Xxxxx směrnice Komise
ze xxx 26. xxxxxxxx 1979,
xxxxxx xx xxxxxxx xxxxxxxxxx xxxxxx Společenství xxx zkoušení xxxxxxxxx xxxxx xxxxxxxx x xxxxxx spotřebě
(79/796/EHS)
KOMISE XXXXXXXXXX XXXXXXXXXXXX,
x xxxxxxx na Xxxxxxx x xxxxxxxx Xxxxxxxxxx xxxxxxxxxxxxx xxxxxxxxxxxx,
x xxxxxxx xx xxxxxxxx Xxxx 73/437/XXX xx xxx 11. xxxxxxxx 1973 x xxxxxxxxxx xxxxxxxx xxxxxxxx členských xxxxx xxxxxxxxxx xx xxxxxxxxx cukrů xxxxxxxx x lidské xxxxxxxx [1], x zejména xx článek 11 xxxxxxx xxxxxxxx,
xxxxxxxx x xxxx, xx článek 11 xxxxxxx xxxxxxxx xxxxxxx, xx složení xxxxxxxxx cukrů xx xxxxxxx analytickými xxxxxxxx Xxxxxxxxxxxx;
xxxxxxxx x xxxx, xx xx vhodné xxxxxxxx xxxxxxxxx řadu xxxxx, xxxxxxx studium xxx bylo ukončeno;
vzhledem x xxxx, xx x xxxxxxx xxxxxxxx 73/437/XXX je stanovena xxxxxx xxx xxxxxxxxx xxxxx x xxxxx xxxx xxxxxx cukru x xxxxx extra xxxxxx, xxxxxx xxxxxxxxx xxxxxx xxxxxxxxxxxxxxxx x xxxxx xxxxx bílého, xxxxxxxx xxxxx, xxxxxxxx xxxxxxxxxx xxxxx x xxxxxx z xxxxxxxxxx xxxxx x xxxxxx xxxxxxxxx xxxxx x xxxxxxx cukru xxxxx xxxxxx x xxxxxxxx xxxxx;
xxxxxxxx k xxxx, xx by xx xxxxx straně xxxx xxxxxx až xx xxxxxxxxxxx xxxxxxx xxxxx Xxxxxxxxxxxx xxx xxxxxxxxx xxxxxxxxxxxx cukrů ponechat xxxxxxxx xxxxxx možnost xxxxxxxx x nadále xxxxxx podle Xxxxx x Eynona (metody 7 x 8 x xxxxxxx XX x. III.3 x XXX.4) místo metody xxxxx Xxxxx a Xxxxxxxx (xxxxxx 6 x xxxxxxx XX x. III.3 x XXX.4);
xxxxxxxx x xxxx, xx analytické xxxxxx xxxxxxxx x této xxxxxxxx xxxx x xxxxxxx se xxxxxxxxxxx Xxxxxxx výboru pro xxxxxxxxx,
XXXXXXX TUTO XXXXXXXX:
Xxxxxx 1
1. Členské xxxxx xxxxxxx, xx xxxxxxx xxxxxxxx x xxxxxxx xxxxxxxx xxxxxxxxx x příloze X xxxx xxx xxxxxxxxx xxxxx metod popsaných x xxxxxxx II xxxx xxxxxxxx.
2. Xxxx xx dotčen xxxxx xxxxxxxxxxx, xxxxxxx xx xxxxxx xxxxx Luffa x Xxxxxxxx (xxxxxxx XX, metoda 6) xx xxxxxxxxx redukujících xxxxx xxxxxxxxxx
- v xxxxxxx cukru,
- v xxxxxxx bílém xxxxx,
- x xxxxxxx xxxxxxxxx xxxxx,
- x xxxxxxx xxxxx invertním xxxxx,
- x xxxxxx z xxxxxxxxxx xxxxx,
- xx xxxxxxxxx xxxxxx,
- x xxxxxxx xxxxxxxxx xxxxxx,
- x xxxxxxxx monohydrátu,
- x xxxxxxxx xxxxxxx.
Xxxxxxx xxxxx však xxxxx xx xxxx území xxxxxxxx ke xxxxxxxxx xxxxxxxxxxxx cukrů x xxxxxx xxxx xxxx xxxxxxx xxxxx xxxxxxxxx x předchozím xxxxxxx xxxxxx xxxxx Xxxxx x Eynona (příloha XX, metoda 7 xxxx 8).
3. Xxxxx xxxxxxx xxxx xxxxxxx xxxxxxx xxxxx xxxxxxxx x xxxx. 2 xxxxxx pododstavci, xxxxxxxxxx x tom xxxxxxx Xxxxxx x xxxxxxx xxxxxxx státy.
Xxxxxx 2
Členské státy xxxxxx x xxxxxxxx xxxxxx a xxxxxxx xxxxxxxx xxxxxxxx xxx xxxxxxxx xxxxxxx s xxxxx xxxxxxxx do 18 xxxxxx xx xxxxxxxx xxxx xxxxxxxx. Xxxxxxxxxx x xxxx xxxxxxx Xxxxxx.
Xxxxxx 3
Xxxx xxxxxxxx xx xxxxxx xxxxxxxx xxxxxx.
V Bruselu dne 26. xxxxxxxx 1979.
Xx Xxxxxx
Xxxxxxx Davignon
člen Xxxxxx
[1] Xx. věst. X 356, 27.12.1973, x. 71.
PŘÍLOHA I
ROZSAH POUŽITÍ XXXXXXXXXXXX XXXXX XXXXXXXXXXXX XXX NĚKTERÉ XXXXX XXXXXX X XXXXXX XXXXXXXX
XXXXXXX XX
XXXXXXXXXX XXXXXX X OVĚŘENÍ XXXXXXX XXXXXXXXX XXXXX XXXXXXXX X XXXXXX SPOTŘEBĚ
ÚVOD
1. Xxxxxxxx xxxxxx k xxxxxxx
Xxxxxx doručený xx xxxxxxxxxx se xxxxxxxx xxxxxxxx.
Xxx xxxxxxx xx xx vzorku oddělí xxxxxxxx xxxxxxx 200 x x okamžitě xxxxxxx xx xxxxx, xxxxx, xxxxxxxxx xxxxxxx xxxxxxxx xxxxxxxxxxxxx xxxxxxxx.
2. Xxxxxxx xxxxxxx, xxxxxxxxx x pomůcky
Při xxxxxx xxxxxxxxx x xxxxxxx xxxx xxxxxxx xxxxxx xxxxx v xxxxxxx xxxxxxxxxxx xxxxxxxx x xxxxxxxxx, xxxx xxxx xxxxxxxxx, které xxxx xxxxxxxxx xxxxxxxxx xxxxxxxxxx.
Xxxxx xx zmiňována xxxx, xxxxxx xx xxxxxxxxxxx xxxx xxxx xxxxxxxxxxxxxxxx xxxx x alespoň xxxxxxxxxxxx čistotou.
Veškerá činidla xxxx být analytické xxxxxxx, pokud není xxxxxxxxx jinak.
Pokud xx xxxxxxxxxx na roztok xxxxxxx xxx xxxxxxx xxxxxxxxx, jedná se x xxxxx xxxxxx.
3. Xxxxxxxxx xxxxxxxx
X úředním xxxxxxxxx x xxxxxxx xx uvede xxxxxxxx xxxxxxx jako xxxxxxxx xxxxxxx xx xxxx xxxxxxxxx x uspokojivou xxxxxxxxxxxxxxx.
Xxxxx xxxx uvedeno xxxxx, xxxx výsledky xxxxxxxxx x xxxxxxxxxx xxxxxxxxxxxx xxxxxxxxx laboratorního xxxxxx xxx, xxx xxx xx xxxxxxxxxx xxxxxxx.
Xxxxx platných xxxxxx x takto xxxxxxxxxx xxxxxxxx je určen xxxxxxxxx metody.
METODA 1
XXXXXXXXX XXXXXX HMOTNOSTI XXXXXXX
1. Xxxxxxx a oblast xxxxxxx
Xxxxxx slouží ke xxxxxxxxx xxxxxx hmotnosti xxxxxxx
- v xxxxx xxxxxxxxx,
- v cukru xxxx x xxxxx xxxxx,
- v xxxxx xxxxx xxxxx.
2. Xxxxxxxx
"Xxxxxx xxxxxxxxx xxxxxxx": xxxxxxx xxxxxx xxxxxxxxx xxxxxxx xxxxxxxxx popsanou metodou.
3. Xxxxxxxx xxxxxx
Xxxxxx xxxxxxxxx xxxxxxx se xxxxxxx xxxxxxx při teplotě 103 ± 2 °X.
4. Xxxxxxxxx a xxxxxxx
4.1 Analytické xxxx xxxxxx x xxxxxxxxx 0,1 xx.
4.2 Sušárna x xxxxxxx xxxxxxxxx, xxxxxx xxxxxxxxxxx, xxxxxxxxxx xxxxxxxx xxxxxxx 103 ± 2 °X.
4.3 Xxxxxx xxxxxxx x xxxxxxx xxxx, odolná xxxx xxxxxxxx xxxxxx x xxxxxxxxxx xxxxxxxxx, x průměrem xxxxxxx 100 mm a x xxxxxxxx xxxxxxx 30 xx.
4.4 Exsikátor x xxxxxxx aktivovaným xxxxxxxxxxx xxxx x xxxxxxxxxxx xxxxxxxx s xxxxxxxxxxx xxxxxx xxxxxxxx.
5. Xxxxxx
Xxxxxxxx:
Xxxxxxx xxxxxxx x xxxxxx 5.3 až 5.7 xxxx xxx xxxxxxxxx okamžitě xx xxxxxxxx xxxxxx xx xxxxxxx.
5.1 Xxxxx (4.3) xx xxxxxx xx xxxxxxxxxx xxxxxxxxx x xxxxxxx (4.2) při xxxxxxx 103 ± 2 °C.
5.2 Xxxxx xx xxxxx x xxxxxxxxxx (4.4) xxxxxxxxxxx xxxxxxx xx xxxx 30 xx 35 xxxxx x poté xx zváží x xxxxxxxxx na 0,1 xx.
5.3 Xx xxxxx xx xxxxxx xxxxxxxxx 20 až 30 x vzorku s xxxxxxxxx xx 0,1 xx.
5.4 Xxxxx se xxxxx xx sušárny (4.2) x xxxxxxx 103 ± 2 °X, xxx xx xxxxxxx 3 xxxxxx.
5.5 Xxxxx se xxxxx xxxxxxxxxxx x xxxxxxxxxx (4.4) a xxxxx xx x xxxxxxxxx xx 0,1 xx.
5.6 Xxxxx se xxxxx xxxxx xx 30 xxxxx do sušárny x xxxxxxx 103 ± 2 °X.
Xxxxx xx xxxxxxxxxxx v xxxxxxxxxx (4.4) a xxxxx xx s xxxxxxxxx na 0,1 xx. Xxxxx xx xxxxxx mezi xxxxx xxxxxxxx xxxxx než 1 mg, xxxxxx xx opakuje. Dojde-li xx xxxxxxx xxxxxxxxx, xxxxxxx se x xxxxxxx xxxxxxxx xxxxxxxxxxx xxxxxxx.
5.7 Xxxxxxx xxx xxxxxx xxxxx být xxxxx xxx xxxxx xxxxxx.
6. Xxxxxxxxx xxxxxxxx
6.1 Xxxxxx x xxxxxx xxxxxxx
Xxxxxx hmotnosti sušením x xxxxxxxxxx hmotnostních xxxxxx xx xxxx xxxxx xxxxxxx:
xxx:
x0 je xxxxxxxxx xxxxxxxx zkušebního xxxxxx (x),
x1 xx xxxxxxxx xxxxxxxxxx xxxxxx xx vysušení (g).
6.2 Xxxxxxxxxxxxxx
Xxxxxx xxxx xxxxxxxx xxxx xxxxxxxxx xxxxxxxxxxx xxxxxxx nebo xxxxxx xx sebou x xxxxx vzorku xxxxxx xxxxxxxxxxx xx xxxxxxxxx xxxxxxxx xxxxx být xxxxx xxx 0,02 x xx 100 x xxxxxx.
XXXXXX 2
XXXXXXXXX XXXXXX
Xxxxxx xxxxxx ve xxxxxxx xxxxxxx
1. Předmět x xxxxxx použití
Metoda xxxxxx ke stanovení xxxxxx xxxxxx
- ve xxxxxxxxx xxxxxx,
- x xxxxxxx xxxxxxxxx xxxxxx,
- x xxxxxxxx xxxxxxxxxxx,
- x xxxxxxxx bezvodé.
2. Xxxxxxxx
"Xxxxx sušiny": xxxxx xxxxxx xxxxxxxxx xxxxxxxx xxxxxxx.
3. Xxxxxxxx metody
Sušina xx xxxxxxx xxx xxxxxxx 70 ± 1 °X ve xxxxxxx xxxxxxx při xxxxx xxxxxxx 3,3 xXx (34 mbar). Xxxxxxxx vzorky škrobového xxxxxx xxxx sušeného xxxxxxxxxx xxxxxx xx xxxx xxxxxxx xxxxxx xxxxxxxxx x vodou x x xxxxxxxxxx.
4. Xxxxxxx xxxxxxx
4.1 Xxxxxxxxx: xxxxxxxx xx x Xüxxxxxxxx xxxxxxx xxxxxxxxxx xxxxxxxxxx zředěnou xxxxxxxxx xxxxxxxxxxxxxxx (1 xx xxxxxxxxxxxxx xxxxxxxx x xxxxxxx 1,19 g/ml xx litr xxxx xxx 20 °X), xxxxx filtrát xxxxxxxxxx xxxxxxxx xxxxxxx xxxxxx. Xxxxxxxxx na xxxxxx xx pak xxxxxxx xxxxx tak dlouho, xxxxx xxxxxxx xX xxxxxxxx nevystoupí xxx 4; xxx se xxxxxxxxx xxxxxx x xxxxxxx xxx 103 ± 2 °X x xxxxx se xx xxxxxxxxxxxxxx xxxxxx.
5. Xxxxxxxxx x xxxxxxx
5.1 Xxxxxxx sušárna, xxxxxxxx, xxxxxx xxxxxxxxxxx, xxxxxxxx xxxxxxxxxx a xxxxxxxx xxxxxxxxxx. Xxxx xxx xxxxxxxxxxxx xxx, aby xxx xxxxxxxx xxxxxx xxxxxxx xxxxx xx xxxxxxx uložených na xxxxxxxx.
5.2 Aparatura x xxxxxxxxx xxxxxxx skládající xx xx xxxxxxxx xxxxxx naplněné xxxxxxx xxxxxxxxxxx xxxxxxxxxxx nebo xxxxxxxxxxx xxxxxxxxxxx, x xxxxxxxxxxx obsahu xxxxxxxx. Xxxx xxxxxx xxxxxxxxxx xxxxxxxxxxxxxx kyselinu sírovou xx sériově propojena x pračkou xxxxx xxxxxxxxxx xx vstup xxxxxxx xx xxxxxxx.
5.3 Xxxxxx umožňující xxxxxxxx x sušárně xxxx 3,3 xXx (34 xxxx) nebo xxxxx.
5.4 Xxxxxx xxxxxxx s xxxxxxx xxxx xxxxxx xxxx xxxxxxxx xxxxxx x xxxxxxxxx xxxxxxx x xxxxxxxx nejméně 100 mm x x xxxxxxxx xxxxxxx 300 mm.
5.5 Xxxxxxxx xxxxxxx x xxxxxx xxxxx, xxx xxxxxxx xxxxx xxxxxxxxx xx xxxxxxx.
5.6 Exsikátor s xxxxxxx xxxxxxxxxxx xxxxxxxxxxx xxxx x xxxxxxxxxxx xxxxxxxxxxx x xxxxxxxxxxx xxxxxx xxxxxxxx.
5.7 Xxxxxxxxxx xxxx xxxxxx s xxxxxxxxx na 0,1 xx.
6. Postup
6.1 Xx xxxxxxx (5.4) xx xxxxxxxxx xxxxxxxx (5.5) xx xxxxxxx xxxxxxxxx 30 x xxxxxxxxx (4.1), xxx xxxxx xx xx sušárny (5.1) x xxxxxxxx 70 ± 1 °X a xxxx xx sníží xxxxxxx xx 3,3 xXx (34 mbar).
Suší se xxx dobu nejméně 5 hodin, xxxxxxx xx xxxx aparaturu xxx vysoušení xxxxxxx xx sušárny xxxxxx xxxxxx xxxxx xxxxxxx. Xxxxx xx zkontroluje xxxx a xxxxx xxxxxxx xx upraví.
6.2 Xxxxxxxxxx xxxxxxxx xxxxxxxxxxxxxx xxxxx x xxxxxxx xx xxxxxxx xxxxxxxx xxxxxxxx xxxxxxx xxxxxxx xxxxxxx. Miska x xx skleněnou tyčinkou xx okamžitě xxxxxxxx xx xxxxxxxxxx (5.6), xxx xx nechá xxxxxxxxxxx, a xxx xx zváží.
6.3 Xx xxxxxxx x obsahu 100 xx xx x xxxxxxxxx na 1 xx xxxxxx xxxxxxxxx 10 x xxxxxxxxxxxxx xxxxxx.
6.4 Zkušební xxxxxx xx xxxxx 10 ml teplé xxxx a roztok xx pomocí skleněné xxxxxxx (5.5) xxxxxxxxxxxxx xxxxxxx xx xxxxxxx.
6.5 Xxxxx xx zkušebním xxxxxxx x xxxxxxxxx xxxxxxxx xx vloží xx xxxxxxx a xxxx xx xxxxx xxxxxxx xx 3,3 xXx (34 xxxx). Xxxx se při 70 ± 1 °X, xxxxxxx xx xxxxxxxx nechá procházet xxxxxx proud suchého xxxxxxx.
Xxxxxx xx xxxxxxx xx xxxx 20 xxxxx; x xxxxxxxxxx xxxxxx xxxxxxxx xx xxxxx xx xxxxx xxxxxxx dne. Xx xxxxxxxx xxxxxxxx vývěvu x xxxxx xxx xxxxxxxxxx xxxxx a xxxxxx xxxxxx proudit xx sušárny xxxxx xxxxxx tak, xxx xx během xxxx xxxx udržoval xxxxxxxxx xx xxxxxxx 3,3 xXx (34 xxxx) xxxx xxxxx.
6.6 Atmosférického xxxxx x sušárně xx xxxx xxxxxxx xxxxxxxx zvýšením přívodu xxxxxxx vzduchu. Váženka x x xxxxxxx xx xxxxxxxx xxxxxxxx xx xxxxxxxxxx, xxx xx nechá xxxxxxxxxxx, x poté xx xxxxx x přesností xx 1 mg.
6.7 Xxxxxxx (6.5) xx xxxxxxx xx další 4 xxxxxx. V xxxxxxx xx xxxxxx xxxxxxxxxxxx xxxx x xxxxx xx ihned xxxxx do exsikátoru. Xxxxx xx xxxxxxxxxxx x vážením se xxxxxx, xxx xxx xxxx dosaženo xxxxxxxxxx xxxxxxxxx. Za xxxxxxxxxx xxxxxxxx xx považuje xxxxxx výsledek, xxx xxxxxx xxxx xxxxx xxxxxxxx xxxx misky xxxx xxxxx než 2 mg. V xxxxxxx případě se xxxxxxx xxxxxxx 6.7.
6.8 Xxx xxxxxxxxx xxxxxx xx vzorcích bezvodé xxxxxxxx xxxx x xxxxxxxxxxx xxxxxxxx xxxx xxxxxxx xxxxxxxxx x xxxx xxxxxxxxx.
7. Vyjádření xxxxxxxx
7.1 Xxxxxx x xxxxxx xxxxxxx
Xxxxx xxxxxx xxxxxxxxx v procentech xxxxxxxxxxxx xxxxxx xx xxxxxxxx xxxxx xxxxxx xxxxxx:
xxx:
x0 = je xxxxxxxxx xxxxxxxx xxxxxxxxxx xxxxxx (g),
m1 = xx xxxxxxxx váženky x křemelinou, xxxxxxxxx xxxxxxxx x xxxxxxx xxxxxxxxxx xxxxxx po xxxxxx (g),
m2 = xx xxxxxxxx xxxxxxx x xxxxxxxxxx a xxxxxxxxx tyčinkou (x).
7.2 Xxxxxxxxxxxxxx
Xxxxxx xxxx výsledky xxxx xxxxxxxxx xxxxxxxxxxx xxxxxxx nebo xxxxxx xx xxxxx x xxxxx vzorku xxxxxx xxxxxxxxxxx xx xxxxxxxxx xxxxxxxx nesmí xxx xxxxx xxx 0,12 x xx 100 x xxxxxx.
XXXXXX 3
STANOVENÍ XXXXXXX XXXXXX
(Xxxxxxxxxxxxxxxx xxxxxx)
1. Xxxxxxx x xxxxxx xxxxxxx
Xxxxxx xxxxxxx obsah xxxxxx
- v xxxxxxx xxxxx,
- v xxxxxxx xxxxx cukru,
- x xxxxxxx xxxxxxxxx xxxxx,
- x tekutém xxxxx xxxxxxxxx cukru,
- x xxxxxx z invertního xxxxx,
- x sirupu x xxxxxx xxxxxxxxxx xxxxx.
2. Xxxxxxxx
"Xxxxx xxxxxx": xxxxx xxxxxx stanovený xxxxxxxx xxxxxxx.
3. Podstata xxxxxx
Xxxxxxx xx index xxxx zkušebního xxxxxx xxx 20 °X x xxxxx xxxxxxx xxxxxxxxxxx xxxxxxxxxxx jako xxxxxx indexu xxxx xx xxxxxxx xx xxxxx xxxxxx.
4. Přístroje x xxxxxxx
4.1 Xxxxxxxxxxxx x přesností xxxxxx xx xxxxx desetinná xxxxx, xxxxxxxx xxxxxxxxxx x xxxxxxxx vodním xxxxxxxxx xxxxxxxxxx x xxxxx xxxxx, xxxxx xx xxxxxxxxx xxxxxxxxxxx xx xxxxxxx 20 ± 0,5 °X.
4.2 Xxxxxxxx xxxxx xxxxxxxxxxx xx sodíkové xxxxxxx.
5. Xxxxxx
5.1 Xxxxx xxxx xx xxxxxx přítomny xxxxxxxx, rozpustí xx xxxxxxxx xxxxxx v xxxxxx 1:1 (m/m).
5.2 Xxxxxxxxxxxxxx (4.1) xx xxxxx xxxxx xxxx xxxxxx xxx 20 °X.
6. Xxxxxxxxx xxxxxxxx x xxxxxx xxxxxxx
6.1 Xxxxx xxxxxx xx xxxxxxx x xxxxxx xxxx xxx xxxxxxx xxxxxxxxx xxx 20 °X xxxxx xxxxxxx xxxxxxx a xxxx xxxxxxx xx xxxxxxxxxx xxxxxxxxxx xxxxx x xxxxxxxxxxxx vzorku xx x xxxxxxxx x xxxxxxx přičte xx xxxxx 1 % xxxxxxxxxx cukru xxxxxxx 0,022.
6.2 Xxxxx byl xxxxxx xxxxxx xxxxx x xxxxxx 1:1 (x/x), xxxx xx xxxxx xxxxxxxxx sušiny xxxxxxxxx xxxxx.
6.3 Opakovatelnost
Rozdíl xxxx xxxxxxxx dvou xxxxxxxxx provedených zároveň xxxx xxxxxx xx xxxxx x xxxxx xxxxxx tímtéž pracovníkem xx totožných xxxxxxxx xxxxx být xxxxx xxx 0,2 x xxxxxx xx 100 x vzorku.
REFERENČNÍ XXXXXXX
Xxxxxx xxxx (x) roztoků xxxxxxxxx xxx 20 °X [1]
|
x (20 °X) |
Xxxxxxxxx (%) |
|
1,3330 |
0,009 |
|
1,3331 |
0,078 |
|
1,3332 |
0,149 |
|
1,3333 |
0,218 |
|
1,3334 |
0,288 |
|
1,3335 |
0,358 |
|
1,3336 |
0,428 |
|
1,3337 |
0,498 |
|
1,3338 |
0,567 |
|
1,3339 |
0,637 |
|
1,3340 |
0,707 |
|
1,3341 |
0,776 |
|
1,3342 |
0,846 |
|
1,3343 |
0,915 |
|
1,3344 |
0,985 |
|
1,3345 |
1,054 |
|
1,3346 |
1,124 |
|
1,3347 |
1,193 |
|
1,3348 |
1,263 |
|
1,3349 |
1,332 |
|
1,3350 |
1,401 |
|
1,3351 |
1,470 |
|
1,3352 |
1,540 |
|
1,3353 |
1,609 |
|
1,3354 |
1,678 |
|
1,3355 |
1,747 |
|
1,3356 |
1,816 |
|
1,3357 |
1,885 |
|
1,3358 |
1,954 |
|
1,3359 |
2,023 |
|
1,3360 |
2,092 |
|
1,3361 |
2,161 |
|
1,3362 |
2,230 |
|
1,3363 |
2,299 |
|
1,3364 |
2,367 |
|
1,3365 |
2,436 |
|
1,3366 |
2,505 |
|
1,3367 |
2,574 |
|
1,3368 |
2,642 |
|
1,3369 |
2,711 |
|
1,3370 |
2,779 |
|
1,3371 |
2,848 |
|
1,3372 |
2,917 |
|
1,3373 |
2,985 |
|
1,3374 |
3,053 |
|
1,3375 |
3,122 |
|
1,3376 |
3,190 |
|
1,3377 |
3,259 |
|
1,3378 |
3,327 |
|
1,3379 |
3,395 |
|
1,3380 |
3,463 |
|
1,3381 |
3,532 |
|
1,3382 |
3,600 |
|
1,3383 |
3,668 |
|
1,3384 |
3,736 |
|
1,3385 |
3,804 |
|
1,3386 |
3,872 |
|
1,3387 |
3,940 |
|
1,3388 |
4,008 |
|
1,3389 |
4,076 |
|
1,3390 |
4,144 |
|
1,3391 |
4,212 |
|
1,3392 |
4,279 |
|
1,3393 |
4,347 |
|
1,3394 |
4,415 |
|
1,3395 |
4,483 |
|
1,3396 |
4,550 |
|
1,3397 |
4,618 |
|
1,3398 |
4,686 |
|
1,3399 |
4,753 |
|
1,3400 |
4,821 |
|
1,3401 |
4,888 |
|
1,3402 |
4,956 |
|
1,3403 |
5,023 |
|
1,3404 |
5,091 |
|
1,3405 |
5,158 |
|
1,3406 |
5,225 |
|
1,3407 |
5,293 |
|
1,3408 |
5,360 |
|
1,3409 |
5,427 |
|
1,3410 |
5,494 |
|
1,3411 |
5,562 |
|
1,3412 |
5,629 |
|
1,3413 |
5,696 |
|
1,3414 |
5,763 |
|
1,3415 |
5,830 |
|
1,3416 |
5,897 |
|
1,3417 |
5,964 |
|
1,3418 |
6,031 |
|
1,3419 |
6,098 |
|
1,3420 |
6,165 |
|
1,3421 |
6,231 |
|
1,3422 |
6,298 |
|
1,3423 |
6,365 |
|
1,3424 |
6,432 |
|
1,3425 |
6,498 |
|
1,3426 |
6,565 |
|
1,3427 |
6,632 |
|
1,3428 |
6,698 |
|
1,3429 |
6,765 |
|
1,3430 |
6,831 |
|
1,3431 |
6,898 |
|
1,3432 |
6,964 |
|
1,3433 |
7,031 |
|
1,3434 |
7,097 |
|
1,3435 |
7,164 |
|
1,3436 |
7,230 |
|
1,3437 |
7,296 |
|
1,3438 |
7,362 |
|
1,3439 |
7,429 |
|
1,3440 |
7,495 |
|
1,3441 |
7,561 |
|
1,3442 |
7,627 |
|
1,3443 |
7,693 |
|
1,3444 |
7,759 |
|
1,3445 |
7,825 |
|
1,3446 |
7,891 |
|
1,3447 |
7,957 |
|
1,3448 |
8,023 |
|
1,3449 |
8,089 |
|
1,3450 |
8,155 |
|
1,3451 |
8,221 |
|
1,3452 |
8,287 |
|
1,3453 |
8,352 |
|
1,3454 |
8,418 |
|
1,3455 |
8,484 |
|
1,3456 |
8,550 |
|
1,3457 |
8,615 |
|
1 3458 |
8,681 |
|
1,3459 |
8,746 |
|
1,3460 |
8,812 |
|
1,3461 |
8,878 |
|
1,3462 |
8,943 |
|
1,3463 |
9,008 |
|
1,3464 |
9,074 |
|
1,3465 |
9,139 |
|
1,3466 |
9,205 |
|
1,3467 |
9,270 |
|
1,3468 |
9,335 |
|
1,3469 |
9,400 |
|
1,3470 |
9,466 |
|
1,3471 |
9,531 |
|
1,3472 |
9,596 |
|
1,3473 |
9,661 |
|
1,3474 |
9,726 |
|
1,3475 |
9,791 |
|
1,3476 |
9,856 |
|
1,3477 |
9,921 |
|
1,3478 |
9,986 |
|
1,3479 |
10,051 |
|
1,3480 |
10,116 |
|
1,3481 |
10,181 |
|
1,3482 |
10,246 |
|
1,3483 |
10,311 |
|
1,3484 |
10,375 |
|
1,3485 |
10,440 |
|
1,3486 |
10,505 |
|
1,3487 |
10,570 |
|
1,3488 |
10,634 |
|
1,3489 |
10,699 |
|
1,3490 |
10,763 |
|
1,3491 |
10,828 |
|
1,3492 |
10,892 |
|
1,3493 |
10,957 |
|
1,3494 |
11,021 |
|
1,3495 |
11,086 |
|
1,3496 |
11,150 |
|
1,3497 |
11,215 |
|
1,3498 |
11,279 |
|
1,3499 |
11,343 |
|
1,3500 |
11,407 |
|
1,3501 |
11,472 |
|
1,3502 |
11,536 |
|
1,3503 |
11,600 |
|
1,3504 |
11,664 |
|
1,3505 |
11,728 |
|
1,3506 |
11,792 |
|
1,3507 |
11,856 |
|
1,3508 |
11,920 |
|
1,3509 |
11,984 |
|
1,3510 |
12,048 |
|
1,3511 |
12,112 |
|
1,3512 |
12,176 |
|
1,3513 |
12,240 |
|
1,3514 |
12,304 |
|
1,3515 |
12,368 |
|
1,3516 |
12,431 |
|
1,3517 |
12,495 |
|
1,3518 |
12,559 |
|
1,3519 |
12,623 |
|
1,3520 |
12,686 |
|
1,3521 |
12,750 |
|
1,3522 |
12,813 |
|
1,3523 |
12,877 |
|
1,3524 |
12,940 |
|
1,3525 |
13,004 |
|
1,3526 |
13,067 |
|
1,3527 |
13,131 |
|
1,3528 |
13,194 |
|
1,3529 |
13,258 |
|
1,3530 |
13,321 |
|
1,3531 |
13,384 |
|
1,3532 |
13,448 |
|
1,3533 |
13,511 |
|
1,3534 |
13,574 |
|
1,3535 |
13,637 |
|
1,3536 |
13,700 |
|
1,3537 |
13,763 |
|
1,3538 |
13,826 |
|
1,3539 |
13,890 |
|
1,3540 |
13,953 |
|
1,3541 |
14,016 |
|
1,3542 |
14,079 |
|
1,3543 |
14,141 |
|
1,3544 |
14,204 |
|
1,3545 |
14,267 |
|
1,3546 |
14,330 |
|
1,3547 |
14,393 |
|
1,3548 |
14,456 |
|
1,3549 |
14,518 |
|
1,3550 |
14,581 |
|
1,3551 |
14,644 |
|
1,3552 |
14,707 |
|
1,3553 |
14,769 |
|
1,3554 |
14,832 |
|
1,3555 |
14,894 |
|
1,3556 |
14,957 |
|
1,3557 |
15,019 |
|
1,3558 |
15,082 |
|
1,3559 |
15,144 |
|
1,3560 |
15,207 |
|
1,3561 |
15,269 |
|
1,3562 |
15,332 |
|
1,3563 |
15,394 |
|
1,3564 |
15,456 |
|
1,3565 |
15,518 |
|
1,3566 |
15,581 |
|
1,3567 |
15,643 |
|
1,3568 |
15,705 |
|
1,3569 |
15,767 |
|
1,3570 |
15,829 |
|
1,3571 |
15,891 |
|
1,3572 |
15,953 |
|
1,3573 |
16,016 |
|
1,3574 |
16,078 |
|
1,3575 |
16,140 |
|
1,3576 |
16,201 |
|
1,3577 |
16,263 |
|
1,3578 |
16,325 |
|
1,3579 |
16,387 |
|
1,3580 |
16,449 |
|
1,3581 |
16,511 |
|
1,3582 |
16,573 |
|
1,3583 |
16,634 |
|
1,3584 |
16,696 |
|
1,3585 |
16,758 |
|
1,3586 |
16,819 |
|
1,3587 |
16,881 |
|
1,3588 |
16,943 |
|
1,3389 |
17,004 |
|
1,3590 |
17,066 |
|
1,3591 |
17,127 |
|
1,3592 |
17,189 |
|
1,3593 |
17,250 |
|
1,3594 |
17,311 |
|
1,3595 |
17,373 |
|
1,3596 |
17,434 |
|
1,3597 |
17,496 |
|
1,3598 |
17,557 |
|
1,3599 |
17,618 |
|
1,3600 |
17,679 |
|
1,3601 |
17,741 |
|
1,3602 |
17,802 |
|
1,3603 |
17,863 |
|
1,3604 |
17,924 |
|
1,3605 |
17,985 |
|
1,3606 |
18,046 |
|
1,3607 |
18,107 |
|
1,3608 |
18,168 |
|
1,3609 |
18,229 |
|
1,3610 |
18,290 |
|
1,3610 |
18,351 |
|
1,3611 |
18,412 |
|
1,3613 |
18,473 |
|
1,3614 |
18,534 |
|
1,3615 |
18,595 |
|
1,3616 |
18,655 |
|
1,3617 |
18,716 |
|
1,3618 |
18,777 |
|
1,3619 |
18,837 |
|
1,3620 |
18,898 |
|
1,3621 |
18,959 |
|
1,3622 |
19,019 |
|
1,3623 |
19,080 |
|
1,3624 |
19,141 |
|
1,3625 |
19,201 |
|
1,3626 |
19,262 |
|
1,3627 |
19,322 |
|
1,3628 |
19,382 |
|
1,3629 |
19,443 |
|
1,3630 |
19,503 |
|
1,3631 |
19,564 |
|
1,3632 |
19,624 |
|
1,3633 |
19,684 |
|
1,3634 |
19,745 |
|
1,3635 |
19,805 |
|
1,3636 |
19,865 |
|
1,3637 |
19,925 |
|
1,3638 |
19,985 |
|
1,3639 |
20,045 |
|
1,3640 |
20,106 |
|
1.3641 |
20,166 |
|
1,3642 |
20,226 |
|
1,3643 |
20,286 |
|
1,3644 |
20,346 |
|
1,3645 |
20,406 |
|
1,3646 |
20,466 |
|
1,3647 |
20,525 |
|
1,3648 |
20,585 |
|
1,3649 |
20,645 |
|
1,3650 |
20,705 |
|
1,3651 |
20,765 |
|
1,3652 |
20,825 |
|
1,3653 |
20,884 |
|
1,3654 |
20,944 |
|
1,3655 |
21,004 |
|
1,3656 |
21,063 |
|
1,3657 |
21,123 |
|
1,3658 |
21,183 |
|
1,3659 |
21,242 |
|
1,3660 |
21,302 |
|
1,3661 |
21,361 |
|
1,3662 |
21,421 |
|
1,3563 |
21,480 |
|
1,3664 |
21,540 |
|
1,3665 |
21,599 |
|
1,3666 |
21,658 |
|
1,3667 |
21,718 |
|
1,3668 |
21,777 |
|
1,3669 |
21,836 |
|
1,3670 |
21,896 |
|
1,3671 |
21,955 |
|
1,3672 |
22,014 |
|
1,1673 |
22,073 |
|
1,3674 |
22,132 |
|
1,3675 |
22,192 |
|
1,3676 |
22,251 |
|
1,1677 |
22,310 |
|
1,3678 |
22,369 |
|
1,3679 |
22,428 |
|
1,3680 |
22,487 |
|
1,3681 |
22,546 |
|
1,3682 |
22,605 |
|
1,3683 |
22,664 |
|
1,3684 |
22,723 |
|
1,3685 |
22,781 |
|
1,3686 |
22,840 |
|
1,3687 |
22,899 |
|
1,3688 |
22,958 |
|
1,3689 |
23,017 |
|
1,3690 |
23,075 |
|
1,3691 |
23,134 |
|
1,3692 |
23,193 |
|
1,3693 |
23,251 |
|
1,3694 |
23,310 |
|
1,3695 |
23,369 |
|
1,3696 |
23,427 |
|
1,3697 |
23,486 |
|
1,3698 |
23,544 |
|
1,3699 |
23,603 |
|
1,3700 |
23,661 |
|
1,3701 |
23,720 |
|
1,3702 |
23,778 |
|
1,3703 |
23,836 |
|
1,3704 |
23,895 |
|
1,3705 |
23,953 |
|
1,3706 |
24,011 |
|
1,3707 |
24,070 |
|
1,3708 |
24,128 |
|
1,3709 |
24,186 |
|
1,3710 |
24,244 |
|
1,3711 |
24,302 |
|
1,3712 |
24,361 |
|
1,3713 |
24,419 |
|
1,3714 |
24,477 |
|
1,3715 |
24,535 |
|
1,3716 |
24,593 |
|
1,3717 |
24,651 |
|
1,3718 |
24,709 |
|
1,3719 |
24,767 |
|
1,3720 |
24,825 |
|
1,3721 |
24,883 |
|
1,3722 |
24,941 |
|
1,3723 |
24,998 |
|
1,3724 |
25,056 |
|
1,3725 |
25,114 |
|
1,3726 |
25,172 |
|
1,3727 |
25,230 |
|
1,3728 |
25287 |
|
1,3729 |
25,345 |
|
1,3730 |
25,403 |
|
1,3731 |
25,460 |
|
1,3732 |
25,518 |
|
1,3733 |
25,576 |
|
1,3734 |
25,633 |
|
1,3735 |
25,691 |
|
1,3736 |
25,748 |
|
1,3737 |
25,806 |
|
1,3738 |
25,863 |
|
1,3739 |
25,921 |
|
1,3740 |
25,978 |
|
1,3741 |
26,035 |
|
1,3742 |
26,093 |
|
1,3743 |
26,150 |
|
1,3744 |
26,207 |
|
1,3745 |
26,265 |
|
1,3746 |
26,322 |
|
1,3747 |
26,379 |
|
1,3748 |
26,436 |
|
1,3749 |
26,493 |
|
1,3750 |
26,551 |
|
1,3751 |
26,608 |
|
1,3752 |
26,665 |
|
1,3753 |
26,722 |
|
1,3754 |
26,779 |
|
1,3755 |
26,836 |
|
1,3756 |
26,893 |
|
1,3757 |
26,950 |
|
1,3758 |
27,007 |
|
1,3759 |
27,064 |
|
1,3760 |
27,121 |
|
1,3761 |
27,178 |
|
1,3762 |
27,234 |
|
1,3763 |
27,291 |
|
1,3764 |
27,348 |
|
1,3765 |
27,405 |
|
1,3765 |
27,462 |
|
1,3767 |
27,518 |
|
1,3768 |
27,575 |
|
1,3769 |
27,632 |
|
1,3770 |
27,688 |
|
1,3771 |
27,745 |
|
1,3772 |
27,802 |
|
1,3773 |
27,858 |
|
1,3774 |
27,915 |
|
1,3775 |
27,971 |
|
1,3776 |
28,028 |
|
1,3777 |
28,084 |
|
1,3778 |
28,141 |
|
1,3779 |
28,197 |
|
1,3780 |
28,253 |
|
1,3781 |
28,310 |
|
1,3782 |
28,366 |
|
1,3783 |
28,422 |
|
1,3784 |
28,479 |
|
1,3785 |
28,535 |
|
1,3786 |
28,591 |
|
1,3787 |
28,648 |
|
1,3788 |
28,704 |
|
1,3789 |
28,760 |
|
1,3790 |
28,816 |
|
1,3791 |
28,872 |
|
1,3792 |
28,928 |
|
1,3793 |
28,984 |
|
1,3794 |
29,040 |
|
1,3795 |
29,096 |
|
1,3796 |
29,152 |
|
1,3797 |
29,208 |
|
1,3798 |
29,264 |
|
1,3799 |
29,320 |
|
1,3800 |
29,376 |
|
1,3801 |
29,432 |
|
1,3802 |
29,488 |
|
1,3803 |
29,544 |
|
1,3804 |
29,600 |
|
1,3805 |
29,655 |
|
1,3806 |
29,711 |
|
1,3807 |
29,767 |
|
1,3808 |
29,823 |
|
1,3809 |
29,878 |
|
1,3810 |
29,934 |
|
1,3811 |
29,989 |
|
1,3812 |
30,045 |
|
1,3813 |
30,101 |
|
1,3814 |
30,156 |
|
1,3815 |
30,212 |
|
1,3816 |
30,267 |
|
1,3817 |
30,323 |
|
1,3818 |
30,378 |
|
1,3819 |
30,434 |
|
1,3820 |
30,489 |
|
1,3821 |
30,544 |
|
1,3822 |
30,600 |
|
1,3823 |
30,655 |
|
1,3824 |
30,711 |
|
1,3825 |
30,766 |
|
1,3826 |
30,821 |
|
1,3827 |
30,876 |
|
1,3828 |
30,932 |
|
1,3829 |
30,987 |
|
1,3830 |
31,042 |
|
1,3831 |
31,097 |
|
1,3832 |
31,152 |
|
1,3833 |
31,207 |
|
1,3834 |
31,262 |
|
1,3835 |
31,317 |
|
1,3836 |
31,372 |
|
1,3837 |
31,428 |
|
1,3838 |
31,482 |
|
1,3839 |
31,537 |
|
1,3840 |
31,592 |
|
1,3841 |
31,647 |
|
1,3842 |
31,702 |
|
1,3843 |
31,757 |
|
1,3844 |
31,812 |
|
1,3845 |
31,867 |
|
1,3846 |
31,922 |
|
1,3847 |
31,976 |
|
1,3848 |
32,031 |
|
1,3849 |
32,086 |
|
1,3850 |
32,140 |
|
1,3851 |
32,195 |
|
1,3852 |
32,250 |
|
1,3853 |
32,304 |
|
1,3854 |
32,359 |
|
1,3855 |
32,414 |
|
1,3856 |
32,468 |
|
1,3857 |
32,523 |
|
1,3858 |
32,577 |
|
1,3859 |
32,632 |
|
1,3860 |
32,686 |
|
1,3861 |
32,741 |
|
1,3862 |
32,795 |
|
1,3863 |
32,849 |
|
1,3864 |
32,904 |
|
1,3865 |
32,958 |
|
1,3866 |
33,013 |
|
1,3867 |
33,067 |
|
1,3868 |
33,121 |
|
1,3889 |
33,175 |
|
1,3870 |
33,230 |
|
1,3871 |
33,284 |
|
1,3872 |
33,338 |
|
1,3873 |
33,392 |
|
1,3874 |
33,446 |
|
1,3875 |
33,500 |
|
1,3876 |
33,555 |
|
1,3877 |
33,609 |
|
1,3878 |
33,663 |
|
1,3879 |
33,717 |
|
1,3880 |
33,771 |
|
1,3881 |
33,825 |
|
1,3882 |
33,879 |
|
1,3883 |
33,933 |
|
1,3884 |
33,987 |
|
1,3885 |
34,040 |
|
1,3886 |
34,094 |
|
1,3887 |
34,148 |
|
1,3888 |
34,202 |
|
1,3889 |
34,256 |
|
1,3890 |
34,310 |
|
1,3891 |
34,363 |
|
1,3892 |
34,417 |
|
1,3893 |
34,471 |
|
1,3894 |
34,524 |
|
1,3895 |
34,578 |
|
1,3896 |
34,632 |
|
1,3897 |
34,685 |
|
1,3898 |
34,739 |
|
1,3899 |
34,793 |
|
1,3900 |
34,846 |
|
1,3901 |
34,900 |
|
1,3902 |
34,953 |
|
1,3903 |
35,007 |
|
1,3904 |
35,060 |
|
1,3905 |
35,114 |
|
1,3906 |
35,167 |
|
1,3907 |
35,220 |
|
1,3908 |
35,274 |
|
1,3909 |
35,327 |
|
1,3910 |
35,380 |
|
1,3911 |
35,434 |
|
1,3912 |
35,487 |
|
1,3913 |
35,540 |
|
1,3914 |
35,593 |
|
1,3915 |
35,647 |
|
1,3916 |
35,700 |
|
1,3917 |
35,753 |
|
1,3918 |
35,806 |
|
1,3919 |
35,859 |
|
1,3920 |
35,912 |
|
1,3921 |
35,966 |
|
1,3922 |
36,019 |
|
1,3923 |
36,072 |
|
1,3924 |
36,125 |
|
1,3925 |
36,178 |
|
1,3926 |
36,231 |
|
1,3927 |
36,284 |
|
1,3928 |
36,337 |
|
1,3929 |
36,389 |
|
1,3930 |
36,442 |
|
1,3931 |
36,495 |
|
1,3932 |
36,548 |
|
1,3933 |
36,601 |
|
1,3934 |
36,654 |
|
1,3935 |
36,706 |
|
1,3936 |
36,759 |
|
1,3937 |
36,812 |
|
1,3938 |
36,865 |
|
1,3939 |
36,917 |
|
1,3940 |
36,970 |
|
1,3941 |
37,023 |
|
1,3942 |
37,075 |
|
1,3943 |
37,128 |
|
1,3944 |
37,180 |
|
1,3945 |
37,233 |
|
1,3946 |
37,286 |
|
1,3947 |
37,338 |
|
1,3948 |
37,391 |
|
1,3949 |
37,443 |
|
1,3950 |
37,495 |
|
1,3951 |
37,548 |
|
1,3952 |
37,600 |
|
1,3953 |
37,653 |
|
1,3954 |
37,705 |
|
1,3955 |
37,757 |
|
1,3956 |
37,810 |
|
1,3957 |
37,862 |
|
1,3958 |
37,914 |
|
1,3959 |
37,967 |
|
1,3960 |
38,019 |
|
1,3961 |
38,071 |
|
1,3962 |
38,123 |
|
1,3963 |
38,175 |
|
1,3964 |
38,228 |
|
1,3965 |
38,280 |
|
1,3966 |
38,332 |
|
1,3967 |
38,384 |
|
1,3968 |
38,436 |
|
1,3969 |
38,488 |
|
1,3970 |
38,540 |
|
1,3971 |
38,592 |
|
1,3972 |
38,644 |
|
1,3973 |
38,696 |
|
1,3974 |
38,748 |
|
1,3975 |
38,800 |
|
1,3976 |
38,852 |
|
1,3977 |
38,904 |
|
1,3978 |
38,955 |
|
1,3979 |
39,007 |
|
1,3980 |
39,059 |
|
1,3981 |
39,111 |
|
1,3982 |
39,163 |
|
1,3983 |
39,214 |
|
1,3984 |
39,266 |
|
1,3985 |
39,318 |
|
1,3986 |
39,370 |
|
1,3987 |
39,421 |
|
1,3988 |
39,473 |
|
1,3989 |
39,525 |
|
1,3990 |
39,576 |
|
1,3991 |
39,628 |
|
1,3992 |
39,679 |
|
1,3993 |
39,731 |
|
1,3994 |
39,782 |
|
1,3995 |
39,834 |
|
1,3996 |
39,885 |
|
1,3997 |
39,937 |
|
1,3998 |
39,988 |
|
1,3999 |
40,040 |
|
1,4000 |
40,091 |
|
1,4001 |
40,142 |
|
1,4002 |
40,194 |
|
1,4003 |
40,245 |
|
1,4004 |
40,296 |
|
1,4005 |
40,348 |
|
1,4006 |
40,399 |
|
1,4007 |
40,450 |
|
1,4008 |
40,501 |
|
1,4009 |
40,553 |
|
1,4010 |
40,604 |
|
1,4011 |
40,655 |
|
1,4012 |
40,706 |
|
1,4013 |
40,757 |
|
1,4014 |
40,808 |
|
1,4015 |
40,860 |
|
1,4016 |
40,911 |
|
1,4017 |
40,962 |
|
1,4018 |
41,013 |
|
1,4019 |
41,064 |
|
1,4020 |
41,115 |
|
1,4021 |
41,166 |
|
1,4022 |
41,217 |
|
1,4023 |
41,268 |
|
1,4024 |
41,318 |
|
1,4025 |
41,369 |
|
1,4026 |
41,420 |
|
1,4027 |
41,471 |
|
1,4028 |
41,522 |
|
1,4029 |
41,573 |
|
1,4030 |
41,623 |
|
1,4031 |
41,674 |
|
1,4032 |
41,725 |
|
1,4033 |
41,776 |
|
1,4034 |
41,826 |
|
1,4035 |
41,877 |
|
1,4036 |
41,928 |
|
1,4037 |
41,978 |
|
1,4038 |
42,029 |
|
1,4039 |
42,080 |
|
1,4040 |
42,130 |
|
1,4041 |
42,181 |
|
1,4042 |
42,231 |
|
1,4043 |
42,282 |
|
1,4044 |
42,332 |
|
1,4045 |
42,383 |
|
1,4046 |
42,433 |
|
1,4047 |
42,484 |
|
1,4048 |
42,534 |
|
1,4049 |
42,585 |
|
1,4050 |
42,635 |
|
1,4051 |
42,685 |
|
1,4052 |
42,736 |
|
1,4053 |
42,786 |
|
1,4054 |
42,836 |
|
1,4055 |
42,887 |
|
1,4056 |
42,937 |
|
1,4057 |
42,987 |
|
1,4058 |
43,037 |
|
1,4059 |
43,088 |
|
1,4060 |
43,138 |
|
1,4061 |
43,188 |
|
1,4062 |
43,238 |
|
1,4063 |
43,288 |
|
1,4064 |
43,338 |
|
1,4065 |
43,388 |
|
1,4066 |
43,439 |
|
1,4067 |
43,489 |
|
1,4068 |
43,539 |
|
1,4069 |
43,589 |
|
1,4070 |
43,639 |
|
1,4071 |
43,689 |
|
1,4072 |
43739 |
|
1,4073 |
43,789 |
|
1,4074 |
43,838 |
|
1,4075 |
43,888 |
|
1,4076 |
43,938 |
|
1,4077 |
43,988 |
|
1,4078 |
44,038 |
|
1,4079 |
44,088 |
|
1,4080 |
44,138 |
|
1,4081 |
44,187 |
|
1,4082 |
44,237 |
|
1,4083 |
44,287 |
|
1,4084 |
44,337 |
|
1,4085 |
44,386 |
|
1,4086 |
44,436 |
|
1,4087 |
44,486 |
|
1,4088 |
44,535 |
|
1,4089 |
44,585 |
|
1,4090 |
44,635 |
|
1,4091 |
44,684 |
|
1,4092 |
44,734 |
|
1,4093 |
44,783 |
|
1,4094 |
44,833 |
|
1,4095 |
44,882 |
|
1,4096 |
44,932 |
|
1,4097 |
44,981 |
|
1,4098 |
45,031 |
|
1,4099 |
45,080 |
|
1,4100 |
45,130 |
|
1,4101 |
43,179 |
|
1,4102 |
45,228 |
|
1,4103 |
45,278 |
|
1,4104 |
45,327 |
|
1,4105 |
45,376 |
|
1,4106 |
45,426 |
|
1,4107 |
45,475 |
|
1,4108 |
45,524 |
|
1,4109 |
45,574 |
|
1,4110 |
45,623 |
|
1,4111 |
45,672 |
|
1,4112 |
45,721 |
|
1,4113 |
45,770 |
|
1,4114 |
45,820 |
|
1,4115 |
45,869 |
|
1,4116 |
45,918 |
|
1,4117 |
46,967 |
|
1,4118 |
46,016 |
|
1,4119 |
46,065 |
|
1,4120 |
46,114 |
|
1,4121 |
46,163 |
|
1,4122 |
46,212 |
|
1,4123 |
46,261 |
|
1,4124 |
46,310 |
|
1,4125 |
46,359 |
|
1,4126 |
46,408 |
|
1,4127 |
46,457 |
|
1,4128 |
46,506 |
|
1,4129 |
46,555 |
|
1,4130 |
46,604 |
|
1,4131 |
46,652 |
|
1,4132 |
46,701 |
|
1,4133 |
46,750 |
|
1,4134 |
46,799 |
|
1,4135 |
46,848 |
|
1,4136 |
46,896 |
|
1,4137 |
46,945 |
|
1,4138 |
46,994 |
|
1,4139 |
47,043 |
|
1,4140 |
47,091 |
|
1,4141 |
47,140 |
|
1,4141 |
47,188 |
|
1,4143 |
47,237 |
|
1,4144 |
47,286 |
|
1,4145 |
47,334 |
|
1,4146 |
47,383 |
|
1,4147 |
47,431 |
|
1,4148 |
47,480 |
|
1,4149 |
47,528 |
|
1,4150 |
47,577 |
|
1,4151 |
47,625 |
|
1,4152 |
47,674 |
|
1,4153 |
47,722 |
|
1,4154 |
47,771 |
|
1,4155 |
47,819 |
|
1,4156 |
47,868 |
|
1,4157 |
47,916 |
|
1,4158 |
47,964 |
|
1,4159 |
48,013 |
|
1,4160 |
48,061 |
|
1,4161 |
48,109 |
|
1,4162 |
48,158 |
|
1,4163 |
48,206 |
|
1,4164 |
48,254 |
|
1,4165 |
48,302 |
|
1,4166 |
48,350 |
|
1,4167 |
48,399 |
|
1,4168 |
48,447 |
|
1,4169 |
48,495 |
|
1,4170 |
48,543 |
|
1,4171 |
48,591 |
|
1,4172 |
48,639 |
|
1,4173 |
48,687 |
|
1,4174 |
48,735 |
|
1,4175 |
48,784 |
|
1,4176 |
48,832 |
|
1,4177 |
48,880 |
|
1,4178 |
48,928 |
|
1,4179 |
48,976 |
|
1,4180 |
49,023 |
|
1,4181 |
49,071 |
|
1,4182 |
49,119 |
|
1,4183 |
49,167 |
|
1,4184 |
49,215 |
|
1,4185 |
49,263 |
|
1,4186 |
49,311 |
|
1,4187 |
49,359 |
|
1,4188 |
49,407 |
|
1,4189 |
49,454 |
|
1,4190 |
49,502 |
|
1,4191 |
49,550 |
|
1,4192 |
49,598 |
|
1,4193 |
49,645 |
|
1,4194 |
49,693 |
|
1,4195 |
49,741 |
|
1,4196 |
49,788 |
|
1,4197 |
49,836 |
|
1,4198 |
49,884 |
|
1,4199 |
49,931 |
|
1,4200 |
49,979 |
|
1,4201 |
50,027 |
|
1,4202 |
50,074 |
|
1,4203 |
50,122 |
|
1,4204 |
50,169 |
|
1,4205 |
50,217 |
|
1,4206 |
50,264 |
|
1,4207 |
50,312 |
|
1,4208 |
50,359 |
|
1,4209 |
50,407 |
|
1,4210 |
50,454 |
|
1,4211 |
50,502 |
|
1,4212 |
50,549 |
|
1,4213 |
50,596 |
|
1,4214 |
50,644 |
|
1,4215 |
50,691 |
|
1,4216 |
50,738 |
|
1,4217 |
50,786 |
|
1,4218 |
50,833 |
|
1,4219 |
50,880 |
|
1,4220 |
50,928 |
|
1,4221 |
50,975 |
|
1,4222 |
51,022 |
|
1,4223 |
51,069 |
|
1,4224 |
51,116 |
|
1,4225 |
51,164 |
|
1,4226 |
51,211 |
|
1,4227 |
51,258 |
|
1,4228 |
51305 |
|
1,4229 |
51,352 |
|
1,4230 |
51,399 |
|
1,4231 |
51,446 |
|
1,4232 |
51,493 |
|
1,4233 |
51,540 |
|
1,4234 |
51,587 |
|
1,4235 |
51,634 |
|
1,4236 |
51,681 |
|
1,4237 |
51,728 |
|
1,4238 |
51,775 |
|
1,4239 |
51,822 |
|
1,4240 |
51,869 |
|
1,4241 |
51,916 |
|
1,4242 |
51,963 |
|
1,4243 |
52,010 |
|
1,4244 |
52,057 |
|
1,4245 |
52,104 |
|
1,4246 |
52,150 |
|
1,4247 |
52,197 |
|
1,4248 |
52,244 |
|
1,4249 |
52,291 |
|
1,4250 |
52,338 |
|
1,4251 |
52,384 |
|
1,4252 |
52,431 |
|
1,4253 |
52,478 |
|
1,4254 |
52,524 |
|
1,4255 |
52,571 |
|
1,4256 |
52,618 |
|
1,4257 |
52,664 |
|
1,4258 |
52,711 |
|
1,4259 |
52,758 |
|
1,4260 |
52,804 |
|
1,4261 |
52,851 |
|
1,4261 |
52,897 |
|
1,4263 |
52,944 |
|
1,4264 |
52,990 |
|
1,4265 |
53,037 |
|
1,4266 |
53,083 |
|
1,4267 |
53,130 |
|
1,4268 |
53,176 |
|
1,4269 |
53,223 |
|
1,4270 |
53,269 |
|
1,4271 |
53,316 |
|
1,4272 |
53,362 |
|
1,4273 |
53,408 |
|
1,4274 |
53,455 |
|
1,4275 |
53,501 |
|
1,4276 |
53,548 |
|
1,4277 |
53,594 |
|
1,4278 |
53,640 |
|
1,4279 |
53,686 |
|
1,4280 |
53,733 |
|
1,4281 |
53,779 |
|
1,4282 |
53,825 |
|
1,4283 |
53,871 |
|
1,4284 |
53,918 |
|
1,4285 |
53,964 |
|
1,4286 |
54,010 |
|
1,4287 |
54,056 |
|
1,4288 |
54,102 |
|
1,4289 |
54,148 |
|
1,4290 |
54,194 |
|
1,4291 |
54,241 |
|
1,4292 |
54,287 |
|
1,4293 |
54,333 |
|
1,4294 |
54,379 |
|
1,4295 |
54,425 |
|
1,4296 |
54,471 |
|
1,4297 |
54,517 |
|
1,4298 |
54,563 |
|
1,4299 |
54,609 |
|
1,4300 |
54,655 |
|
1,4301 |
54,701 |
|
1,4302 |
54,746 |
|
1,4303 |
54,792 |
|
1,4304 |
54,838 |
|
1,4305 |
54,884 |
|
1,4306 |
54,930 |
|
1,4307 |
54,976 |
|
1,4308 |
55,022 |
|
1,4309 |
55067 |
|
1,4310 |
55,113 |
|
1,4311 |
55,159 |
|
1,4312 |
55,205 |
|
1,4313 |
55,250 |
|
1,4314 |
55,296 |
|
1,4315 |
55,342 |
|
1,4316 |
55,388 |
|
1,4317 |
55,433 |
|
1,4318 |
55,479 |
|
1,4319 |
55,524 |
|
1,4320 |
55,570 |
|
1,4321 |
55,616 |
|
1,4322 |
55,661 |
|
1,4323 |
55,707 |
|
1,4324 |
55,752 |
|
1,4325 |
55,798 |
|
1,4326 |
55,844 |
|
1,4327 |
55,889 |
|
1,4328 |
55,935 |
|
1,4329 |
55,980 |
|
1,4330 |
56,026 |
|
1,4331 |
56,071 |
|
1,4332 |
56,116 |
|
1,4133 |
56,162 |
|
1,4334 |
56,207 |
|
1,4335 |
56,253 |
|
1,4336 |
56,298 |
|
1,4337 |
56,343 |
|
1,4338 |
56,389 |
|
1,4339 |
56,434 |
|
1,4340 |
56,479 |
|
1,4341 |
56,525 |
|
1,4342 |
56,570 |
|
1,4343 |
56,615 |
|
1,4344 |
56,660 |
|
1,4345 |
56,706 |
|
1,4346 |
56,751 |
|
1,4347 |
56,796 |
|
1,4348 |
56,841 |
|
1,4349 |
56,887 |
|
1,4350 |
56,932 |
|
1,4351 |
56,977 |
|
1,4352 |
57,022 |
|
1,4353 |
57,067 |
|
1,4354 |
57,112 |
|
1,4355 |
57,157 |
|
1,4356 |
57,202 |
|
1,4357 |
57,247 |
|
14358 |
57,292 |
|
1,4359 |
57,337 |
|
1,4360 |
57,382 |
|
1,4361 |
57,427 |
|
1,4362 |
57,472 |
|
1,4363 |
57,517 |
|
1,4364 |
57,562 |
|
1,4365 |
57,607 |
|
1,4366 |
57,652 |
|
1,4367 |
57,697 |
|
1,4368 |
57,742 |
|
1,4369 |
57,787 |
|
1,4370 |
57,832 |
|
1,4371 |
57,877 |
|
1,4372 |
57,921 |
|
1,4373 |
57,966 |
|
1,4374 |
58,011 |
|
1,4375 |
58,056 |
|
1,4376 |
58,101 |
|
1,4377 |
58,145 |
|
1,4378 |
58,190 |
|
1,4379 |
58,235 |
|
1,4380 |
58,279 |
|
1,4381 |
58,324 |
|
1,4382 |
58,369 |
|
1,4383 |
58,413 |
|
1,4384 |
53,458 |
|
1,4385 |
58,503 |
|
1,4386 |
58,547 |
|
1,4387 |
58,592 |
|
1,4388 |
58,637 |
|
1,4389 |
58,681 |
|
1,4390 |
58,726 |
|
1,4391 |
58,770 |
|
1,4392 |
58,815 |
|
1,4393 |
58,859 |
|
1,4394 |
58,904 |
|
1,4395 |
58,948 |
|
1,4396 |
58,993 |
|
1,4397 |
59,037 |
|
1,4398 |
59,082 |
|
1,4399 |
59,126 |
|
1,4400 |
59,170 |
|
1,4401 |
59,215 |
|
1,4402 |
59,259 |
|
1,4403 |
59,304 |
|
1,4404 |
59,348 |
|
1,4405 |
59,392 |
|
1,4406 |
59,437 |
|
1,4407 |
59,481 |
|
1,4408 |
59,525 |
|
1,4409 |
59,569 |
|
1,4410 |
59,614 |
|
1,4411 |
59,658 |
|
1,4412 |
59,702 |
|
1,4413 |
59,746 |
|
1,4414 |
59,791 |
|
1,4415 |
59,835 |
|
1,4416 |
59,879 |
|
1,4417 |
59,923 |
|
1,4418 |
59,967 |
|
1,4419 |
60,011 |
|
1,4420 |
60,056 |
|
1,4421 |
60,100 |
|
1,4422 |
60,144 |
|
1,4423 |
60,188 |
|
1,4424 |
60,232 |
|
1,4425 |
60,276 |
|
1,4426 |
60,320 |
|
1,4427 |
60,364 |
|
1,4428 |
60,408 |
|
1,4429 |
60,452 |
|
1,4430 |
60,496 |
|
1,4431 |
60,540 |
|
1,4432 |
60,584 |
|
1,4433 |
60,628 |
|
1,4434 |
60,672 |
|
1,4435 |
60,716 |
|
1,4436 |
60,759 |
|
1,4437 |
60,803 |
|
1,4438 |
60,847 |
|
1,4439 |
60,891 |
|
1,4440 |
60,935 |
|
1,4441 |
60,979 |
|
1,4442 |
61,023 |
|
1,4443 |
61,066 |
|
1,4444 |
61,110 |
|
1,4445 |
61,154 |
|
1,4446 |
61,198 |
|
1,4447 |
61,241 |
|
1,4448 |
61,285 |
|
1,4449 |
61,329 |
|
1,4450 |
61,372 |
|
1,4451 |
61,416 |
|
1,4452 |
61,460 |
|
1,4453 |
61,503 |
|
1,4454 |
61,547 |
|
1,4455 |
61,591 |
|
1,4456 |
61,634 |
|
1,4457 |
61,678 |
|
1,4458 |
61,721 |
|
1,4459 |
61,765 |
|
1,4460 |
61,809 |
|
1,4461 |
61,852 |
|
1,4462 |
61,896 |
|
1,4463 |
61,939 |
|
1,4464 |
62,983 |
|
1,4465 |
62,026 |
|
1,4466 |
62,070 |
|
1,4467 |
62,113 |
|
1,4468 |
62,156 |
|
1,4469 |
62,200 |
|
1,4470 |
62,243 |
|
1,4471 |
62,287 |
|
1,4472 |
62,330 |
|
1,4473 |
62,373 |
|
1,4474 |
62,417 |
|
1,4475 |
62,460 |
|
1,4476 |
62,503 |
|
1,4477 |
62,547 |
|
1,4478 |
62,590 |
|
14479 |
62,633 |
|
1,4480 |
62,677 |
|
1,4481 |
62,720 |
|
1,4482 |
62,763 |
|
1,4483 |
62,806 |
|
1,4184 |
62,849 |
|
1,4485 |
62,893 |
|
1,4486 |
62,936 |
|
1,4487 |
62,979 |
|
1,4488 |
63,022 |
|
1,4489 |
63,065 |
|
1,4490 |
63,108 |
|
1,4491 |
63,152 |
|
1,4492 |
63,195 |
|
1,4493 |
63,238 |
|
1,4494 |
63,281 |
|
1,4495 |
63,324 |
|
1,4496 |
63,367 |
|
1,4497 |
63,410 |
|
1,4498 |
63,453 |
|
1,4499 |
63,496 |
|
1,4500 |
63,539 |
|
1,4501 |
63,582 |
|
1,4502 |
63,625 |
|
1,4503 |
63,668 |
|
1,4304 |
63,711 |
|
1,4505 |
63,754 |
|
1,4506 |
63,797 |
|
1,4507 |
63,840 |
|
1,4508 |
63,882 |
|
1,4509 |
63,925 |
|
1,4510 |
63,968 |
|
1,4511 |
64,011 |
|
1,4512 |
64,054 |
|
1,4513 |
64,097 |
|
1,4514 |
64,139 |
|
1,4515 |
64,182 |
|
1,4516 |
64,225 |
|
1,4517 |
64,268 |
|
1,4518 |
64,311 |
|
1,4519 |
64,353 |
|
1,4520 |
64,396 |
|
1,4521 |
64,439 |
|
1,4522 |
64,481 |
|
1,4523 |
64,524 |
|
1,4524 |
64,567 |
|
1,4525 |
64,609 |
|
1,4526 |
64,652 |
|
1,4527 |
64,695 |
|
1,4528 |
64,737 |
|
1,4529 |
64,780 |
|
1,4530 |
64,823 |
|
1,4531 |
64,865 |
|
1,4532 |
64,908 |
|
1,4533 |
64,950 |
|
1,4534 |
64,993 |
|
1,4535 |
65,035 |
|
1,4536 |
65,078 |
|
1,4537 |
65,120 |
|
1,4538 |
65,163 |
|
1,4539 |
65,205 |
|
1,4540 |
65,248 |
|
1,4541 |
65,290 |
|
1,4542 |
65,333 |
|
1,4543 |
65,375 |
|
1,4544 |
65,417 |
|
1,4545 |
65,460 |
|
1,4546 |
65,502 |
|
1,4547 |
65,544 |
|
1,4548 |
65,587 |
|
1,4549 |
65,629 |
|
1,4550 |
65,672 |
|
1,4551 |
65,714 |
|
1,4552 |
65,756 |
|
1,4553 |
65,798 |
|
1,4554 |
65,841 |
|
1,4555 |
65,883 |
|
1,4556 |
65,925 |
|
1,4557 |
65,967 |
|
1,4558 |
66,010 |
|
1,4559 |
66,052 |
|
1,4560 |
66,094 |
|
1,4561 |
66,136 |
|
1,4562 |
66,178 |
|
1,4563 |
66,221 |
|
1,4564 |
66,263 |
|
1,4565 |
66,305 |
|
1,4566 |
66,347 |
|
1,4567 |
66,389 |
|
1,4568 |
66,431 |
|
1,4569 |
66,473 |
|
1,4570 |
66,515 |
|
1,4571 |
66,557 |
|
1,4572 |
66,599 |
|
1,4573 |
66,641 |
|
1,4574 |
66,683 |
|
1,4575 |
66,725 |
|
1,4576 |
66,767 |
|
1,4577 |
66,809 |
|
1,4578 |
66,851 |
|
1,4579 |
66,893 |
|
1,4580 |
66,935 |
|
1,4581 |
66,977 |
|
1,4582 |
67,019 |
|
1,4583 |
67,061 |
|
1,4584 |
67,103 |
|
1,4585 |
67,145 |
|
1,4586 |
67,186 |
|
1,4587 |
67,228 |
|
1,4588 |
67,270 |
|
1,4589 |
67,312 |
|
1,4590 |
67,354 |
|
1,4591 |
67,396 |
|
1,4592 |
67,437 |
|
1,4593 |
67,479 |
|
1,4594 |
67,521 |
|
1,4595 |
67,563 |
|
1,4596 |
67,604 |
|
1,4597 |
67,646 |
|
1,4598 |
67,688 |
|
1,4599 |
67,729 |
|
1,4600 |
67,771 |
|
1,4601 |
67,813 |
|
1,4602 |
67,854 |
|
1,4603 |
67,896 |
|
1,4604 |
67,938 |
|
1,4605 |
67,979 |
|
1,4606 |
68,021 |
|
1,4607 |
68,063 |
|
1,4608 |
68,104 |
|
1,4609 |
68,146 |
|
1,4610 |
68,187 |
|
1,4611 |
68,229 |
|
1,4611 |
68,270 |
|
1,4613 |
68,312 |
|
1,4614 |
68,353 |
|
1,4615 |
68,395 |
|
1,4616 |
68,436 |
|
1,4617 |
68,478 |
|
1,4618 |
68,519 |
|
1,4619 |
68,561 |
|
1,4620 |
68,602 |
|
1,4621 |
68,643 |
|
1,4622 |
68,685 |
|
1,4623 |
68,726 |
|
1,4624 |
68,768 |
|
1,4625 |
68,809 |
|
1,4626 |
68,850 |
|
1,4627 |
68,892 |
|
1,4628 |
68,933 |
|
1,4629 |
68,974 |
|
1,4630 |
69,016 |
|
1,4631 |
69,057 |
|
1,4632 |
69,098 |
|
1,4633 |
69,139 |
|
1,4634 |
69,181 |
|
1,4635 |
69,222 |
|
1,4636 |
69,263 |
|
1,4637 |
69,304 |
|
1,4638 |
69,346 |
|
1,4639 |
69,387 |
|
1,4640 |
69,428 |
|
1,4641 |
69,469 |
|
1,4642 |
69,510 |
|
1,4643 |
69,551 |
|
1,4644 |
69,593 |
|
1,4645 |
69,634 |
|
1,4646 |
69,675 |
|
1,4647 |
69,716 |
|
1,4648 |
69,757 |
|
1,4649 |
69,798 |
|
1,4650 |
69,839 |
|
1,4651 |
69,880 |
|
1,4652 |
69,921 |
|
1,4653 |
69,962 |
|
1,4654 |
70,003 |
|
1,4655 |
70,044 |
|
1,4656 |
70,085 |
|
1,4657 |
70,126 |
|
1,4658 |
70,167 |
|
1,4659 |
70,208 |
|
1,4660 |
70,249 |
|
1,4661 |
70,290 |
|
1,4662 |
70,331 |
|
1,4663 |
70,372 |
|
1,4664 |
70,413 |
|
1,4665 |
70,453 |
|
1,4666 |
70,494 |
|
1,4667 |
70,535 |
|
1,4668 |
70,576 |
|
1,4669 |
70,617 |
|
1,4670 |
70,658 |
|
1,4671 |
70,698 |
|
1,4672 |
70,739 |
|
1,4673 |
70,780 |
|
1,4674 |
70,821 |
|
1,4675 |
70,861 |
|
1,4676 |
70,902 |
|
1,4677 |
70,943 |
|
1,4678 |
70,984 |
|
1,4679 |
71024 |
|
1,4680 |
71,065 |
|
1,4681 |
71,106 |
|
1,4681 |
71,146 |
|
1,4683 |
71,187 |
|
1,4684 |
71,228 |
|
1,4685 |
71,268 |
|
1,4686 |
71,309 |
|
1,4687 |
71,349 |
|
1,4688 |
71,390 |
|
1,4689 |
71,431 |
|
1,4690 |
71,471 |
|
1,4691 |
71,512 |
|
1,4692 |
71,552 |
|
1,4693 |
71,593 |
|
1,4694 |
71,633 |
|
1,4695 |
71,674 |
|
1,4696 |
71,714 |
|
1,4697 |
71,755 |
|
1,4698 |
71,795 |
|
1,4699 |
71,836 |
|
1,4700 |
71,876 |
|
1,4701 |
71,917 |
|
1,4702 |
71,957 |
|
1,4703 |
71,998 |
|
1,4704 |
72,038 |
|
1,4705 |
72,078 |
|
1,4706 |
72,119 |
|
1,4707 |
72,159 |
|
1,4708 |
72,199 |
|
1,4709 |
72,240 |
|
1,4710 |
72,280 |
|
1,4711 |
72,320 |
|
1,4712 |
72,361 |
|
1,4713 |
72,401 |
|
1,4714 |
72,441 |
|
1,4715 |
72,482 |
|
1,4716 |
72,522 |
|
1,4717 |
72,562 |
|
1,4718 |
72,602 |
|
1,4719 |
72,643 |
|
1,4720 |
72,683 |
|
1,4721 |
72,723 |
|
1,4722 |
72,763 |
|
1,4723 |
72,803 |
|
1,4724 |
72,843 |
|
1,4725 |
72,884 |
|
1,4726 |
72924 |
|
1,4727 |
72,964 |
|
1,4728 |
73,004 |
|
1,4729 |
73,044 |
|
1,4730 |
73,084 |
|
1,4731 |
73,124 |
|
1,4732 |
73,164 |
|
1,4733 |
73,204 |
|
1,4734 |
73,244 |
|
1,4735 |
73,285 |
|
1,4736 |
73,325 |
|
1,4737 |
73,365 |
|
1,4738 |
73,405 |
|
1,4739 |
73,445 |
|
1,4740 |
73,485 |
|
1,4741 |
73,524 |
|
1,4742 |
73,564 |
|
1,4743 |
73,604 |
|
1,4744 |
73,644 |
|
1,4745 |
73,684 |
|
1,4746 |
73,724 |
|
1,4747 |
73,764 |
|
1,4748 |
73,804 |
|
1,4749 |
73,844 |
|
1,4750 |
73,884 |
|
1,4751 |
73,924 |
|
1,4752 |
73,963 |
|
1,4753 |
74,003 |
|
1,4754 |
74,043 |
|
1,4755 |
74,083 |
|
1,4756 |
74,123 |
|
1,4757 |
74,162 |
|
1,4758 |
74,202 |
|
1,4759 |
74,242 |
|
1,4760 |
74,282 |
|
1,4761 |
74,321 |
|
1,4762 |
74,361 |
|
1,4763 |
74,401 |
|
1,4764 |
74,441 |
|
1,4765 |
74,480 |
|
1,4766 |
74,520 |
|
1,4767 |
74,560 |
|
1,4768 |
74,599 |
|
1,4769 |
74,639 |
|
1,4770 |
74,678 |
|
1,4771 |
74,718 |
|
1,1772 |
74,758 |
|
1,4773 |
74,797 |
|
1,4774 |
74,837 |
|
1,4775 |
74,876 |
|
1,4776 |
74,916 |
|
1,4777 |
74,956 |
|
1,4778 |
74,995 |
|
1,4779 |
75,035 |
|
1,4780 |
75,074 |
|
1,1781 |
75,114 |
|
1,4782 |
75,153 |
|
1,4783 |
75,193 |
|
1,4784 |
75,232 |
|
1,4785 |
75,272 |
|
1,4786 |
75,311 |
|
1,4787 |
75,350 |
|
1,4788 |
75,390 |
|
1,4789 |
75,429 |
|
1,4790 |
75,469 |
|
1,4791 |
75,508 |
|
1,4792 |
75,547 |
|
1,4793 |
75,587 |
|
1,4794 |
75,626 |
|
1,4795 |
75,666 |
|
1,4796 |
75,705 |
|
1,4797 |
75,744 |
|
1,4798 |
75,784 |
|
1,4799 |
75,823 |
|
1,4800 |
75,862 |
|
1,4801 |
75,901 |
|
1,4802 |
75,941 |
|
1,4803 |
75,980 |
|
1,4804 |
76,019 |
|
1,4805 |
76,058 |
|
1,4806 |
76,098 |
|
1,4807 |
76,137 |
|
1,4808 |
76,176 |
|
1,4809 |
76,215 |
|
1,4810 |
76,254 |
|
1,4810 |
76,294 |
|
1,4812 |
76,333 |
|
1,4813 |
76,372 |
|
1,4814 |
76,411 |
|
1,4815 |
76,450 |
|
1,4816 |
76,489 |
|
1,4817 |
76,528 |
|
1,4818 |
76,567 |
|
1,4819 |
76,607 |
|
1,4820 |
76,646 |
|
1,4821 |
76,685 |
|
1,4822 |
76,724 |
|
1,4823 |
76,763 |
|
1,4824 |
76,802 |
|
1,4825 |
76,841 |
|
1,4826 |
76,880 |
|
1,4827 |
76,919 |
|
1,4828 |
76,958 |
|
1,4829 |
76,997 |
|
1,4830 |
77,036 |
|
1,4831 |
77,075 |
|
1,4832 |
77,113 |
|
1,4833 |
77,152 |
|
1,4834 |
77,191 |
|
1,4835 |
77,230 |
|
1 4336 |
77269 |
|
1,4837 |
77,308 |
|
1,4838 |
77,347 |
|
1,4839 |
77,386 |
|
1,4840 |
77,425 |
|
1,4841 |
77,463 |
|
1,4842 |
77,502 |
|
1,4843 |
77,541 |
|
1,4844 |
77,580 |
|
1,4845 |
77,619 |
|
1,4846 |
77,657 |
|
1,4847 |
77,696 |
|
1,4848 |
77,735 |
|
1,4849 |
77,774 |
|
1,4850 |
77,812 |
|
1,4851 |
77,851 |
|
1,4852 |
77,890 |
|
1,4853 |
77,928 |
|
1,4854 |
77,967 |
|
1,4855 |
78,006 |
|
1,4856 |
78,045 |
|
1,4857 |
78,083 |
|
1,4858 |
78,122 |
|
1,4859 |
78,160 |
|
1,4860 |
78,199 |
|
1,4861 |
78,238 |
|
1,4862 |
78,276 |
|
1,4863 |
78,315 |
|
1,4864 |
78,353 |
|
1,4865 |
78,392 |
|
1,4866 |
78,431 |
|
1,4867 |
78,469 |
|
1,4868 |
78,508 |
|
1,4869 |
78,546 |
|
1,4870 |
78,585 |
|
1,4871 |
78,623 |
|
1,4872 |
78,662 |
|
1,4873 |
78,700 |
|
1,4874 |
78,739 |
|
1,4875 |
78,777 |
|
1,4876 |
78,816 |
|
1,4877 |
78,854 |
|
1,4878 |
78,892 |
|
1,4879 |
78,931 |
|
1,4880 |
78,969 |
|
1,4881 |
79,008 |
|
1,4882 |
79,046 |
|
1,4883 |
79,084 |
|
1,4884 |
79,123 |
|
1,4885 |
79,161 |
|
1,4886 |
79,199 |
|
1,4887 |
79,238 |
|
1,4888 |
79,276 |
|
1,4889 |
79,314 |
|
1,4890 |
79,353 |
|
1,4891 |
79,391 |
|
1,4892 |
79,429 |
|
1,4893 |
79,468 |
|
1,4894 |
79,506 |
|
1,4895 |
79,544 |
|
1,4896 |
79,582 |
|
1,4897 |
79,620 |
|
1,4898 |
79,659 |
|
1,4899 |
79,697 |
|
1,4900 |
79,735 |
|
1,4901 |
79,773 |
|
1,4902 |
79,811 |
|
1,4903 |
79,850 |
|
1,4904 |
79,888 |
|
1,4905 |
79,926 |
|
1,4906 |
79,964 |
|
1,4907 |
80,002 |
|
1,4908 |
80,040 |
|
1,4909 |
80,078 |
|
1,4910 |
80,116 |
|
1,4911 |
80,154 |
|
1,4912 |
80,192 |
|
1,4913 |
80,231 |
|
1,4914 |
80,269 |
|
1,4915 |
80,307 |
|
1,4916 |
80,345 |
|
1,4917 |
80,383 |
|
1,4918 |
80,421 |
|
1,4919 |
80,459 |
|
1,4920 |
80,497 |
|
1,4921 |
80,534 |
|
1,4922 |
80,572 |
|
1,4923 |
80,610 |
|
1,4924 |
80,648 |
|
1,4925 |
80,686 |
|
1,4926 |
80,724 |
|
1,4927 |
80,762 |
|
1,4928 |
80,800 |
|
1,4929 |
80,838 |
|
1,4930 |
80,876 |
|
1,4931 |
80,913 |
|
1,4932 |
80,951 |
|
1,4933 |
80,989 |
|
1,4934 |
81,027 |
|
1,4935 |
81,065 |
|
1,4936 |
81,103 |
|
1,4937 |
81,140 |
|
1,4938 |
81,178 |
|
1,4939 |
81,216 |
|
1,4940 |
81,254 |
|
1,4941 |
81,291 |
|
1,4942 |
81,329 |
|
1,4943 |
81,367 |
|
1,4944 |
81,405 |
|
1,4945 |
81,442 |
|
1,4946 |
81,480 |
|
1,4947 |
81,518 |
|
1,4948 |
81,555 |
|
1,4949 |
81,593 |
|
1,4950 |
81,631 |
|
1,4951 |
81,668 |
|
1,4952 |
81,706 |
|
1,4953 |
81,744 |
|
1,4954 |
81,781 |
|
1,4955 |
81,819 |
|
1,4956 |
81,856 |
|
1,4957 |
81,894 |
|
1,4958 |
81,932 |
|
1,4959 |
81,969 |
|
1,4960 |
82,007 |
|
1,4961 |
82,044 |
|
1,4962 |
82,082 |
|
1,4963 |
82,119 |
|
1,4964 |
82,157 |
|
1,4965 |
82,194 |
|
1,4966 |
82,232 |
|
1,4967 |
82,269 |
|
1,4968 |
82,307 |
|
1,4969 |
82,344 |
|
1,4970 |
82,381 |
|
1,4971 |
82,419 |
|
1,4972 |
82,456 |
|
1,4973 |
82,494 |
|
1,4974 |
87,531 |
|
1,4975 |
82,569 |
|
1,9976 |
82,606 |
|
1,4977 |
82,643 |
|
1,4978 |
82,681 |
|
1,4979 |
82,718 |
|
1,4980 |
82,755 |
|
1,4981 |
82,793 |
|
1,4982 |
82,830 |
|
1,4983 |
82,867 |
|
1,4984 |
82,905 |
|
1,4985 |
82,942 |
|
1,4986 |
82,979 |
|
1,4987 |
83,016 |
|
1,4988 |
83,054 |
|
1,4989 |
83,091 |
|
14990 |
83,128 |
|
1,4991 |
83,165 |
|
1,4992 |
83,202 |
|
1,4993 |
83,240 |
|
1,4994 |
83,277 |
|
1,4995 |
83,314 |
|
1,4996 |
83,351 |
|
1,4997 |
83,388 |
|
1,4998 |
83,425 |
|
14999 |
83,463 |
|
1,5000 |
83,500 |
|
1,5001 |
83,537 |
|
1,5002 |
83,574 |
|
1,5003 |
83,611 |
|
1,5004 |
83,648 |
|
1,5005 |
83,685 |
|
1,5006 |
83,722 |
|
1,5007 |
83,759 |
|
1,5008 |
83,796 |
|
1,5009 |
83,833 |
|
1,5010 |
83,870 |
|
1,5011 |
83,907 |
|
1,5012 |
83,944 |
|
1,5013 |
83,981 |
|
1,5014 |
84,018 |
|
1,5015 |
84,055 |
|
1,5016 |
84,092 |
|
1,5017 |
84,129 |
|
1,5018 |
84,166 |
|
1,5019 |
84,203 |
|
1,5020 |
84,240 |
|
1,5021 |
84,277 |
|
1,5022 |
84,314 |
|
1,5023 |
84,351 |
|
1,5024 |
84,388 |
|
1,5025 |
84,424 |
|
1,5026 |
84,461 |
|
1,5027 |
84,498 |
|
1,5028 |
84,535 |
|
1,5029 |
84,572 |
|
1,5030 |
84,609 |
|
1,5031 |
84,645 |
|
1 5032 |
84,682 |
|
1,5033 |
84,719 |
|
1,5034 |
84,756 |
|
1,5035 |
84,792 |
|
1,5036 |
84,829 |
|
1,5037 |
84,866 |
|
1,5038 |
84,903 |
|
1,5039 |
84,939 |
|
1,5040 |
84,976 |
|
1,5041 |
85,013 |
|
1,5042 |
85,049 |
|
1,5043 |
85,086 |
|
1,5044 |
85,123 |
|
1,5045 |
85,159 |
|
1,5046 |
85,196 |
|
1,5047 |
85,233 |
|
1,5048 |
85,269 |
|
1,5049 |
85,306 |
|
1,5050 |
85,343 |
|
1,5051 |
85,379 |
|
1,5052 |
85,416 |
|
1,5053 |
85,452 |
|
1,5054 |
85,489 |
|
1,5055 |
85,525 |
|
1,5056 |
85,562 |
|
1,5057 |
85,598 |
|
1,5058 |
85,635 |
|
1,5059 |
85,672 |
|
1,5060 |
85,708 |
|
1,5061 |
85,744 |
|
1,5062 |
85,781 |
|
1,5063 |
85,817 |
|
1,5064 |
85,854 |
|
1,5065 |
85,890 |
|
1,5066 |
85,927 |
|
1,5067 |
85,963 |
|
1,5068 |
86,000 |
|
1,5069 |
86,036 |
|
1,5070 |
86,072 |
|
1,5071 |
86,109 |
|
1,5072 |
86,145 |
|
1,5073 |
86,182 |
|
1,5074 |
86,218 |
|
1,5075 |
86,254 |
|
1,5076 |
86,291 |
|
1,5077 |
86,327 |
|
1,5078 |
86,363 |
|
1,5079 |
86,399 |
[1] Xxxxxxx x x xxxxxx xxxxxxxxx jsou vypočteny xxxxxx rovnice, jejímž xxxxxxx pro XXXXXX xx X. Xxxxxxxxxx. Xxxxxxx xxxx xxxxxxxxxxxxxx x xxxxxxx provedeny Xxxxxxx X. Xxxxxxxxxxx x XXXX x xxxx publikovány x Xxxxx J. 33, 15-22 (červen 1970). Xxxxx xxxx xxx xxxxx při 20 °X xxxxxx D xxxx Xx. Brix (xxxxxxxx xxxxxxxxxx xxxxxxxxx) xxx xxxxxx vážením xxx 20 °X xx xxxxxxx xxx xxxxx 760 xxxxx (xx Hg) a xxxxxxxxxxxxxxxxx xxxxxxxxx vlhkosti. Xxxx xxxxxxx xxxxxxxxx xxxxxxx předchozí (47&xxxx;012, xxxxxx 11) publikovanou x Intern. Sugar X. 39, 22 (1937).
XXXXXX 4
XXXXXXXXX REDUKUJÍCÍCH XXXXX XXXXXXXXXXX XXXX XXXXXXXX XXXXX
(Xxxxxx podle xxxxxx Xxxxxx Xxxxxxxx)
1. Xxxxxxx x oblast xxxxxxx
Xxxxxx xxxxxx xx xxxxxxxxx xxxxxxxxxxxx xxxxx xxxxxxxxxxx jako invertní xxxx x xxxxx xxxxxxxxx
2. Definice
„Redukující xxxxx xxxxxxxxx xxxx xxxxxxxx xxxx“: obsah xxxxxxxxxxxx xxxxx xxxxxxxxx xxxxxxxx xxxxxxx.
3. Podstata xxxxxx
Xxxxxx xxxxxx x obsahem xxxxxxxxxxxx xxxxx se xxxxxxx xxx xxxxxxx xxxxxxx xxxxxxxx mědi XX. Xxxxxxx xxxx xxxxx xx xxx xxxxxxx odměrným xxxxxxxx xxxx (xx xxxxxx xxxxxx), xxxxx přebytek xx stanoví xxxxxxx xxxxxxx xxxxxxxx roztokem xxxxxxxxxx xxxxxxx (xx xxxxxx titrem).
4. Xxxxxxx xxxxxxx
4.1 Xxxxxx Xx XX (Mullerův roztok)
4.1.1 Xx 400 xx xxxxxx xxxx xx xxxxxxxx 35 g xxxxxx měďnatého xxxxxxxxxxxx (XxXX4 5H2O) a xxxxx xx xxxxxxxxxxx.
4.1.2 X 500 xx xxxxxx xxxx xx xxxxxxxx 173 g xxxxxx sodnodraselného xxxxxxxxxxxx (Xxxxxxxxxx nebo Xxxxxxxxxxx xxx, XXxX4X4X6,4X2X) x 68 x xxxxxxxxx xxxxxxxxxx xxxxxxx x xxxxx xx xxxxxxxxxxx.
4.1.3 Xxx xxxxxxx (4.1.1 x 4.1.2) se xxxxxxxx xx xxxxxxx xxxxxxx xxxxx x xxxxxx xx xxxxx xx 1 litru. Xx xxxxxxx 2 x aktivního xxxx xx xxxxx xxxxxxxx, xxxxx se xxxxxxx xxxxx xxxx x xxxx xx xxxxxxxxxxx xxxx hustý xxxxxxxx xxxx xxxxxxxxxx xxxxx.
Xxxxx xx v xxxxxxx xxxxxxxxxx xxxxxxx xxxxxx xxxx xxxxxxxx xxxxx xxxxxxx, xx xxxxx xxxxxx xxxxx xxxxxxxxxxxx.
4.2 Xxxxxxxx xxxxxx, xxxxxx 5 xxx/x.
4.3 Roztok xxxx, 0,01665 mol/l (0,0333X; 4,2258 g/l).
4.4 Xxxxxx thiosíranu xxxxxxx, xxxxxx 0,0333 mol/l.
4.5 Xxxxxx škrobu: xx xxxxx xxxxxx xxxx xx xxxxxxx xxxx 5 g xxxxxxxxxxx xxxxxx rozmíchaného xx 30 xx xxxx, xxxxxx se 3 xxxxxx x xxxxx xxxxxxxxxxx. X případě xxxxxxx se přidá 10 mg jodidu xxxxxxxxxx xxxx konzervačního xxxxxxx.
5. Přístroje x xxxxxxx
5.1 Xxxxxxxxxxxxx baňka, 300 xx; přesné xxxxxx a pipety.
5.2 Xxxxx xxxxx, vroucí.
6. Xxxxxx
6.1 Xx 300 xx Erlenmeyerovy baňky xx xxxxxx xxxx xxxxxx (10 x xxxx xxxx), xxxxx xxxxxxxxxx xxxx než 30 mg xxxxxxxxxx xxxxx, x rozpustí xx xxxxxxxxx xx 100 xx xxxx.
Xx xxxxx s xxxxxxxx xxxxxx xx xxxxxxxxxx 10 ml xxxxxxx Xx XX (4.1), xxxxx xx krouživým xxxxxxx xxxxxxx x xxxxx xx xxxxx xx xxxxxx vodní xxxxx (5.2) xx xxxx xxxxxx 10 xxxxx.
Xxxxxxx roztoku x Xxxxxxxxxxxxx xxxxx xxxx xxx xxxxxxx 20 xx xxx xxxxxx xxxxxxx xx vodní xxxxx. Baňka xx xxxxxx xxxxxxx xxxxxxx xxxxxxx xxxx, přičemž xx xxxxxx nesmí xxxxxxxxxxx, aby xxxxxxx x xxxxxxxx xxxxxxx xxxxxxxxxxx xxxxx xxxxxxx xxxxxxxx kyslíkem.
Bez xxxxxxxxxxxx xxxxxx xx xxxxxxx xxxxx 5 xx xxxxxxx kyseliny xxxxxx (4.2) x koncentraci 5 xxx/x x xxxxx poté se xxxxxxx xxxxx xxxxxxxx (20 až 40 xx) xxxxxxx xxxx (4.3) x xxxxxxxxxxx 0,016 65 mol/l.
Sraženina xxxx xx xxxxxxxx xxxxxxxx x xxxxxxxx xxxx xx xxxxxxx xxxxxxxx thiosíranu sodného (4.4) x xxxxxxxxxxx 0,0333 xxx/x xxx xxxxxxx xxxxxxx škrobu (4.5) xxxx indikátoru. Xxxxxxxxx se přidává xx xxxxx xxxxxxx.
6.2 X xxxxx xx xxxxxxx xxxxx xxxxx, xxxxx se opakuje xxxx při použití xxxxxx xxxxxxx Xx XX (4.4). Xxxxxxxx xxxxxxxx nepřekročí 0,1 xx.
6.3 X cukerným xxxxxxxx xx xx xxxxxx provede xxxxxxxxx xxxxxxx. Xxxxxx xx xxxxx xxxx xxx xxxxxxxxxxx xxxxxxx xx xxxx 10 xxxxx, xxx mohlo dojít x reakci xxxxxx, xxxxxxxxxx přítomných redukujících xxxxx, jako xx xxxxxxxxx xxxx xxxxxxxx.
7. Xxxxxxxxx xxxxxxxx
7.1 Xxxxxx x xxxxxx xxxxxxx
Xxxxx xxxxxxxxxxxxxx xxxxxxx xxxx xx xxxxx xxxxxx (xx) xxxxxxxx xxxxxxxxx xxxxxxx xxxx (0,016 65 xxx/x) minus xxxxx (xx) roztoku xxxxxxxxxx sodného (0,0333 xxx/x) spotřebovaného při xxxxxxx.
Xxxxx (xx) xxxxxxxxxxxxxx xxxxxxx xxxx (0,016 65 xxx/x) xx xxxxxx xxxxxxxxx:
7.1.1 počtu xx xxxxxxxxxxxxxx xxx xxxxxx xxxxxx x xxxxx (6.2),
7.1.2 počtu xx xxxxxxxxxxxxxx xxx xxxxxxxxx xxxxxxx s xxxxxxxx roztokem za xxxxxx (6.3),
7.1.3 xxxxxx 2,0 xx na xxxxxxx 10 x xxxxxxxxx xxxxxxxx x xxxxxxxx alikvotním xxxxxx xxxx xxxxxxxx xxxxxxxx, xxxxxxxx-xx xxxxxx méně xxx 10 x xxxxxxxxx (xxxxxxx xx xxxxxxxxx).
Xx provedení xxxxxx xxxxxxx odpovídá xxxxxxxx 1 xx xxxxxxxx xxxxxxx (4.3) 1 xx xxxxxxxxxx xxxxx.
Xxxxx xxxxxxxxxx xxxxx x xxxxxxxxxx vzorku se xxxxxxxx podle xxxxxx:
xxx:
X1 = počet ml xxxxxxxx roztoku (4.3) xx korekci,
m0 = xxxxxxxx použitého xxxxxx (x).
7.2 Xxxxxxxxxxxxxx
Xxxxxx xxxx xxxxxxxx xxxx stanovení xxxxxxxxxxx zároveň xxxx xxxxxx za xxxxx x xxxxx vzorku xxxxxx xxxxxxxxxxx za xxxxxxxxx podmínek nesmí xxx xxxxx xxx 0,02 x xx 100 g xxxxxx.
XXXXXX 5
XXXXXXXXX REDUKUJÍCÍCH XXXXX XXXXXXXXXXX XXXX XXXXXXXX XXXX
(Xxxxxx xxxxx Xxxxxxx x Xxxxxx)
1. Xxxxxxx x xxxxxx xxxxxxx
Xxxxxx xxxxxx ke xxxxxxxxx xxxxxxxxxxxx xxxxx xxxxxxxxxxx xxxx xxxxxxxx xxxx
- x xxxxx nebo x cukru xxxxx,
- x xxxxx xxxxx xxxxx.
2. Xxxxxxxx
„Xxxxxxxxxx cukry xxxxxxxxx xxxx invertní xxxx“: xxxxx xxxxxxxxxxxx xxxxx stanovený popsanou xxxxxxx.
3. Podstata metody
K xxxxxxx vzorku xx xxxxx x xxxxxxxx xxxxxxx s obsahem Xx II, zredukovaný x nezredukovaný xxxxx xx xxx xxxxxxx xxxxxxx xxxxxxx x xxxxxxxx XXXX.
4. Xxxxxxx xxxxxxx
4.1 Kyselina ethylendiamintetraoctová (xxxxxxxxx sůl) (EDTA), xxxxxx 0,0025 xxx/x: xxxxxxxx se 0,930 x EDTA xx xxxx a doplní xx xxxxx do xxxxxxx litru.
4.2 Xxxxxx xxxxxxxxxx xxxxxxxx: 0,25 x xxxxxxxx xx xxxxx xx 50 xx xxxx a xxxxxx se x 20 xx xxxxxxx xxxxxxx methylenové xxxxx x xxxxxxxxxxx 0,2 x/100 xx.
4.3 Alkalické xxxxxxx xxxxxxx: x 600 ml vody xxxxxxxxxx 40 xx xxxxxxxxx xxxxxxx x xxxxxxxxxxx 1,0 xxx/x xx xxxxxxxx 25 x bezvodého xxxxxxxxxx xxxxxxx a 25 x vinanu sodnodraselného xxxxxxxxxxxx. Přibližně x 100 ml xxxx xx xxxxxxxx 6,0 x síranu xxxxxxxxx – xxxxxxxxxxxx (XxXX4 5X2X), vzniklý roztok xx xxxxx x xxxxxxx xxxxxx x xxxxxx vodou do xxxxxxx xxxxx.
Xxxxxxxx: Roztok xx omezenou xxxxxxxxxxx (xxxxx týden).
4.4 Xxxxxxxxxx xxxxxx invertního xxxxx: x xxxxxxx baňce x objemu 250 xx xx xxxxxxxx 23,750 g xxxxx xxxxxxxxx (4.5) xxx xx 120 xx xxxx. Xxxxx se 9 ml xxxxxxxx xxxxxxxxxxxxxx (X20 = 1,16) x xxxxx xx stát při xxxxxxxxxxx teplotě xx xxxx 8 dní. Xxxxxx xx doplní xx 250 xx x xxxxxxxx xxxxxxxxx xx xxxxxxxxxxx xxxxxxx xx xxxxxxxxxxx xxxx xxxxxxxxxxxx xxx xxxxxxx xxxxxxx o xxxxx 200 xx. Zjištěná xxxxxxx xx má xxxxxx 11,80 ± 0,05°X (xxx poznámka 8). 200 ml xxxxxx roztoku xx xxxxxxxxxx xx odměrné xxxxx x xxxxxx 2000 xx, zředí xx vodou x xx xxxxxxx protřepávání (xxx xxxxxxx x xxxxxxxxxx xxxxxxxx xxxxxxxxxxxxx xxxxxxx) xx přidá 71,4 xx roztoku xxxxxxxxx xxxxxxx (1 xxx/x), ve xxxxxx xxxx rozpuštěny 4 x kyseliny benzoové. Xxxxxx xx doplní xx 2000 xx, xx. xxx xxxxxxxxx 1 x xxxxxxxxxx xxxxx xx 100 xx; xxxxxxx pH xxxxxxx se xx xxxxxxxxx xxxxx 3.
Xxxxx xxxxx xxxxxxx roztok xx xxxx pouze xxxxxxxxxxxxx před xxxxxxxx.
4.5 Xxxxx xxxxxxxxx: xxxxxx xxxxx xxxxxxxxx x xxxxxxx invertního cukru xxxxxxx 0,001 x/100 x.
5. Xxxxxxxxx x xxxxxxx
5.1 Xxxxxxxx 150 x 20 mm.
5.2 Xxxx porcelánová miska.
5.3 Xxxxxxxxxx xxxx xxxxxx x xxxxxxxxx na 0,1 mg.
6. Xxxxxx
6.1 Xx xxxxxxxx (5.1) xx xxxxxxxx 5 x xxxxxx cukru x 5 xx xxxxxxx xxxx, přidají xx 2,0 xx xxxxxxxxx xxxxxxx (4.3) x obsah se xxxxxxxx. Xxxxxxxx xx xxxxxx xx lázně x xxxxxx xxxxx xx xxxx 5 xxxxx x xxxx xx ve xxxxxxx xxxx xxxxxxx.
6.2 Roztok xx xx xxxxxxxx xxxxxxxxxxxxx, x použitím xx nejmenšího množství xxxx, převede do xxxx porcelánovou xxxxx (5.2), xxxxxxx xx xxx xxxxx indikátoru (4.2) x xxxxxxx xx xxxxxxxx XXXX (4.1). Xxxxxxxx xxxxxxxx x xx se xxxxxx xxxx X0.
Xxxxx xxxx ukončením xxxxxxx xx xxxxx xxxxxxx xxxxx xx xxxxxx xxxx xxxxx xx xxxxxxxxxx x xxxxxxxx xxxx. Xxxxxxxxx xxxxx xxxxxx xxxx x xxxxxxxx xxxxxxx xxxxx xxxxxxx na oxid xxxxxxx xxxxxxxx oxidace xxxxxx xx koncentraci xxxxxxxx xxxxxxxxxxx xxxx. Xxxxx xx při xxxxxxx nutné xxxxxxxxx xxxxxxxxx xxxx xx xxxxx xxxxxxxxxxx.
6.3 Sestrojí xx kalibrační křivka xx xxxxxxx xxxxxxxxx xxxxxxx xxxxxxxx invertního xxxxx (xxxxxxxxx xxxxxxx xxxxxx 4.4) x 5 x čisté xxxxxxxxx (4.5) x xxxxxxxxxxxxxx xxxxxxxx xxxxxxx xxxx xxx, xxx xxxxxxx xxxxx přidaného xxxxxxx xxxxx 5 xx. Xxxxxxxx spotřeba (xx) se xxxxxx xx xxxxx xxxxx xxxxxxxxxxx xxxxxx xxxxxxxxxx xxxxx xxxxxxxxx x 5 g xxxxxxxxx; xxxxxxxxx xxxxxxx je xxxxxx x xxxxxxx 0,001 xx 0,019 x xx 100 x xxxxxxxxxx xxxxx, xxxx. 100 x xxxxxx.
7. Xxxxxxxxx xxxxxxxx
7.1 Xxxxxx xxxxxxx
X kalibrační xxxxxx xx xxxxxx xxxxx xxxxxxxxxx xxxxx (x xxxxxxxxxx) odpovídající xxxxxxxx XXXX X0 xx xxx xxxxxxx xxxxxx.
7.2 Pokud xx xxxxxxxxxxx xxxxx xxxxxxxxxxx xxx 0,017 x xxxxxxxxxx cukru ve 100 x xxxxxxxxxxxxx xxxxxx, musí xx xxxxxxxxx snížit množství xxxxxx x bodě 6.1, analyzovaný xxxxxx xx xxxx musí xxxxxxx do 5 x xxxxxx sacharosou (4.5).
7.3 Xxxxxxxxxxxxxx
Xxxxxx mezi xxxxxxxx xxxx stanovení xxxxxxxxxxx xxxxxxx xxxx xxxxxx za sebou x téhož vzorku xxxxxx xxxxxxxxxxx xx xxxxxxxxx xxxxxxxx nesmí xxx xxxxx xxx 0,005 x xx 100 x vzorku.
8. Xxxxxxxx
Xxx xxxxxxx xxxxxxx xx °S xx xxxxxxxxxxxxxx xxxxxx xxxxxx xx xxxxxxx xxxxxxx x °X xxxx 2,889 (polarimetrická xxxxxxx x xxxxx 200 xx; xxxxxxxx xxxxxxx xxxx xxxxxxxx xxxxx; xxxxxxxx xxxxxxxx x xxxxxxxxx, xx xxxxx xx xxxxx xxxxxxxx xxxxxxx kolem 20 °X).
XXXXXX 6
XXXXXXXXX REDUKUJÍCÍCH XXXXX VYJÁDŘENÝCH JAKO XXXXXXXX XXXX XXXX XXXXXXXXXX XXXXXXXXXX
(Xxxxxx xxxxx Xxxxx a Xxxxxxxx)
1. Xxxxxxx x oblast xxxxxxx
Xxxxxx xxxxxx xx xxxxxxxxx
1.1 xxxxxx xxxxxxxxxxxx xxxxx xxxxxxxxxxx xxxx xxxxxxxx xxxx
- x xxxxxxx xxxxx,
- x xxxxxxx bílém xxxxx,
- x xxxxxxx xxxxxxxxx xxxxx,
- x tekutém xxxxx xxxxxxxxx xxxxx,
- x xxxxxx x xxxxxxxxxx xxxxx,
- x xxxxxx z xxxxxxxxxx xxxxx xxxxxx;
1.2 xxxxxx xxxxxxxxxxxx cukrů xxxxxxxxxxx x vypočteného (xxxxxxxx xx xxxxxx) xxxx xxxxxxxxxx xxxxxxxxxx
- ve xxxxxxxxx xxxxxx,
- x xxxxxxx škrobovém xxxxxx;
1.3 xxxxxx xxxxxxxxxxxx cukrů xxxxxxxxxxx jako X-xxxxxxx
- x xxxxxxxx xxxxxxxxxxx,
- x dextrose bezvodé.
2. Xxxxxxxx
„Xxxxxxxxxx xxxxx xxxxxxxxx xxxx xxxxxxxx xxxxx, X-xxxxxxx xxxx jako xxxxxxxxxx ekvivalent": obsah xxxxxxxxxxxx cukrů xxxxxxxxx xxxx xxxxxxxxx xxxx xxxxxxxx cukr, Xxxxxxxx xxxx xxxxxxxxxx ekvivalent xxxxxxxxx popsanou metodou.
3. Xxxxxxxx xxxxxx
Xxxxxx s xxxxxxxxxxxx xxxxx se xxxxxx (x x xxxxxxx potřeby xxxxxx) xx xxxxxxxxxxxx xxxxxxxx x xxxx varu x roztokem Xx XX, xxxxx xx xxxxxxxx xxxxxxxx na Xx I. Přebytek Xx XX se xxxx stanoví xxxxxxxxxxxx.
4. Xxxxxxx činidla
4.1 Xxxxxxxx xxxxxx I: 21,95 x xxxxxx xxxxxxxxxxx xxxxxxxxx, (Xx(XX3XXX)22X2X) nebo 24 g octanu xxxxxxxxxxx trihydrátu, (Xx(XX3XXX)2-3X2X) xx spolu s xxxxxxxxx 3 ml xxxxxx kyseliny xxxxxx xxxxxxxx xx xxxx x xxxxxx vodou xx 100 ml.
4.2 Xxxxxxxx roztok XX: 10,6 x hexakyanoželeznatanu xxxxxxxxxx trihydrátu (X4[Xx(XX)6]-3X2X) xx xxxxxxxx xx xxxx x xxxxxx xxxxx xx 100 xx.
4.3 Luffovo-Schoorlovo činidlo: xxxxxxxx se xxxx xxxxxxx:
4.3.1 Xxxxxx xxxxxx xxxxxxxxx: 25 g xxxxxx měďnatého pentahydrátu (XxXX45X2X) xxxxxxxxxxxxxx xxxxxx xx xxxxxxxx ve 100 xx xxxx.
4.3.2 Xxxxxx xxxxxxxx citrónové: 50 g xxxxxxxx xxxxxxxxx monohydrátu (X6X8X7-X2X) xx xxxxxxxx v 50 xx vody.
4.3.3 Xxxxxx uhličitanu sodného: 143,8 x xxxxxxxxx xxxxxxxxxx xxxxxxx xx xxxxxxxx xxxxxxxxx x 300 xx horké xxxx x xxxxx xx vychladnout.
4.3.4 K xxxxxxx uhličitanu xxxxxxx (4.3.3) x litrové xxxxxxx baňce xx xx mírného xxxxxxxxxxxx xxxxxxxxx pohybem xxxxxxx xxxxxx kyseliny citronové (4.3.2). Obsah xx xxxxx, xxxxx xx xxxxxxxxxx vyvíjet xxxx, xxx xx xxxxx xxxxxx síranu xxxxxxxxx (4.3.1) x xxxxx xx xxxxxx xx 1000 ml. Roztok xx nechá stát xxxx noc, x xxxxxxx xxxxxxx xx xxxxx přefiltruje. Xxxxxxx xx xxxxxxxx xxxxxxxx xxxxxxx činidla xxxxx xxxxxx xxxxxxx x xxxx 6.1 (Cu 0,1 xxx/x; Xx2XX3 1 xxx/x).
4.4 Roztok xxxxxxxxxx, 0,1 mol/l.
4.5 Xxxxxx škrobu: xx xxxxxxx xxxxx xxxxxx xxxx xx přilije 5 g xxxxxxxxxxx xxxxxx rozmíchaného xx 30 xx vody. Xxxxxx xx 3 xxxxxx a xxxxx xx xxxxxxxxxxx; je-li xxxxx, xxxxx se 10 xx jodidu xxxxxxxxxx xxxx xxxxxxxxxxx xxxxxxx.
4.6 Kyselina sírová, 3 xxx/x.
4.7 Roztok xxxxxx xxxxxxxxxx, 30 % (x/X).
4.8 Xxxxxx xxxxx, xxxxxxxx x xxxxxxxx chlorovodíkové, xxxxxxx xxxxx do xxxxxxxx xxxxxx xxxxxx x xxxxxxxx.
4.9 Xxxxxxxxxxx.
4.10 Xxxxxxxx xxxxx, 0,1 mol/l.
4.11 Xxxxxxxx xxxxxxxxxxxxxx, 0,1&xxxx;&xxxx;&xxxx; xxx/x.
4.12 Xxxxxxxxxxx, jednoprocentní xxxxxx (x/X) x xxxxxxxx.
5. Xxxxxxxxx a xxxxxxx
5.1 Xxxxxxxxxxxxx xxxxx, x objemu 300 xx, xx xxxxxxx xxxxxxxxx.
5.2 Stopky.
6. Xxxxxx
6.1 Xxxxxxxxx xxxxx Luffova-Schoorlova xxxxxxx (4.3):
6.1.1 Xx 25 xx Luffova-Schoorlova xxxxxxx (4.3) xx xxxxxxx 3 x xxxxxx xxxxxxxxxx x 25 xx xxxxxxxx xxxxxx x koncentraci 3 xxx/x (4.6).
Xxxxxxx xx xxxxxxxx thiosíranu xxxxxxx x xxxxxxxxxxx 0,1 xxx/x (4.4) xx xxxxxxx xxxxxxxxxx xxxxxxx (4.5) xxxx xxxxxxxxxx, který xx xxxxx xx xx xxxxx xxxxxxx. Pokud xxxx xxxxxxxx roztoku xxxxxxxxxx o koncentraci 0,1 xxx/x xxxxx 25 xx, xxxx xxx xxxxxxx připraveno xxxxx.
6.1.2 Xxxxxxxxxx se 10 xx xxxxxxx xx 100ml xxxxxxx xxxxx x po xxxxx xx doplní xxxxx.
10 ml xxxxx xxxxxxxxx činidla se xxxxxxxxxx do Xxxxxxxxxxxxx xxxxx xxxxxxxxxx 25 xx kyseliny xxxxxxxxxxxxxx x koncentraci 0,1 xxx/x (4.11) x xxxxxxx xx xx xxxx jedné hodiny xx vroucí xxxxx xxxxx. Pak xx xxxxxx xxxxxxx, doplní xx xx xxxxxxx xxxxx čerstvě xxxxxxxxxx xxxxx x titruje xxxxxxxx xxxxxxxxx xxxxxxx x xxxxxxxxxxx 0,1 xxx/x (4.10) za xxxxxxx xxxxxxxxxxxxx (4.12) xxxx indikátoru.
Spotřeba xxxxxxx xxxxxxxxx xxxxxxx, 0,1 xxx/x (4.10) xxxx xxx xxxx 5,5 x 6,5 ml.
6.1.3 10 ml xxxxxxxxx xxxxxxx (6.1.2) se xxxxxxx xxxxxxxxx xxxxxxxxxxxxxxx, 0,1 xxx/x (4.11) xx xxxxxxx fenolftaleinu (4.12) xxxx xxxxxxxxxx. Xxxxxxx xxx titrace xx xxxxxxxxxxxxxxx xxxxxxx xxxxxxxxx xxxxxxxx.
Xxxxxxxx roztoku xxxxxxxx chlorovodíkové, 0,1 xxx/x (4.11) musí xxx xxxx 6,0 x 7,5 ml.
6.1.4 Xxxxxxx pH Xxxxxxx-Xxxxxxxxxx xxxxxxx xxxx xxx xxxx 9,3 a 9,4 při 20 °X.
6.2 Xxxxxxxx roztoku
6.2.1 Xxxxxx se 5 x xxxxxx x xxxxxxxxx na 1 xx a xxxxxxxxxxxxx xx xxxxxxx do xxxxxxx baňky o xxxxxx 250 ml xxxxxxxxxx 200 ml xxxx. X xxxxxxx xxxxxxx xx xxxxxx xxxxxxxx 5 xx Xxxxxxxxx xxxxxxx I (4.1), xxx se xxxxx 5 xx Xxxxxxxxx xxxxxxx II (4.2). Xx přídavku xxxxxxx xxxxxxx se xxxxx xxxxxxx. Xxxxxx xx xxxxxx xxxxx xx 250 ml x xxxxx xxxxxxxx. X případě xxxxxxx xx roztok xxxxxxxxxxx.
6.2.2 Xxxxxx (6.2.1) xx xxxxx x xxxxxxx xxxxxx, xxx obsah xxxxxxxxxxxx cukrů xxxxxxxxxxx xxxx xxxxxxx se x 25 xx xxxxxxx xxxxxxxxx x xxxxxxx 15 xx 60 xx.
6.3 Xxxxxxx xxxxx Xxxxxxx-Xxxxxxxxxx metody
Do 300 xx Xxxxxxxxxxxxx xxxxx (5.1) xx xxxxxxxxxx 25 ml Xxxxxxx-Xxxxxxxxxx xxxxxxx (4.3), xx xxxxx se xxx pipetou xxxxxx 25 ml cukerného xxxxxxx (6.2.2) a xxxxx xx xxx xxxxxx xxxxx (4.8). X xxxxx (5.1) xx xxxxxxx zpětný xxxxxxx x aparatura xx xxxxx umístí xx xxxxxxxx xxxxxxxxxx xxxxx nad xxxxxx Xxxxxxxxx kahanu. Xxxxx xx x xxxxxxxxx xxxxx xxxxxxxxx kruhový xxxxx x xxxxxx xxxxxxx, xxxx xx xxx baňky. Xxxxxxxx xx přibližně xxxxx xxxx xxxxx uvede xx xxxx x xxxxx xx xxxxxx 10 xxxxx mírně xxxxx. Xxx xx xxxxx xxxxxxx ve xxxxxxx vodě a xx pěti xxxxxxxx xx titruje podle xxxxxx xxxxxxx:
Xxxxx se 10 ml xxxxxxx xxxxxx xxxxxxxxxx (4.7), xxxxxxxxxxxxx poté se xxxxx xxxxxxx (x xxxxxxx xx xxxxxxxx xxxxx xxxxx) 25 xx kyseliny xxxxxx x xxxxxxxxxxx 3 xxx/x (4.6). Xxxxxxx xx xxxxxxxx xxxxxxxxxx xxxxxxx x xxxxxxxxxxx 0,1 xxx/x (4.4), xxxxx se xxxxxx xxxxx xxxxxxxxx, xxx xx přidá xxxx xxxxxxxxx xxxxxxx xxxxxxxxx xxxxxxx xxxxxx (4.5) x xxxxxxxxx xx x xxxxxxx až xx xxxxxxxx xxxxxxx xxxxxxxx.
Xxxxxxx xx xxxxx xxxxx x 25 xx vody místo 25 ml xxxxxxxxx xxxxxxx (6.2.2).
7. Xxxxxxxxx xxxxxxxx
7.1 Xxxxxx a xxxxxx xxxxxxx
X xxxx xxxxxxx xxxxxxx se xxxxxx (xxxxxxxx xx xxxxxxx xxxxxxxxxxx) hmotnost xxxxxxx xxxx invertního xxxxx v xx, xxxxxxxxxxxx xxxxxxx mezi xxxxx xxxxxxxxxx spotřebami, xxxxxxxxxxx x xx xxxxxxx xxxxxxxxxx xxxxxxx x koncentraci 0,1 xxx/x.
Xxxxxxxx xx xxxxxxx x xxxxxxxxxx (m/m) xxxxxxxxxx xxxxx xxxx X-xxxxxxx, xxxxxxxxxx xx xxxxxx.
7.2 Xxxxxxxxxxxxxx
Xxxxxx xxxx xxxxxxxx xxxx xxxxxxxxx xxxxxxxxxxx xxxxxxx xxxx xxxxxx za sebou x xxxxx xxxxxx xxxxxx xxxxxxxxxxx xx xxxxxxxxx xxxxxxxx xxxxx xxx větší xxx 0,2 xx.
8. Xxxxxxxx
Xxxx xxxxxxxxxx xxxxxxxxx xxxxxxx xx může xxxxxx xxxx množství xxxxxxxxxxxx (4.9), xxx xx xxxxxxx xxxxxx xxxx.
Xxxxxxx xxxxxx pro Xxxxxxx – Xxxxxxxxxx činidlo
|
0,1 xxx/x Xx2X2X3 |
Xxxxxxx, fruktosa, xxxxxxxx xxxx C6H12O6 |
|
|
ml |
mg |
rozdíl |
|
1 |
2,4 |
|
|
2 |
4,8 |
2,4 |
|
3 |
7,2 |
2,4 |
|
4 |
9,7 |
2,5 |
|
5 |
12,2 |
2,5 |
|
6 |
14,7 |
2,5 |
|
7 |
17,2 |
2,5 |
|
8 |
19,8 |
2,6 |
|
9 |
22,4 |
2,6 |
|
10 |
25,0 |
2,6 |
|
11 |
27,6 |
2,6 |
|
12 |
30,3 |
2,7 |
|
13 |
33,0 |
2,7 |
|
14 |
35,7 |
2,7 |
|
15 |
38,5 |
2,8 |
|
16 |
41,3 |
2,8 |
|
17 |
44,2 |
2,9 |
|
18 |
47,1 |
2,9 |
|
19 |
50,0 |
2,9 |
|
20 |
53,0 |
3,0 |
|
21 |
56,0 |
3,0 |
|
22 |
59,1 |
3,1 |
|
23 |
62,2 |
3,1 |
METODA 7
XXXXXXXXX REDUKUJÍCÍCH CUKRŮ XXXXXXXXXXX XXXX INVERTNÍ XXXX
(Xxxxxx xxxxx Xxxxx x Eynona – xxxxxxxxxx x xxxxxxxxxxx xxxxxxx)
1. Předmět x xxxxxx použití
Metoda xxxxxx xx xxxxxxxxx xxxxxxxxxxxx xxxxx xxxxxxxxxxx xxxx xxxxxxxx xxxx
- x xxxxxxx cukru,
- v xxxxxxx xxxxx xxxxx,
- x xxxxxxx xxxxxxxxx xxxxx,
- x xxxxxxx xxxxx xxxxxxxxx cukru,
- x xxxxxx x xxxxxxxxxx xxxxx,
- x xxxxxx z invertního xxxxx xxxxxx.
2. Xxxxxxxx
"Xxxxxxxxxx xxxxx xxxxxxxxx xxxx xxxxxxxx cukr": xxxxx xxxxxxxxxxxx xxxxx xxxxxxxxx xxxxxxxx metodou.
3. Podstata xxxxxx
Xxxxxxxx xxxxxxxxxx xxxxxx xx xxxxxxx za xxxx xxxx určité xxxxxxxx Xxxxxxxxxx roztoku x xxxxxxxx methylenové xxxxx xxxx indikátoru.
4. Xxxxxxx xxxxxxx
4.1 Fehlingův xxxxxx:
4.1.1 Roztok A:
69,3 x xxxxxx xxxxxxxxx xxxxxxxxxxxx (CuSO4·5H2O) se xxxxxxxx xx xxxx x xxxxxx xx xx 1000 xx.
4.1.2 Xxxxxx X:
346,0 x xxxxxx xxxxxxxxxxxxxxx tetrahydrátu (XXxX4X4X6·4X2X) x 100 x xxxxxxxxx xxxxxxx xx rozpustí ve xxxx x xxxxxx xx 1000 xx. Xxxx xxxxxx xx xxxxxx dekantací xx xxxxxxxxx, která xx xxxx někdy vytvořit.
Poznámka:
Tyto xxx roztoky xx xxxxx xxxxxxxxx x xxxxxxx xxxx xxxxxxxxx xxxxxxxxxx lahvích.
4.2 Xxxxxx xxxxxxxxx xxxxxxx, 1 xxx/x.
4.3 Xxxxxxxxxx roztok xxxxxxxxxx xxxxx: 23,750 x čisté sacharosy xx rozpustí asi xx 120 xx xxxx ve 250xxxxxxxxxxx xxxxxxx baňce, přidá xx 9 xx xxxxxxxx xxxxxxxxxxxxxx (xxxxxxx 1,16 x/xx) x xxxxx xx xxxx xxx xxxxxxxxxxx xxxxxxx xx xxxx 8 xxx. Xxxxxx se xxxxxx do 250 xx x xxxxxxxx xxxxxxxxx xx xxxxxxxxxxx xxxxxxxxxxxx xxxx xxxxxxxxxxxxx xxxxxx xxxxxxx xxxxx 200 xx. Xxxxxxxx xxxxxxx xx má xxxxxx 11,80 ± 0,05 °X (xxx xxxxxxxx 8). 200 xx tohoto xxxxxxx xx xxxxxxxxxx xx 2000xxxxxxxxxxx odměrné xxxxx, xxxxx xx xxxxx x za xxxxxxx xxxxxxxxxxxx (aby xxxxxxx x nadměrnému xxxxxxxx xxxxxxxxxxxxx roztoku) se xxxxx 71,4 xx xxxxxxx xxxxxxxxx sodného x xxxxxxxxxxx 1 xxx/x (4.2), xx xxxxxx jsou xxxxxxxxxx 4 g xxxxxxxx xxxxxxxx. Xxxxx xx xxxxxx xx 2000 xx, xxx xxxxxxxx xxxxxx xxxxxxxxx 1 x xxxxxxxxxx cukru xx 100 xx. Xxxxxxx xX roztoku xx být xxxxxxxxx xxxxx 3.
Xxxxx xxxxxxxx xxxxxxx roztok xx xx xxx xxxxx xx těsně xxxx xxxxxxxx.
Xxx xxxxxxxx xxxxxxx xxxxxxxxxx cukru o xxxxxxxxxxx 0,25 x/100 xx xx 250ml xxxxxxx xxxxx naplní xx xxxxx xxxxxxxx xxxxxxxx x koncentraci 1 x/100 xx xxx 20 °X. Xxxxx se kvantitativně xxxxxxx xx 1000 xx xxxxxxx xxxxx x xxxxxx se xxx 20 °C xx rysku xxxxx.
4.4 Xxxxxx xxxxxxxxxxx xxxxx, 1 g/100 xx.
5. Xxxxxxxxx x xxxxxxx
5.1 Xxxxx baňky s xxxxx hrdlem o xxxxxx 500 xx.
5.2 Xxxxxx o xxxxxx 50 xx, dělená xx 0,05 ml, x xxxxxxxxxx xxxxxxxx.
5.3 Xxxxxx x xxxxxxx xx 20, 25 x 50 xx.
5.4 Xxxxxxx baňky x xxxxxx 250, 1000 x 2000 xx.
5.5 Xxxxxxxx x ohřevu, xxxxxx xxx udržování xxxx xx podmínek xxxxxxxxx x bodě 6.1 x umožňující xxxxxxxx barevnou změnu x xxxxxxxx xxxx, xxxx xx xx xxxxx xxxxx (5.1) xxxxxx xxxxxxxxx xx xxxxxx tepla.
5.6 Xxxxxx xxxxxxxxx x přesností xxxxxxx na 1 xxxxxxx.
6. Postup
6.1 Xxxxxxxxx xxxxx Fehlingova roztoku
6.1.1 Xx čisté a xxxxx xxxxxxx xx xxxxxxxxxx 50 ml xxxxxxx B (4.1.2), xxxx 50 xx xxxxxxx A (4.1.1) x xxxxx xx xxxxxxxx.
6.1.2 Xxxxxx xx xxxxxxxxxx a xxxxxx 0,25 % (0,25 x/100 xx) xxxxxxxxxxx xxxxxxxx invertního xxxxx (4.3).
6.1.3 Xx 500 xx xxxxx xxxxx (5.1) xx xxxxxxxxxx xxxxxxxxx podíl 20 xx xxxxxxxx xxxxxxx X x X (6.1.1) x xxxxxxx xx 15 xx xxxx. Z xxxxxx xx xx baňky xxxxxx 39 ml xxxxxxx xxxxxxxxxx xxxxx, xxxxx xx xxxxxxx xxxxxxx xxxxxxx x xxxxx xx xxxxxx xxxxxxxxx xxxxxxx xxxxxxxx.
6.1.4 Xxxxx xxxxx xx xxxxxxx x xxxx x xxxxx xx xxxxx xxxxxx xxx xxxxxx. Xxxxx xxxxxxx xxxxxxx se baňka xxxxx xxxxxxx ze xxxxxx tepla x xxxxx dojít x xxxxxxxxx xxxx.
Xx konci xxxxxxxxxxxxxx xxxx xx xxxxxxx xxx nebo xxxxx kapky xxxxxxx xxxxxxxxxxx xxxxx (4.4). Xxxxx xxxxxxx xxxx xxx výrazně xxxxx.
6.1.5 Xxxxxxxxx se x xxxxxxxxx xxxxxxxxxxxx xxxxxxx xxxxxxxxxx cukru x xxxxxx, xxxxxxxx xx 0,2 ml, xxx xx 0,1 ml x nakonec xx xxxxxxx, až xx xxxxxxx xxxxxxxxx xxxx. Xxx xx xxxxxxxxx xxxxxxxxx xxxxxxx xxxxxxxx xxxxxxxx xxxxxxxxxxx xxxxx. Xxxxx roztoku xx xxxxxxxxxxx následkem xxxxxxxxxxx xxxxxxxx xxxxx xxxxxxx.
6.1.6 Xxxxxxxxx xxxx titrace xx xxxx xxx xxxxxxxx do xxx xxxxx xx xxxxxxx xxxx xxxxxxx. Xxxxxxx xxxxxxxx V0 xx xxxx pohybovat x xxxxxxx 39,0 xx 41,0 xx. Xx-xx xxxxxxx V0 mimo xxxxxxx tohoto xxxxxxx, xxxxxx se koncentrace xxxx xx Xxxxxxxxxx xxxxxxx X (4.1.1) x xxxxxxxxx xxxxx xx xxxxxxx.
6.2 Xxxxxxxx xxxxxxx xxxxxx
Xxxxxxxxxxx xxxxxxx xxxxxxxxxx xxxxxx xx xx xxxxxxxxx x xxxxxxx 250 xx 400 xx xxxxxxxxxx xxxxx xx 100 xx.
6.3 Orientační xxxxxxx
6.3.1 Xx nutné xxxxxxx xxxxxxxxxx xxxxxxx ke xxxxxxxx potřebného xxxxxxxx xxxx x 20 xx směsného xxxxxxx X x B, xxxxx zajistí, xx xxxxxxx xxxxx po xxxxxxx xxxx činit 75 ml.
Postupuje xx xxxxxx xxxxx xxxxxx x xxxx 6.1.4, xxxxx xxxxx xxxxxxxxxxxx xxxxxxx xxxxxxxxxx xxxxx xx xxxxxxx xxxxxx xxxxxx, tj. do xxxxx xx byretou xxxxxx 25 ml xxxxxxx xxxxxx, xxxxx xx 15 xx xxxx, xxxxx xx 2 xxxxxx povařit x xxxxxx xx xxx titruje až xx dosažení xxxxxxxxx xxxx, jak xx xxxxxxx v bodě 6.1.5.
6.3.2 Xxxxx xx xxxxxxxx xxxxxxx methylenové xxxxx přetrvává xxxxxxxxxxx xxxxxxxx, je xxxxxxx xxxxxx vzorku xxxxxx xxxxxxxxxxxxx. V tomto xxxxxxx se zkouška xxxxxxx x xxxxxxx xx xxxxxxxxx xxxxxxxxx x xxxxx xxxxxxxxxxx xxxxxxx xxxxxx.
Xx-xx x xxxxxxxx načervenalého xxxxxxxx xxxxxxxxx více xxx 50 xx roztoku xxxxxx, musí se xxxxxx xxxxxx xxxxxx x vyšší xxxxxxxxxxx.
Xxxxxxxx xxxx, které se xx xxxxxx, xx xxxxxxxx odečtením xxxxxx xxxxxxxx Xxxxxxxxxx roztoku (20 ml) a xxxxxx xxxxxxx xxxxxx xx 75 xx.
6.4 Xxxxxxx analýza xxxxxxx xxxxxx
6.4.1 Xx varné xxxxx xx xxxxxxxxxx 20 xx xxxxxxxx Xxxxxxxxxx xxxxxxx x xxxxxxxx xxxx xxxxxxxxx xxxxx xxxx 6.3.
6.4.2 X xxxxxx xx xxxxxx xxxxxx xxxxxx x xxxxxxxx xxxxxxxxxx xxxxx bodu 6.3, xxxxxxxx x 1 xx. Xxxxx se xxxxxxx varných xxxxxxx, xxxxx baňky xx xxxxxxxxx pohybem promíchá, xxxxxx x titruje xxxxx předchozího xxxxx (6.3). Xxxxxxxxx xxxx xxxxxxx musí být xxxxxxxx xxxxx minutu xx xxxxxxx xxxxxxx xxxxxxxxxxx modři. Spotřeba xxx xxxxxxx xxxxxxx xx xxxxx X1.
7. Xxxxxxxxx xxxxxxxx
7.1 Xxxxxx x xxxxxx výpočtu
Obsah xxxxxxxxxxxx xxxxx xx xxxxxx xxxxxxxxx jako xxxxxxxx cukr xx xxxxxxxx xxxxx vzorce:
kde:
C = koncentrace roztoku xxxxxxxxxx xxxxxx (x/100 xx),
X0 = spotřeba xxxxxxxxxxxx xxxxxxx invertního xxxxx (ml) xxx xxxxxxxxx xxxxx,
X1 = xxxxxxxx roztoku xxxxxxxxxx xxxxxx (xx) xxx xxxxxx analýze (6.4.2),
f = korekční xxxxxx xxxxxxxxxxxx koncentraci xxxxxxxxx xxxxxxxx x xxxxxxx xxxxxxxxxx xxxxxx; xxxxxxx xxxx uvedeny x xxxx xxxxxxx xxxxxxx:
|
Xxxxxxxxx (x xx xxxxx xxxxxxx xx xxxx) |
Xxxxxxxx xxxxxx f |
|
0,0 |
1,000 |
|
0,5 |
0,982 |
|
1,0 |
0,971 |
|
1,5 |
0,962 |
|
2,0 |
0,954 |
|
2,5 |
0,946 |
|
3,0 |
0,939 |
|
3,5 |
0,932 |
|
4,0 |
0,926 |
|
4,5 |
0,920 |
|
5,0 |
0,915 |
|
5,5 |
0,910 |
|
6,0 |
0,904 |
|
6,5 |
0,898 |
|
7,0 |
0,893 |
|
7,5 |
0,888 |
|
8,0 |
0,883 |
|
8,5 |
0,878 |
|
9,0 |
0,874 |
|
9,5 |
0,869 |
|
10,0 |
0,864 |
Korekce pro xxxx množství xxxxxxxxx x xxxxxxx xxxxxxxxxx xxxxxx se xxxxx xxxxxxxxx z xxxxxxxxxxx xxxxxx xxxxxxxxxxx.
Xxxxxxxx:
Xxxxxxxxx koncentrace xxxxxxxxx se xxxx xxxxxxxx xxxxxxxxx xxxxxxxxxxx xxxxxxxxxxxx xxxxxxx látek x xxxxxxxxxx xxxxx (xxx xxxxx výpočet xx použita xxxxxxx x xxxxx 1,0) xx xxxxxxxxxxx xxxxxxxxx xxxxxxxxxxxx látek xxxxxxxxxxx xxxx sacharosa a xxxxxxxxxxx na xxxxxxx xxxxxx xxxx xxxxx xxxxxx 3 xxxxxx xxxxxxxx.
7.2 Xxxxxxxxxxxxxx
Xxxxxx xxxx xxxxxxxx dvou xxxxxxxxx xxxxxxxxxxx zároveň xxxx xxxxxx xx sebou x xxxxx vzorku xxxxxx xxxxxxxxxxx za xxxxxxxxx podmínek nesmí xxx xxxxx xxx 1,0 % jejich xxxxxxxxxxxxx xxxxxxx.
8. Xxxxxxxx
Xxx xxxxxxx hodnoty ve °X na xxxxxxxxxxxxxx xxxxxx stupně xx xxxx xxxxxxx xxxxx x xxxxxxxxxx °X xxxx xxxxxxxx 2,889 (xxxxxxxxxxxxxx xxxxxxx x xxxxx 200 xx; xxxxxxxx xxxxxxx jako xxxxxxxx xxxxx; přístroj xxxxxxxx x místnosti, xx xxxxx je xxxxx udržovat xxxxxxx xxxxxxx 20 °X).
XXXXXX 8
XXXXXXXXX XXXXXXXXXXXX EKVIVALENTU
(Metoda xxxxx Lanea x Xxxxxx x konstantním xxxxxx)
1. Předmět x xxxxxx použití
Tato metoda xxxxxx xx stanovení xxxxxxxxxxxx xxxxxxxxxxx
- xx xxxxxxxxx sirupu,
- v xxxxxxx xxxxxxxxx xxxxxx,
- x xxxxxxxx xxxxxxxxxxx,
- x dextrose xxxxxxx.
2. Xxxxxxxx
2.1 "Xxxxxxxx xxxx": xxxxx redukujících xxxxx xxxxxxxxx xxxxxxxx xxxxxxx, xxxxxxxxx jako xxxxxxx xxxxxxxx (D-glukosa) x xxxxxxxxx v procentech xxxxxxxxx vzorku.
2.2 "Dextrosový xxxxxxxxxx": xxxxxxxx síla xxxxxxxxx v xxxxxxxxxx xxxxxxxxx xxxxxx vzorku.
3. Xxxxxxxx xxxxxx
Xxxxxxxx xxxxxxxxxx xxxxxx se xx xxxxxx určených xxxxxxxx xxxxxxx xx xxxx xxxx určitý xxxxx xxxxxxxx Xxxxxxxxxx roztoku x použitím xxxxxxxxxxx xxxxx xxxx xxxxxxxxxx.
4. Xxxxxxx činidla
4.1 Fehlingův xxxxxx:
4.1.1 Xxxxxx X:
Xx xxxx xx xxxxxxxx 69,3 g síranu xxxxxxxxx xxxxxxxxxxxx (XxXX4·5X2X) x x odměrné xxxxx x objemu 1000 ml xx xxxxxx xx rysku.
4.1.2 Xxxxxx X:
Xx xxxx xx rozpustí 346,0 x xxxxxx sodno-draselného xxxxxxxxxxxx (KNaC4H4O6·4H2O) x 100 x xxxxxxxxx xxxxxxx x x xxxxxxx baňce x xxxxxx 1000 xx xxxxxx xxxxx xx xxxxx. Xxxx xxxxxx xx xxxxxxxxx oddělí xx usazeniny, která xx může xxxxx xxxxxxxx.
Xxxxxxxx:
Xxxx xxx xxxxxxx (4.1.1 x 4.1.2) xx xxxxx xxxxxxxxx x xxxxxxx xxxx xxxxxxxxx xxxxxxxxxx xxxxxxx.
4.1.3 Xxxxxxxx směsného Xxxxxxxxxx xxxxxxx
Xx xxxxx xxxxxxx xx odpipetuje 50 xx xxxxxxx X (4.1.2) a xxxx 50 xx roztoku X (4.1.1) x xxxxx xx xxxxxxxxxx.
Xxxxxxxx:
Xxxxxx Xxxxxxxxx roztok xx xxxxx xxxxxxxxx, nýbrž xx musí xxxxx xxx připravovat čerstvý x xxxxxxxxxxxxxxx (6.1).
4.2 Xxxxxxx xxxxxxxx (D-glukosa) (X6X12X6)
Xxxxx xxxxxxxx je xxxxx xxxx xxxxxxxx 4 xxxxxx xxxxx xx xxxxxxx sušárně xxx teplotě 100 ± 1 °C xxxx xxxxx a xxx xxxxx xxx 10 xXx (103 xxxx).
4.3 Xxxxxxxxxx roztok xxxxxxxx, 0,600 g/100 xx
X xxxxxxxxx na 0,1 xx xx xxxxxx 0,6 x xxxxxxx xxxxxxxx (4.2), xxxxxxxx se xx xxxx, xxxxxxxxxxxxx xxxxxxx xx xxxxxxx xxxxx x objemu 100 xx (5.4), xxxxxx xxxxx xx xxxxx x xxxxxxxx.
Xxxxx roztok xx nutno připravit xxxxxxx na každý xxx, xxx bude xxxxxxxx.
4.4 Xxxxxx methylenové xxxxx, 0,1 x/100 xx xxxx
Xxxxxxxx xx 0,1 x xxxxxxxxxxx xxxxx xx 100 xx vody.
5. Xxxxxxxxx x pomůcky
5.1 Xxxxx xxxxx x xxxxx xxxxxx x xxxxxx 250 ml.
5.2 Byreta x xxxxxx 50 xx, s xxxxxxxxxx xxxxxxxx x dělená xx 0,05 ml.
5.3 Xxxxxx xxxxxxxx x xxxxxxx 25 ml x 50 xx.
5.4 Xxxxxxx xxxxx x xxxxxx 100 x 500 ml.
5.5 Xxxxxxxx x xxxxxx, xxxxxx xxx xxxxxxxxx varu x souladu x xxxxxxxxxx popsanými x xxxx 6.1 x xxxxxxxxxx xxxxxxxx xxxxxxxx xxxxx v konečném xxxx xxx xxxxxxxx xxxxxxx xxxxxx xxxxx (5.1) xx xxxxxx xxxxx (viz xxx 6.1 xxxxxxxx 3).
5.6 Xxxxxx xxxxxxxxx s xxxxxxxxx nejméně xx 1 xxxxxxx.
6. Xxxxxx
6.1 Xxxxxxxxxxxxx Fehlingova xxxxxxx
6.1.1 Xx xxxxx xxxxx xxxxx baňky (5.1) xx xxxxxxxxxx 25 xx Xxxxxxxxxx xxxxxxx (4.1.3).
6.1.2 Xxxxxx (5.2) xx xxxxxx standardním xxxxxxxx xxxxxxxx (4.3) x xxxxxxxx se xxxxxxx xx xxxxxxx xxxxx.
6.1.3 Xx xxxxx xxxxx (5.1) xx x xxxxxx xxxxxxx 18 xx xxxxxxxxxxxx xxxxxxx xxxxxxxx (4.3) x xxxxx xx xxxxxxxxx xxxxxxx promíchá.
6.1.4 Xxxxx baňka xx xxxxxx na xxxxxxxx x xxxxxx (5.5), xxxxxx xxxxxxxxx xxx, xxx xxx xxxxxx xx 120 ± 15 xxxxxx.
X celém xxxxxxx titrace nesmí xxx xxxxxxxx k xxxxxx nastavováno xxxxx (xxx poznámka 1).
6.1.5 Xxxxxxx xx xxxxxx xxxxx vařit, xxxxxx xx xxxxxx xx xxxx.
6.1.6 Xxxxx baňky xx povaří 120 xxxxxx (xxxxx xxxxxx).
Xx xxxxx se přidá 1 xx xxxxxxx xxxxxxxxxxx modři (4.4).
6.1.7 Xx 120 xxxxxxxxx (xxxxx xxxxxx) xx xxxxxxx xxxx xx xxxxx z xxxxxx (6.1.2) do xxxxx xxxxx (5.1) xxxxxxxx xxxxxxxxxx xxxxxx xxxxxxxx xx 0,5xx xxxxxxx, xxxxx xx methylenová xxxx xxxxxxxxx (viz xxxxxxxx 2 x 3).
Xxxxxxxxx xx celkový xxxxx xxxxxxxxx xxxxxxxxxxxx xxxxxxx dextrosy (X xx) xxxxxx předposlední 0,5xx dávky.
6.1.8 Xxxxx x xxxxxx 6.1.1 x 6.1.2 xx xxxxxxxx.
6.1.9 X xxxxxx xx do xxxxx xxxxx (5.1) napustí (X 0,3) ml xxxxxxxxxxxx roztoku xxxxxxxx.
6.1.10 Xxxxx v xxxxxx 6.1.4, 6.1.5 a 6.1.6 xx xxxxxxxx.
6.1.11 Xx 120 xxxxxxxxx (xxxxx stopek) od xxxxxxx xxxx xx xxxxx z xxxxxx xx xxxxx xxxxx (5.1) xxxxxxxx xxxxxxxxxx xxxxxx dextrosy, xxxxxxxx xx 0,2ml xxxxxxx x nakonec xx xxxxxxx, dokud xx xxxxxxxxxxx xxxx xxxxx xxxxxxxxx.
Xx xxxxx tohoto xxxxxxx musí xxx xxxx xxxx xxxxx xx xxxx xxxxxxxxxxxxx xxxxxxxx standardního xxxxxxx xxxxxxxx 10 až 15 xxxxxx.
Xxxx přidávání xxxx xxx xxxxxxxxx xxxxx 60 xxxxxx x xxxxxxx xxxx xxxx tedy xxxxx xxxxxxxxx 180 xxxxxx.
X xxxxxx xxxxx může xxx xxxxxxxxx provést xxxxx xxxxxxx x xxxxxxx větší, xxxxxxxxx xxxxxxxxx xxxxxxxxx xxxxxx xxxxxxxxxxxx xxxxxxx dextrosy (6.1.9).
6.1.12 Zaznamená xx xxxxxxx xxxxxxxx (V0 xx) xxxxxxxxxxxx xxxxxxx xxx závěrečné xxxxxxx (xxx xxxxxxxx 4).
6.1.13 Xxxxxxx V0 xxxx xxx x xxxxxxx 19,0 xx 21,0 xx xxxxxxxxxxxx xxxxxxx xxxxxxxx (4.3).
Xxxxx xx xxxxxxx X0 nachází xxxx xxxx xxxxxxx, xxxxxxxxx xx xxxxxx xxxxxxxxxxx Xxxxxxxxxx xxxxxxx X (4.1.1) a xxxxxxxxxxxxxx proces se xxxxxxxx.
6.1.14 Xxxxxxxx x xxxx, že hodnota X0 xx xxxxxx xxxxx, je xxxxx xxx každodenní xxxxxxxxxxxxx xxxxxxx xxxxx xxxxxxx x xxxxxxxxxx přídavkem xxxxxxxxxxxx roztoku dextrosy X0 – 0,5.
Xxxxxxxx 1:
Xxxxx xx zajištěno, xx xxxxxxx xxxxxxx xxx, vyvíjení xxxx xx xxxxxx x xxxxxxxxxxx xxxxx xxxx xxxxxxxx xxxxxxxxx x x xx xxxxxxxx xxxx se xxxxxxx xxxxxxxx xxxxxxx xx xxxxxxxx baňky x xxxxxxxx opětovné oxidaci xxxxxx obsahu.
Poznámka 2:
Xxxxxxxxx xxxxxxx xxxxxxxxxxx xxxxx xx xxxxxxx xxxxxxxxxxxxx x horních vrstvách xxxxxx xxxxxxxx xxxxx x v oblasti xxxxxxx, xx. x xxxxxxx, které v xxxxxxxx neobsahují xxxxxxx xxxxxxx xxxx xxxxxxx. Xxxxxxxxx xx xxxxxxxx xxxxxxxxxxxxx za xxxxxxxxx xxxxxxxxx. Xx xxxxxxx xxxxxx stínítko za xxxxxxxx baňkou.
Poznámka 3:
Xxxxxx xx měla xxx xxxxx xxxxxxxxx xx xxxxxxx xxxxxxxx xxxx xxxxxxx xxxxx.
Xxxxxxxx 4:
Vzhledem x xxxx, xx xxxxx xxxxx vyloučit xxxxxxxxxxx xxxxxx, xxxx xxxxx pracovník provádět xxxx xxxxxxx standardizační xxxxxxx x při xxxxxxx musí použít xxxx xxxxxxx hodnotu X0 (7.1).
6.2 Xxxxxxxxxx xxxxxxx připraveného vzorku
6.2.1 Xxxxx xxxx xxxxx xxxxxxxxx xxxxxxx xxxxxxxx xxxx (2.1) xxxxxxxxxxxx xxxxxx, je xxxxx xxxxxxx předběžnou xxxxxxx, xxx se xxxxxxx xxxx přibližná hodnota, x mohla xxx xxx xxxxxxxxx xxxxxxxx xxxxxxxxxx vzorku (6.3).
Xxxx xxxxxxx xx xxxxxxx xxxxx:
6.2.2 Připraví se X % (x/X) xxxxxx vzorku, "Z" xx přibližnou hodnotu.
6.2.3 Xxxxxxxxx se xxxx x bodě 6.1.2 x xxxxxxxx xxxxxxx xxxxxx (6.2.2) xxxxxxx xxxxxxxxxxxx roztoku xxxxxxxx.
6.2.4 Xxxxxxxxx se jako x xxxx 6.1.1.
6.2.5 Xxxxxxxxx se xxxx x bodě 6.1.3 x xxxxxxxx 10 xx roztoku xxxxxx xxxxxxx 18,0 ml xxxxxxxxxxxx xxxxxxx xxxxxxxx.
6.2.6 Xxxxxxxxx xx jako x bodě 6.1.4.
6.2.7 Xxxxx baňky xx xxxxxxx x varu. Xxxxx xx 1 xx xxxxxxx xxxxxxxxxxx xxxxx (4.4).
6.2.8 Xxxxxxx xxxxxxx var, xxxxxx xx xxxxxx (5.6) xx xxxx x xxxxx xxxxxxxxx roztoku xxxxxx z xxxxxx xx xxxxx xx 1,0 xx xxxxxxx x odstupem asi 10 xxxxxx, x xx xx xx xxxxxxxxx xxxxxxxxxxx xxxxx.
Xxxxxxxxx xx celková xxxxxxxx xxxxxxxxxxxx xxxxxxx dextrosy (X xx) včetně xxxxxxxxxxxx 0,5 ml xxxxx.
6.2.9 Xxxxxxx "Y" xxxxx přesáhnout 50 xx. Pokud k xxxx xxxxx, xx xxxxx xxxxxx koncentraci xxxxxxx xxxxxx x xxxxxxx zopakovat.
6.2.10 Přibližná xxxxxxx xxxxxxxx xxxx xxxxxxxxxxxx xxxxxx xx xxxxxxxxx xxxx xxxxxxx (x %):
6.3 Xxxxxxxx xxxxxx
X xxxxxxxxx xx 0,1 xx se xxxxxx xxxxxx xxxxxxxx xxxxxxxxxxxx xxxxxx (xx), xxxxx xxxxxxxx 2,85 xx 3,15 g xxxxxxxxxxxx xxxxx xxxxxxxxxxx xxxx xxxxxxx xxxxxxxx (Xxxxxxxx). Xxx xxxxxxx xx xxxxxxx buď xxxxx xxxxxxxxx xxxxxxx xxxxxxxx xxxx (2.1), xxxx přibližná hodnota xxxxxxx v bodě 6.2.10.
6.4 Xxxxxxxx xxxxxx
Xxxxxxxx xxxxxx xx x xxxxxxx baňce x xxxxxx 500 xx xxxxxxxx ve vodě x xxxxx xxxxxx xx xxxxx.
6.5 Stanovení
6.5.1 Xxxxxxxxx xx jako x xxxx 6.1.1.
6.5.2 Xxxxxx (5.2) xx xxxxxx zkušební roztokem (6.4) x meniskus xx xxxxxxx xx xxxx.
6.5.3 X byrety xx do varné xxxxx napustí 18,5 xx roztoku zkušebního xxxxxxx. Vířením xx xxxxx baňky zamíchá.
6.5.4 Xxxxxxxxx xx xxxx x xxxx 6.1.4.
6.5.5 Xxxxxxxxx se jako x xxxx 6.1.5.
6.5.6 Xxxxxxxxx se jako x bodě 6.1.6.
6.5.7 Xxxxxxxxx xx xxxx x bodě 6.1.7, x použitím xxxxxxxxxx xxxxxxx xxxxxxx standardního xxxxxxx xxxxxxxx.
6.5.8 Xxxxxxxxx xx jako x xxxx 6.1.8.
6.5.9 Xxxxxxxxx xx xxxx v xxxx 6.1.9, x xxxxxxxx xxxxxxxxxx xxxxxxx xxxxxxx xxxxxxxxxxxx roztoku xxxxxxxx.
6.5.10 Xxxxxxxxx xx xxxx v xxxx 6.1.10.
6.5.11 Xxxxxxxxx se xxxx x bodě 6.1.11, x použitím xxxxxxxxxx xxxxxxx xxxxxxx xxxxxxxxxxxx xxxxxxx xxxxxxxx.
6.5.12 Xxxxxxxxx xx objem (X1) xxxxxxxxxxxxxx xxxxxxxxxx xxxxxxx xxx xxxxxxxxx xxxxxxx.
6.5.13 Xxxxxxx X1 xxxx xxx x xxxxxxx 19,0 až 21,0 xx xxxxxxxxxx xxxxxxx.
Xxxxx se xxxxxxx X1 xxxxxxx xxxx xxxx xxxxxxx, upraví xx xxxxxxxxxxx xxxxxxxxxx xxxxxxx x kroky 6.5.1 xx 6.5.12 xx xxxxxxxx.
6.5.14 Xxxxxxxx xx dvě xxxxxxxxx x xxxxxxxx xxxxx xxxxxxxxxx xxxxxxx.
6.6 Obsah xxxxxx
Xxxxxx metody 2 xx xxxxxxx obsah xxxxxx připraveného xxxxxx.
7. Xxxxxxxxx xxxxxxxx
7.1 Xxxxxx x xxxxxx xxxxxxx
7.1.1 Xxxxxxxx síla
Redukční xxxx xxxxxxxxx x procentech xxxxxxxxxxxx připraveného xxxxxx xx xxxx xxxxxxx:
xxx
X0 = xxxxx (xx) xxxxxxxxxxxx roztoku xxxxxxxx (4.3) spotřebovaný xxx xxxxxxxxxxxxxx xxxxxxx (6.1),
X1 = objem (xx) xxxxxxxxxx roztoku (6.4) xxxxxxxxxxxxxx xxx titraci x postupu xxxxxxxxx (6.5),
X = xxxxxxxx xxxxxxxxxx xxxxxx (g) (6.3) xxxxxxxxx x xxxxxxxx 500 ml xxxxxxxxxx xxxxxxx.
7.1.2 Xxxxxxxxxx xxxxxxxxxx
Xxxxxxxxxx xxxxxxxxxx xxxxxxxxx x xxxxxxxxxx xxxxxxxxx xxxxxx připraveného vzorku xx dán výrazem:
kde
RP = xxxxxxxx xxxx xxxxxxxxx x xxxxxxxxxx xxxxxxxxxxxx xxxxxxxxxxxx xxxxxx (7.1.1),
X = obsah xxxxxx xxxxxxxxxxxx xxxxxx x procentech xxxxxxxxxxxx.
7.1.3 Xxxxxxxxx xx xxxxxxxxxxx xxxxxx xxxxxxxx xxxx xxxxxxxxx za předpokladu, xx xx splněn xxxxxxxxx xxxxxxx na xxxxxxxxxxxxxx (7.2).
7.2 Xxxxxxxxxxxxxx
Xxxxxx xxxx výsledky xxxx xxxxxxxxx provedených xxxxxxx xxxx rychle za xxxxx z xxxxx xxxxxx xxxxxx pracovníkem xx xxxxxxxxx xxxxxxxx xxxxx xxx xxxxx xxx 1,0 % xxxxxx aritmetického xxxxxxx.
XXXXXX 9
XXXXXXXXX SÍRANOVÉHO XXXXXX
1. Xxxxxxx x xxxxxx xxxxxxx
Xxxxxx xxxxxx xx xxxxxxxxx xxxxxx síranového xxxxxx
- xx škrobovém xxxxxx,
- v sušeném xxxxxxxxx sirupu,
- x xxxxxxxx monohydrátu,
- x xxxxxxxx bezvodé.
2. Xxxxxxxx
"Xxxxx xxxxxxxxxx xxxxxx": xxxxx xxxxxxxxxx xxxxxx xxxxxxxxx xxxxxxxx xxxxxxx.
3. Xxxxxxxx xxxxxx
Xx xxxxxxxxxx xxxxxxx xxxxxxxxxx vzorku x xxxxxxxx atmosféře při 525 °C za xxxxxxxxxxx xxxxxxxx sírové xx xxxxxxxxx jeho xxxxxxxx xxxxxxxx x xx vyjádřena x xxxxxxxxxx xxxxxxxxxxxx xxxxxx.
4. Xxxxxxx xxxxxxx
4.1 Xxxxxxxx xxxxxx, xxxxxxx roztok: xxxxxx x opatrně xx xxxxxxx 100 xx koncentrované xxxxxxxx xxxxxx (xxxxxxx při 20 °X = 1,84 x/xx; 96 % m/m) xx 300 ml xxxx xx xxxxxxxxxx xxxxxxx x chlazení.
5. Xxxxxxxxx x pomůcky
5.1 Xxxxxxxxxx xxxxxxx pec, vybavená xxxxxxxxxx a umožňující xxxxxx při xxxxxxx 525 ± 25 °X.
5.2 Analytické váhy, xxxxxx s přesností xx 0,1 mg.
5.3 Xxxxxxx xxx stanovení xxxxxx, xxxxxxxxx či xxxxxxxx, vhodného xxxxxx.
5.4 Xxxxxxxxx xxxxxxxxxx xxxxxxx xxxxxxxxxx xxxxxxxxx xxxx xxxxxxxxxxxx xxxxxxxxxx x xxxxxxxxxxx obsahu vlhkosti.
6. Xxxxxx
Xxxxxxx (5.3) xx xxxxxx xx xxxxxxxxxxxx xxxxxxx, xxxxxxx xx x xxxxxxxxxx vychladnout x zváží xx. Xx kelímku xx xxxxxx (xx 0,1 xx) xxxxxx 5 x xxxxxxxxxx xxxxxx xxxx xxxxxxxx škrobového xxxxxx, xxxxxxxx 10 x xxxxxxxx xxxxxxxxxxx xxxx dextrosy bezvodé.
Přidá xx 5 xx xxxxxxx xxxxxxxx xxxxxx (4.1) (xxx poznámka 8.1) x vzorek xx x xxxxxxx xxxxxxx xxxxxxx xxx xxxxxxxx nebo na xxxxx plotýnce xxx xxxxxx, dokud xxxxx xxxxxxxxxxx. Xxxxxxxxxxx, xxxxx xxxxx odhořívají xxxxxx xx vzorku (xxx xxxxxxxx 8.2), xx xxxx xxxxxxxx x xxxxxxxxx.
Xxxxxxx (5.3) se xxxxxx xx xxxxxxx xxxx (5.1), xxxxxxxxxx xx 525 ± 25 °X, x xxxxxxx xx x xx, dokud nevznikne xxxx xxxxx. To xxxxxxx xxxx dvě xxxxxx (viz xxxxxxxx 8.3).
Xxxxxx xx xxxxx xxx 30 minut xxxxxxxxxxx x xxxxxxxxxx (5.4) a xxxx xx xxxxx.
7. Xxxxxxxxx xxxxxxxx
7.1 Xxxxxx x xxxxxx výpočtu
Obsah síranového xxxxxx vyjádřený x xxxxxxxxxx hmotnostních vzorku xxxxxxxx x xxxxxxx xx dán vzorcem:
kde
m1 = hmotnost xxxxxx (x),
x0 = xxxxxxxx xxxxxxx xxxxxxxxxx xxxxxx (x).
7.2 Xxxxxxxxxxxxxx
Xxxxxx xxxx xxxxxxxx dvou stanovení xxxxxxxxxxx xxxxxxx nebo xxxxxx xx sebou x xxxxx vzorku xxxxxx pracovníkem xx xxxxxxxxx xxxxxxxx nesmí xxx xxxxx než 2,0 % jejich xxxxxxxxxxxxx xxxxxxx.
8. Xxxxxxxx
8.1 Xxxxxxxx sírová xx xxxxxxx xx xxxxxx xxxxxxx, xxx xx xxxxxxxxx xxxxxxxxxx pěnění.
8.2 Xxx xxxxxx xxxxxxxxxxx xx třeba xxxxxxxxxx xxxxxxxx obezřetně, xxx xxxxxxx xx xxxxxxx xxxxxx xxxx xxxxxx xxxxx přílišnému xxxxxxxx xxxxxx.
8.3 Xxxxx xx xxxxxxx xxxxxxxxx xxxxxxx xxxxxxxxxx (xx. zůstávají xxxxx xxxxxxx), xxxxxxx xx xxxxx x xxxxxxx xxxx xxxxxxx, xxxxxx xx xxxxxxxxx xxxxxxx xxxxxxxx xxxxxxx xxxx x xxxx xxxxxx do xxxx.
XXXXXX 10
XXXXXXXXX XXXXXXXXXX
1. Xxxxxxx x xxxxxx xxxxxxx
Xxxxxx xxxxxx ke xxxxxxxxx xxxxxxxxxx
- x cukru xxxxxxxxx,
- x xxxxx xxxx v cukru xxxxx,
- x xxxxx xxxxx xxxxx.
2. Xxxxxxxx
Xxxxxxxxxx xx xxxxxx schopnost xxxxxxxxx xxxxxxx xxxxxxxxxxxx 26 x cukru xx 100 xx, xxxxx je uzavřen x xxxxxxx x xxxxx 200 mm, xxxxxx rovinu polarizovaného xxxxxx.
3. Xxxxxxxx xxxxxx
Xxxxxxxxxx xx xxxxxxx xxxxxx xxxxxxxxxxxx nebo xxxxxxxxxxx xx xxxxxxxx xxxxxxxxx x níže xxxxxxx xxxxxx.
4. Xxxxxxx xxxxxxx
4.1 Xxxxxx xxxxxxx: xxxxxxx xxxxxx xxxxxx xxxxxxxxxx.
Xx xxx 1000 xx xxxxxxx xxxxxxxxx xxxx xx přidá 560 x xxxxxxx bazického xxxxxx olovnatého. Směs xx 30 xxxxx xxxx x poté xx nechá xxxx xxxx noc.
Tekutý xxxxxxxxxxx xx xxxxxxxxx a xxxxx čerstvě xxxxxxxxxx xxxxx tak, aby xxxxxx roztok o xxxxxxx 1,25 x/xx (xxx 20 °X).
Xxxxx xxxxxx xx xxxxx xxxxxxx xxxx xxxxxxxxx xxxxxxx.
4.2 Xxxxxxxxxxxx
5. Xxxxxxxxx x xxxxxxx
5.1 Xxxxxxxxxxx xxxxxxxxxxxx xx normální xxxxxxxx 26 x xxxxxxxxx, popřípadě xxxxxxxxxx
Xxxxx xxxxxxxx xxxx xxx xxxxxxx v xxxxxxxxx, xx xxxxx xx xxxxx xxxxxxxx xxxxxxx xxxxx 20 °X. Xxxxxxxx xx xxxxxxxxxx xxxxxx xxxxxxxxxxxx xxxxxxxxxx xxxxx.
5.2 Xxxxxxxx zdroj xxxxxxxxxxx xx sodíkové xxxxxxx.
5.3 Přesné xxxxxxxxxxxxxx xxxxxxx x xxxxx 200 xx x xxxxxxxxx ± 0,02 xx.
5.4 Analytické xxxx, xxxxxx x přesností xx 0,1 xx.
5.5 Xxxxxxxxxx kalibrované xxxxxxx xxxxx x xxxxxx 100 ml se xxxxxxx. Xxxxx se xxxxxxxxx xxxxxxx v xxxxxxx 100,00 ± 0,01 xx mohou xxx použity bez xxxxxxx. Xxxxx x xxxxxxx xxxx uvedené xxxxxxx xxxxx být xxxxxxx pouze x xxxxxxxxx xxxxxxx na 100 ml.
5.6 Xxxxx xxxxx xxxxxx xxxxxxxxxxx, xxxxxxxxx xx 20 ± 0,1 °X.
6. Xxxxxx
6.1 Xxxxxxxx xxxxxxx
Xx xxxxxxxxxxx xx xxxxxx 26 ± 0,002 x xxxxxx x xxxxxxxxxxxxx se xxxxxxx xx xxxxxxx xxxxx x xxxxxx 100 xx (5.5) obsahující xxx 60 ml xxxx.
Xxxxxx xx xxxxxxxx xxxxxxx, xxxxxx však xxxxxxxxxx.
Xxxxx je xxxxx xxxxxx xxxxxxx, xxxxx xx 0,5 xx xxxxxxx xxxxxx olovnatého (4.1).
Xxxxxx se xxxxx xxxxxxxxx xxxxxxx baňky x stěny xxxxx xx oplachují tak xxxxxx, dokud xxxxxxxx xxxxxxxxxx xxx 10 xx xxx xxxxxxxxxx xxxxx.
Xxxxx xx umístí xx xxxxx lázeň (5.6) xxxxxxxxxx xxx 20 ± 0,1 °X x xxxxxxx xx xxx xxx xxxxxx, dokud xx xxxxxxx cukerného roztoku xxxxxxxx.
Xxxxxxx xxxxxxx xxxxxxxxx xx xxxxxxx xxxxxxxx xx xxxxxxxx xxxxxx xxxxxxxxxxxxx (4.2).
Xxxxxx xx xxxxxx xxxxx po xxxxx.
Xxxxx xx zazátkuje x xxxxx se xxxxxxxx xxxxxxx xxxxxxxxxxxx xxxxxxxxx xxxx xxxxxx.
Xxxxx xx xxxxx xxx xxxxx xxxx.
6.2 Xxxxxxxxx xxxxxxxxxx
Xx dobu xxxxx xxxx uvedených xxxxx xx xxxxxxx teplota 20 ± 0,1 °X.
6.2.1 Polarimetr xx xxxxxxx na xxxx.
6.2.2 Xxxxxx se xxxxxxxxxxx xxxx filtrační xxxxx. Xxxxxxx 10 xx xxxxxxxx se nepoužije. Xxxx xx až xxxxxxx 50 xx xxxxxxxx.
6.2.3 Xxxxxxxxxxxxxx trubice xx promyje xxxxxxxxxxxx xxxxxxxxxxxxx roztokem xxxxxx xxxxxxxx k xxxxxxx (6.2.2).
6.2.4 Xxxxxxx se xxx teplotě 20 ± 0,1 °X xxxxxxx xxxxxx roztokem xxxxxx xxxxxxxx x xxxxxxx.
Xxx zasouvání uzavírací xxxxxxxx se xxxxxxxx xxxxxxx xxxxxxxxx xxxxxxx. Xxxxxxxx xxxxxxx xx xxxxxx do kolébky xxxxxxxxx.
6.2.5 Xxxxxx xx xxxxxxxxxx s xxxxxxxxx xx 0,05°X xxxx 0,02 úhlových stupňů. Xxxxx se xxxxxxxx xxxxx xxxxxxxxx. Xxxxxxx xx průměr x xxxxxx xxxx xxxxxx.
7. Xxxxxxxxx výsledků
7.1 Vzorec x xxxxxx výpočtu
Výsledky xxxx xxxxxxxxx ve xxxxxxxx S x xxxxxxxxx xx 0,1°X. Xxx převod xxxxxxxx xxxxxx xx stupně X se xxxxxxx xxxxx vzorec:
S = xxxxxx xxxxxx × 2,889
7.2 Opakovatelnost
Rozdíl mezi xxxxxxxx dvou xxxxxxxxx xxxxxxxxxxx zároveň xxxx xxxxxx za xxxxx x xxxxx xxxxxx xxxxxx xxxxxxxxxxx xx xxxxxxxxx podmínek nesmí xxx větší než 0,1°X, xxxxxxx xxxxxxxx xxxxxxx xxxxxxxxx xx xxxxxxxx x xxxx xxxxxx.