1 Xxxxxx činidlo: xxxxxxx xxxxxx xxxxxx olovnatého.
Do xxx 1000 xx xxxxxxx xxxxxxxxx xxxx xx xxxxx 560 x xxxxxxx xxxxxxxxx xxxxxx xxxxxxxxxx. Xxxx xx 30 minut xxxx x poté xx xxxxx xxxx xxxx xxx.
Xxxxxx xxxxxxxxxxx xx dekantuje a xxxxx xxxxxxx xxxxxxxxxx xxxxx xxx, xxx xxxxxx roztok o xxxxxxx 1,25 x/xx (xxx 20 °C).
Tento xxxxxx je xxxxx xxxxxxx xxxx xxxxxxxxx xxxxxxx.
4.2 Xxxxxxxxxxxx
5. Xxxxxxxxx x xxxxxxx
5.1 Sacharimetr xxxxxxxxxxxx na normální xxxxxxxx 26 x xxxxxxxxx, xxxxxxxxx xxxxxxxxxx
Xxxxx xxxxxxxx musí xxx xxxxxxx x místnosti, xx xxxxx xx xxxxx xxxxxxxx xxxxxxx xxxxx 20 °C. Xxxxxxxx se xxxxxxxxxx xxxxxx standardních xxxxxxxxxx xxxxx.
5.2 Xxxxxxxx xxxxx xxxxxxxxxxx xx xxxxxxxx xxxxxxx.
5.3 Přesné polarimetrické xxxxxxx x xxxxx 200 xx s xxxxxxxxx ± 0,02 xx.
5.4 Xxxxxxxxxx xxxx, xxxxxx x xxxxxxxxx xx 0,1 xx.
5.5 Xxxxxxxxxx kalibrované odměrné xxxxx x objemu 100 xx xx xxxxxxx. Xxxxx xx xxxxxxxxx xxxxxxx x xxxxxxx 100,00 ± 0,01 xx xxxxx xxx xxxxxxx bez xxxxxxx. Baňky x xxxxxxx xxxx uvedené xxxxxxx mohou být xxxxxxx xxxxx x xxxxxxxxx korekcí xx 100 ml.
5.6 Vodní xxxxx xxxxxx xxxxxxxxxxx, xxxxxxxxx na 20 ± 0,1 °X.
6. Xxxxxx
6.1 Xxxxxxxx roztoku
Co xxxxxxxxxxx se xxxxxx 26 ± 0,002 x xxxxxx x xxxxxxxxxxxxx xx xxxxxxx xx odměrné xxxxx x xxxxxx 100 xx (5.5) xxxxxxxxxx xxx 60 xx xxxx.
Xxxxxx xx xxxxxxxx xxxxxxx, xxxxxx však xxxxxxxxxx.
Xxxxx xx xxxxx xxxxxx xxxxxxx, xxxxx xx 0,5 ml xxxxxxx xxxxxx xxxxxxxxxx (4.1).
Xxxxxx se míchá xxxxxxxxx pohybem xxxxx x xxxxx baňky xx xxxxxxxxx xxx xxxxxx, xxxxx meniskus xxxxxxxxxx xxx 10 xx xxx kalibrační xxxxx.
Xxxxx se xxxxxx xx xxxxx xxxxx (5.6) xxxxxxxxxx při 20 ± 0,1 °X x xxxxxxx xx xxx tak xxxxxx, xxxxx xx xxxxxxx xxxxxxxxx roztoku xxxxxxxx.
Xxxxxxx xxxxxxx vytvořené xx povrchu xxxxxxxx xx xxxxxxxx xxxxxx xxxxxxxxxxxxx (4.2).
Xxxxxx xx xxxxxx vodou xx xxxxx.
Xxxxx se xxxxxxxxx x řádně se xxxxxxxx alespoň trojnásobným xxxxxxxxx dnem xxxxxx.
Xxxxx xx xxxxx pět xxxxx stát.
6.2 Stanovení xxxxxxxxxx
Xx dobu všech xxxx xxxxxxxxx xxxxx xx xxxxxxx xxxxxxx 20 ± 0,1 °X.
6.2.1 Xxxxxxxxxx xx xxxxxxx xx nulu.
6.2.2 Xxxxxx se přefiltruje xxxx xxxxxxxxx xxxxx. Xxxxxxx 10 ml xxxxxxxx xx xxxxxxxxx. Xxxx xx xx xxxxxxx 50 xx xxxxxxxx.
6.2.3 Polarimetrická trubice xx promyje dvojnásobným xxxxxxxxxxxxx roztokem xxxxxx xxxxxxxx k xxxxxxx (6.2.2).
6.2.4 Trubice xx xxx xxxxxxx 20 ± 0,1 °X xxxxxxx naplní xxxxxxxx xxxxxx xxxxxxxx x xxxxxxx.
Xxx xxxxxxxxx xxxxxxxxx xxxxxxxx xx xxxxxxxx xxxxxxx vzduchové xxxxxxx. Xxxxxxxx xxxxxxx se xxxxxx xx kolébky xxxxxxxxx.
6.2.5 Xxxxxx xx xxxxxxxxxx s přesností xx 0,05°S xxxx 0,02 xxxxxxxx xxxxxx. Xxxxx se zopakuje xxxxx xxxxxxxxx. Xxxxxxx xx xxxxxx x xxxxxx xxxx xxxxxx.
7. Xxxxxxxxx xxxxxxxx
7.1 Vzorec x xxxxxx výpočtu
Výsledky xxxx xxxxxxxxx xx xxxxxxxx X s xxxxxxxxx xx 0,1°S. Xxx xxxxxx xxxxxxxx xxxxxx xx xxxxxx X xx xxxxxxx xxxxx vzorec:
S = xxxxxx xxxxxx × 2,889
7.2 Opakovatelnost
Rozdíl xxxx xxxxxxxx xxxx xxxxxxxxx xxxxxxxxxxx xxxxxxx xxxx xxxxxx xx sebou x xxxxx xxxxxx xxxxxx xxxxxxxxxxx xx xxxxxxxxx xxxxxxxx nesmí xxx větší xxx 0,1°X, přičemž xxxxxxxx xxxxxxx xxxxxxxxx xx xxxxxxxx x xxxx xxxxxx.